公开(公告)号：US07557165B2

公开(公告)日：2009-07-07

申请号：US11353109

申请日：2006-02-14

申请人： Jun Shindo ,  Atsushi Nanba

发明人： Jun Shindo ,  Atsushi Nanba

IPC分类号： C08L9/00 ,  A63B37/06

CPC分类号： A63B45/00 ,  A63B37/0003 ,  A63B37/0033 ,  A63B37/0039 ,  A63B37/005 ,  A63B37/0064 ,  A63B37/0065 ,  A63B37/0066 ,  A63B37/0068 ,  A63B37/0073 ,  A63B37/0074 ,  A63B37/0075 ,  A63B37/0076 ,  A63B37/008 ,  A63B37/0083 ,  C08K5/3477 ,  C08K5/37 ,  C08L9/00 ,  C08L21/00 ,  C08L2666/08

摘要： A molded rubber material for golf balls which is obtained by molding and curing a rubber compound composed of base rubber and such ingredients as crosslinking agent, co-crosslinking agent, and vulcanization accelerator, wherein the base rubber is polybutadiene which results from polymerization with the help of a catalyst of rare earth element and has a stress relaxation time (T80) no longer than 5 (measured according to ASTM D 1646-96), the vulcanization accelerator is hexamethylenetetramine, and the rubber compound contains an organosulfur compound. A method for producing the molded rubber material, and a golf ball having the molded rubber material as the solid core. The method permits efficient production of high-quality rubber molded material with high rebound resilience.

摘要翻译： 一种用于高尔夫球的模制橡胶材料，其通过模制和固化由基础橡胶组成的橡胶化合物和诸如交联剂，共交联剂和硫化促进剂的成分而获得，其中所述基础橡胶是由帮助聚合引起的聚丁二烯 的稀土元素催化剂，其应力松弛时间（T80）不超过5（根据ASTM D 1646-96测定），硫化促进剂为六亚甲基四胺，橡胶化合物含有有机硫化合物。 一种生产模制橡胶材料的方法和一种具有模制橡胶材料作为实芯的高尔夫球。 该方法可有效地生产具有高回弹性的高品质橡胶模制材料。

公开(公告)号：US07534835B2

公开(公告)日：2009-05-19

申请号：US11336790

申请日：2006-01-23

申请人： Jun Shindo ,  Atsushi Nanba

发明人： Jun Shindo ,  Atsushi Nanba

IPC分类号： A63B37/06 ,  A63B37/00 ,  C08L9/00

CPC分类号： A63B37/0003 ,  A63B37/0054 ,  A63B2209/00 ,  C08F8/44

摘要： A golf ball is composed at least in part of a material molded under heat from a rubber composition which includes: (a) a base rubber composed primarily of a mixture of at least 60 wt % of a polybutadiene having a stress relaxation time (T80), defined as the length of time it takes from the moment when rotor rotation is stopped immediately after measurement of the ML1+4 (100° C.) value (the Mooney viscosity measured at 100° C. in accordance with ASTM D-1646-96) for the ML1+4 value to decrease 80%, of less than 4 seconds with up to 40 wt % of a polybutadiene having a stress relaxation time (T80) of at least 4 seconds; (b) an unsaturated carboxylic acid and/or a metal salt thereof; and (c) an organic peroxide. The golf ball has an excellent manufacturability and rebound.

摘要翻译： 高尔夫球至少部分由在橡胶组合物的加热下成型的材料组成，该橡胶组合物包括：（a）主要由至少60重量％的具有应力松弛时间（T80）的聚丁二烯的混合物组成的基础橡胶， ，定义为在ML1 + 4（100℃）值测量之后立即停止转子转动时的时间长度（根据ASTM D-1646-）测定的100℃下的门尼粘度， 96）对于ML1 + 4值降低80％，小于4秒，高达40重量％的具有应力松弛时间（T80）的聚丁二烯至少为4秒; （b）不饱和羧酸和/或其金属盐; 和（c）有机过氧化物。 高尔夫球具有很好的可制造性和反弹性。

公开(公告)号：US07294067B2

公开(公告)日：2007-11-13

申请号：US11324297

申请日：2006-01-04

申请人： Jun Shindo ,  Atsushi Nanba

发明人： Jun Shindo ,  Atsushi Nanba

IPC分类号： A63B37/00

CPC分类号： C08K5/36 ,  A63B37/0003 ,  A63B37/0033 ,  A63B37/0045 ,  A63B37/005 ,  A63B37/0063 ,  A63B37/0064 ,  A63B37/0065 ,  C08C19/44 ,  C08L15/00

摘要： A golf ball having, as a constituent element, an article molded under heat from a rubber composition which includes: (a) a base rubber containing polybutadiene having a stress relaxation time (T80), defined as the time in seconds from the moment when rotor rotation is stopped immediately after measurement of the ML1+4 (100° C.) value (the Mooney viscosity measured at 100° C. in accordance with ASTM D-1646-96) that is required for the ML1+4 value to decrease 80%, of at most 3.5, (b) an unsaturated carboxylic acid and/or a metal salt thereof, and (c) an organic peroxide. The golf ball has an excellent rebound.

摘要翻译： 作为构成要素的高尔夫球，由橡胶组合物在加热下成型的制品，其特征在于，包括：（a）含有应力松弛时间（T 80 S）的聚丁二烯的基础橡胶，定义为 在测量ML 1 + 4（100℃）值之后立即停止转子旋转的时刻（在100℃下根据ASTM D- （b）不饱和羧酸和/或其金属盐所要求的最小值为16％〜80％，（c） 有机过氧化物。 高尔夫球有很好的反弹。

公开(公告)号：US20070232415A1

公开(公告)日：2007-10-04

申请号：US11392596

申请日：2006-03-30

申请人： Jun Shindo ,  Atsushi Nanba

发明人： Jun Shindo ,  Atsushi Nanba

IPC分类号： A63B37/14

CPC分类号： A63B37/0003 ,  A63B37/0054 ,  A63B37/0088 ,  A63B45/00 ,  A63B2209/00

摘要： A molded rubber material for a golf ball is obtained by molding and vulcanizing a rubber composition composed of (a) a diene rubber, (b) an α,β-unsaturated carboxylic acid and/or a metal salt thereof, (c) an organic peroxide, and (d) an inorganic oxide. The inorganic oxide is prepared by a plasma process, a laser process or flame synthesis, has an average particle size of at most 200 nm, and is added in an amount of at least 1 wt % based on the zinc acrylate. The molded rubber material has a high hardness, a good resilience, and excellent durability.

摘要翻译： 通过对由（a）二烯橡胶，（b）α，β-不饱和羧酸和/或其金属盐组成的橡胶组合物进行成型和硫化获得高尔夫球用模制橡胶材料，（c）有机 过氧化物，（d）无机氧化物。 无机氧化物通过等离子体处理，激光处理或火焰合成制备，其平均粒度为至多200nm，并且以基于丙烯酸锌的至少1重量％的量添加。 成型橡胶材料具有高硬度，良好的弹性和优异的耐久性。

公开(公告)号：US07906575B2

公开(公告)日：2011-03-15

申请号：US11481004

申请日：2006-07-06

申请人： Atsushi Nanba ,  Jun Shindo

发明人： Atsushi Nanba ,  Jun Shindo

IPC分类号： C08K3/22 ,  A63B37/00 ,  A63B37/12

CPC分类号： C08K5/09 ,  A63B37/0063 ,  A63B37/0065 ,  A63B37/0073 ,  A63B37/0075 ,  C08K5/14 ,  C08L21/00

摘要： The invention provides a molded and crosslinked rubber material for golf balls which is obtained by molding and crosslinking a rubber composition containing rubber and rubber compounding ingredients, including a base rubber, a filler and an organic peroxide, into a spherical body of one or more layers. A monomer is impregnated into the molded and crosslinked rubber material, and one or both of the following chemical reactions is induced: (i) chemical reaction of the monomer with the rubber and/or a rubber compounding ingredient, (ii) chemical reaction of the monomer itself. The depth of impregnation by the monomer from a surface of the molded and crosslinked rubber material to the interior thereof is at least 0.3 mm. The invention also provides a method for manufacturing such a molded and crosslinked rubber material for golf balls. The invention enables the hardness profile, which is the surface hardness of the molded and crosslinked rubber material in combination with the cross-sectional hardness at given depths from the surface, to be adjusted as desired. In particular, when the molded and crosslinked rubber material is used as a golf ball core, the degree of freedom in the core hardness design, i.e., the surface and cross-sectional hardness profile of the core, can be improved.

摘要翻译： 本发明提供了一种用于高尔夫球的模制和交联的橡胶材料，其通过将包含橡胶和橡胶配混成分的橡胶组合物（包括基础橡胶，填料和有机过氧化物）模制和交联成一个或多个层的球体而获得 。 将单体浸渍到模制和交联的橡胶材料中，并且诱发以下一种或两种化学反应：（i）单体与橡胶和/或橡胶配混成分的化学反应，（ii） 单体本身 单体从模制和交联的橡胶材料的表面到其内部的浸渍深度至少为0.3mm。 本发明还提供一种用于制造这种用于高尔夫球的模制和交联的橡胶材料的方法。 本发明能够根据需要调整作为模制和交联的橡胶材料的表面硬度的硬度分布以及从表面给定深度处的横截面硬度。 特别地，当模制和交联的橡胶材料用作高尔夫球芯时，可以提高芯硬度设计的自由度，即芯的表面和截面硬度分布。

公开(公告)号：US07879937B2

公开(公告)日：2011-02-01

申请号：US11350097

申请日：2006-02-09

申请人： Jun Shindo ,  Atsushi Nanba

发明人： Jun Shindo ,  Atsushi Nanba

IPC分类号： A63B37/00 ,  C08L9/00 ,  C08L33/02

CPC分类号： C08F8/44 ,  A63B37/0003 ,  A63B37/0054 ,  A63B37/0073 ,  A63B37/0074 ,  A63B2209/00

摘要： The invention provides a molded polymer material which is obtained by subjecting a polymer composition that includes (A) at least one polymer containing α,β-ethylenically unsaturated carboxylic acid, (B) at least one diene polymer, (C) at least one metal cation source, and (D) at least one organic peroxide, and has a chemical structure arrived at by neutralizing some or all of the carboxyl groups in component A with component C in the presence of component B, to molding and crosslinking under the influence of radicals generated by decomposing component D. The molded polymer material has a high resilience, a high hardness and a good durability, making it well-suited for use in golf balls.

摘要翻译： 本发明提供一种模塑聚合物材料，其通过使包含（A）至少一种含有α，β-烯属不饱和羧酸的聚合物，（B）至少一种二烯聚合物，（C）至少一种 金属阳离子源和（D）至少一种有机过氧化物，并且具有通过在组分B存在下将组分A中的部分或全部羧基与组分C中和，从而在影响下成型和交联而获得的化学结构 由分解组分D产生的自由基。模塑的聚合物材料具有高弹性，高硬度和良好的耐久性，使其非常适用于高尔夫球。

公开(公告)号：US07749106B2

公开(公告)日：2010-07-06

申请号：US11392596

申请日：2006-03-30

申请人： Jun Shindo ,  Atsushi Nanba

发明人： Jun Shindo ,  Atsushi Nanba

IPC分类号： A63B37/00

CPC分类号： A63B37/0003 ,  A63B37/0054 ,  A63B37/0088 ,  A63B45/00 ,  A63B2209/00

摘要： A molded rubber material for a golf ball is obtained by molding and vulcanizing a rubber composition composed of (a) a diene rubber, (b) an α,β-unsaturated carboxylic acid and/or a metal salt thereof, (c) an organic peroxide, and (d) an inorganic oxide. The inorganic oxide is prepared by a plasma process, a laser process or flame synthesis, has an average particle size of at most 200 nm, and is added in an amount of at least 1 wt % based on the zinc acrylate. The molded rubber material has a high hardness, a good resilience, and excellent durability.

摘要翻译： 通过对（a）二烯橡胶，（b）α，β-不饱和羧酸和/或其金属盐组成的橡胶组合物进行成型和硫化，得到高尔夫球用成型橡胶材料，（c） 有机过氧化物，和（d）无机氧化物。 无机氧化物通过等离子体处理，激光处理或火焰合成制备，其平均粒度为至多200nm，并且以基于丙烯酸锌的至少1重量％的量添加。 成型橡胶材料具有高硬度，良好的弹性和优异的耐久性。

公开(公告)号：US20070184916A1

公开(公告)日：2007-08-09

申请号：US11350097

申请日：2006-02-09

申请人： Jun Shindo ,  Atsushi Nanba

发明人： Jun Shindo ,  Atsushi Nanba

IPC分类号： C08F8/00 ,  A63B37/04

CPC分类号： C08F8/44 ,  A63B37/0003 ,  A63B37/0054 ,  A63B37/0073 ,  A63B37/0074 ,  A63B2209/00

摘要： The invention provides a molded polymer material which is obtained by subjecting a polymer composition that includes (A) at least one polymer containing α,β-ethylenically unsaturated carboxylic acid, (B) at least one diene polymer, (C) at least one metal cation source, and (D) at least one organic peroxide, and has a chemical structure arrived at by neutralizing some or all of the carboxyl groups in component A with component C in the presence of component B, to molding and crosslinking under the influence of radicals generated by decomposing component D. The molded polymer material has a high resilience, a high hardness and a good durability, making it well-suited for use in golf balls.

摘要翻译： 本发明提供一种模制的聚合物材料，其通过使包含（A）至少一种含有α，β-烯键式不饱和羧酸的聚合物，（B）至少一种二烯聚合物，（C）至少一种金属 阳离子源和（D）至少一种有机过氧化物，并且具有通过在组分B的存在下用组分C中的组分A中的一些或全部羧基中和部分或全部成分并在 通过分解组分D产生的自由基。模制的聚合物材料具有高回弹性，高硬度和良好的耐久性，使其非常适合用于高尔夫球。

公开(公告)号：US20060293429A1

公开(公告)日：2006-12-28

申请号：US11481004

申请日：2006-07-06

申请人： Atsushi Nanba ,  Jun Shindo

发明人： Atsushi Nanba ,  Jun Shindo

IPC分类号： C08K3/22

CPC分类号： C08K5/09 ,  A63B37/0063 ,  A63B37/0065 ,  A63B37/0073 ,  A63B37/0075 ,  C08K5/14 ,  C08L21/00

摘要： The invention provides a molded and crosslinked rubber material for golf balls which is obtained by molding and crosslinking a rubber composition containing rubber and rubber compounding ingredients, including a base rubber, a filler and an organic peroxide, into a spherical body of one or more layers. A monomer is impregnated into the molded and crosslinked rubber material, and one or both of the following chemical reactions is induced: (i) chemical reaction of the monomer with the rubber and/or a rubber compounding ingredient, (ii) chemical reaction of the monomer itself. The depth of impregnation by the monomer from a surface of the molded and crosslinked rubber material to the interior thereof is at least 0.3 mm. The invention also provides a method for manufacturing such a molded and crosslinked rubber material for golf balls. The invention enables the hardness profile, which is the surface hardness of the molded and crosslinked rubber material in combination with the cross-sectional hardness at given depths from the surface, to be adjusted as desired. In particular, when the molded and crosslinked rubber material is used as a golf ball core, the degree of freedom in the core hardness design, i.e., the surface and cross-sectional hardness profile of the core, can be improved.

摘要翻译： 本发明提供了一种用于高尔夫球的模制和交联的橡胶材料，其通过将包含橡胶和橡胶配混成分的橡胶组合物（包括基础橡胶，填料和有机过氧化物）模制和交联成一个或多个层的球体而获得 。 将单体浸渍到模制和交联的橡胶材料中，并且诱发以下一种或两种化学反应：（i）单体与橡胶和/或橡胶配混成分的化学反应，（ii） 单体本身 单体从模制和交联的橡胶材料的表面到其内部的浸渍深度至少为0.3mm。 本发明还提供一种用于制造这种用于高尔夫球的模制和交联的橡胶材料的方法。 本发明能够根据需要调整作为模制和交联的橡胶材料的表面硬度的硬度分布以及从表面给定深度处的横截面硬度。 特别地，当模制和交联的橡胶材料用作高尔夫球芯时，可以提高芯硬度设计的自由度，即芯的表面和截面硬度分布。

公开(公告)号：US20060128900A1

公开(公告)日：2006-06-15

申请号：US11011043

申请日：2004-12-15

申请人： Atsushi Nanba ,  Jun Shindo

发明人： Atsushi Nanba ,  Jun Shindo

IPC分类号： C08L19/00 ,  A63B37/00 ,  A63B37/12

CPC分类号： A63B37/0003 ,  A63B37/0031 ,  A63B37/0062 ,  A63B37/0092 ,  C08K5/098 ,  C08K5/14 ,  C08L9/00

摘要： The present invention provides a solid golf ball comprising a hot-molded product of a rubber composition comprising (a) 100 parts by weight of a polybutadiene synthesized using a rare-earth catalyst and having a cis-1,4 content of at least 60% and a 1,2 vinyl content of at most 2%, having a viscosity η at 25° C. as a 5 wt % solution in toluene of up to 600 mPa·s, and having Mooney viscosity (ML1+4 (100° C.)) of more than 30, (b) 0.01 to 0.5 parts by weight of a sulfur, (c) 10 to 60 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, (d) 0.1 to 5 parts by weight of an organosulfur compound, (e) 5 to 80 parts by weight of an inorganic filler, and (f) 0.1 to 5 parts by weight of an organic peroxide, wherein the hot-molded product has a difference in JIS-C hardness between the center and surface thereof of more than 20 and up to 40. The solid golf balls of the invention have a soft feel upon impact and excellent rebound characteristics. Moreover, the solid golf balls are improved in flight performance by making its spin rate reduced when shot with a driver.

摘要翻译： 本发明提供一种固体高尔夫球，其包括橡胶组合物的热模制品，该组合物包含（a）100重量份的使用稀土催化剂合成的聚丁二烯，并且顺式-1,4含量为至少60重量％ 和至多2％的1,2-乙烯基含量，在25℃下的粘度eta为5重量％的甲苯溶液，最高达600mPa.s，门尼粘度（ML 1 + 4） （100℃））大于30，（b）0.01〜0.5重量份的硫，（c）10〜60重量份的不饱和羧酸和/或其金属盐 ，（d）0.1〜5重量份的有机硫化合物，（e）5〜80重量份的无机填料，（f）0.1〜5重量份的有机过氧化物，其中， 其中心和表面之间的JIS-C硬度差异在20以上至40以下。本发明的固体高尔夫球具有柔软的冲击感和优异的回弹特性。 此外，通过在用驾驶员拍摄时使其旋转速度降低，固体高尔夫球的飞行性能得到改善。