摘要:
The present invention provides a non-aqueous electrolyte solution comprising a non-aqueous solvent and a lithium electrolyte, wherein the non-aqueous solvent is obtained by adding a phosphoric acid compound prepared by substituting at least one hydrogen atom in phosphoric acid or polyphosphoric acid with a group represented by the general formula [1]: wherein, X represents Si, Ge or Sn atom, and each of R1 to R3 independently represents an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms.
摘要:
A lithium secondary battery that includes a cathode containing, as an active material, a material that can be doped/undoped with lithium ions; an anode containing, as an active material, a lithium metal, a lithium alloy or a material that can be doped/undoped with lithium ions; and a liquid or solid electrolyte. In this lithium secondary battery, the active material used in the cathode is lithiated nickel dioxide containing gallium. As a result, the lithium secondary battery attains excellent cycle and overcharge resistance characteristics and has a high energy density.
摘要:
Disclosed are an electrode and a battery comprising the electrode. The electrode comprises a nano composite comprising nano particles capable of being oxidized and reduced and a carbonaceous material covering the nano particles.
摘要:
The present invention relates to an electrode for an electrochemical energy storage device. The electrode comprises a nano-structured hollow carbonaceous material and the nano-structured hollow carbonaceous material preferably meets a requirement (A). (A) the nano-structured hollow carbonaceous material has a carbonaceous material portion and a hollow portion, and has such a structure that the hollow portion is covered with the carbonaceous material portion in a saclike shape, a part of the structure, or an aggregate of the structure.
摘要:
A nonaqueous electrolyte secondary battery comprising a positive electrode containing a granular positive electrode active material composed of a mixed metal oxide and an M3-containing compound (M3 represents one or more elements selected from the group consisting of Group 3B elements in the periodic table, and the M3-containing compound is different from said mixed metal oxide) placed in the form of particles or a layer on the surface of the mixed metal oxide, wherein the positive electrode active material has M1 (M1 represents one or more elements selected from the group consisting of alkali metal elements), M2 (M2 represents one or more elements selected from the group consisting of Mn, Fe, Co and Ni), M3 (M3 has the same meaning as that described above) and O on its surface, and when the molar ratio (M3/M2) of the number of M3 atoms (mol) to the number of M2 atoms (mol) on the surface of the positive electrode active material is represented by A and the BET specific surface area of the positive electrode active material is represented by S (m2/g), A and S satisfy the following formula (1): A/S≧1 (1), a negative electrode, a separator, and a nonaqueous electrolyte.
摘要:
A lithium secundary battery cathode composition comprising a cathode active material, a conductive substance and a binder, wherein the binder comprises a fluororesin and a polyolefin resin, and the amount of the fluororesin in the composition is 1 to 10% by weight and the amount of the polyolefin resin in the composition is 0.1 to 2% by weight.The cathode using the cathode composition of the present invention has an excellent binding property with a current collector, and the lithium secondary battery of the present invention has a high energy density and improved safety against an external heating, and the industrial value is very high.
摘要:
The invention provides a cathode for a lithium secondary battery including lithiated nickel dioxide with a large discharge capacity as an active material and having a high density so that a larger amount of the active material can be charged in a battery container with a limited volume, a production method for the same and a lithium secondary battery utilizing the cathode. The cathode for a lithium secondary battery includes lithiated nickel dioxide as an active material, and the lithiated nickel dioxide is produced by firing a mixture of a lithium compound and a nickel compound at a temperature ranging between 350.degree. C. and 800.degree. C. The supernatant obtained by dispersing 5 g of the lithiated nickel dioxide in 100 cm.sup.3 of water in a glass vessel for 5 minutes and allowing the resultant solution to stand for 30 seconds has pH of 12.00 or less. The production method includes the steps of obtaining the lithiated nickel dioxide as above and treating or milling the lithiated nickel dioxide in an atmosphere including carbon dioxide.
摘要:
The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 μm or more to less than 1 μm, the diameter determined by a laser diffraction scattering method.
摘要:
Disclosed is a positive electrode active material for nonaqueous electrolyte secondary batteries which contains a complex oxide mainly containing sodium, nickel and a tetravalent metal while having a hexagonal structure. This positive electrode active material enables to obtain a nonaqueous electrolyte secondary battery with high operating voltage. The complex oxide is preferably expressed as Na[Na(1/3-2x/3)Ni(x-y)M(2/3-x/3-y)A2y]O2 (wherein M represents one or more tetravalent metals, A represents one or more trivalent metals, 0 y).
摘要:
There is provided a simple and easy method of preparation of a positive electrode active material for a non-aqueous secondary battery which comprises a compound comprising lithium, nickel and manganese and having a layered structure. Said method comprises firing a mixture of (1) at least one member selected from the group consisting of dinickel trioxide and boron compounds and (2) one or more metal compounds comprising lithium, nickel and manganese as their metal elements.