公开(公告)号：US07220508B2

公开(公告)日：2007-05-22

申请号：US10025763

申请日：2001-12-26

申请人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

发明人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

IPC分类号： H01M8/10 ,  C08F259/08 ,  C08F12/20 ,  C08F16/24

CPC分类号： H01M8/1067 ,  B01D71/32 ,  B01D71/44 ,  B01D71/72 ,  B01D71/76 ,  C08F216/1466 ,  C08F228/02 ,  C08J5/2268 ,  C08J2327/18 ,  C08J2365/00 ,  C08J2387/00 ,  C08L65/00 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/0525 ,  H01M10/0565

摘要： A solid polymer electrolyte material made of a copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1): CF2═CF(Rf)jSO2X  (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM {wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

摘要翻译： 一种由共聚物制成的固体聚合物电解质材料，该共聚物包含基于通过自由基聚合在主链中具有脂环结构的聚合物的基于含氟单体A的重复单元和基于下式（1）的含氟单体B的重复单元， ：<？in-line-formula description =“In-line Formulas”end =“lead”？> CF -CF（R） 其中j为0或1，X为氟原子，X为1或2， ，氯原子或OM（其中M为氢原子，碱金属原子或NR 1 R 2 O 3 R 3的基团） 4（其中R 1，R 2，R 3和R 4中的每一个） 其可以相同或不同，是氢原子或一价有机基团）}，并且R f是具有直链的C 1〜20个多氟亚烷基 或可以含有醚氧原子的支链结构。

公开(公告)号：US20110305971A1

公开(公告)日：2011-12-15

申请号：US13214273

申请日：2011-08-22

申请人： Atsushi WATAKABE ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

发明人： Atsushi WATAKABE ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

IPC分类号： H01M8/10

CPC分类号： H01M8/1067 ,  B01D71/32 ,  B01D71/44 ,  B01D71/72 ,  B01D71/76 ,  C08F216/1466 ,  C08F228/02 ,  C08J5/2268 ,  C08J2327/18 ,  C08J2365/00 ,  C08J2387/00 ,  C08L65/00 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/0525 ,  H01M10/0565

摘要： A solid polymer electrolyte material made of a copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1): CF2═CF(Rf)jSO2X   (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM {wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

摘要翻译： 一种由共聚物制成的固体聚合物电解质材料，该共聚物包含基于通过自由基聚合在主链中具有脂环结构的聚合物的基于含氟单体A的重复单元和基于下式（1）的含氟单体B的重复单元， ：CF2 = CF（Rf）jSO2X（1）其中j为0或1，X为氟原子，氯原子或OM（其中M为氢原子，碱金属原子或NR1R2R3R4基团 R 1，R 2，R 3和R 4可以相同或不同，为氢原子或一价有机基团}}，R f为可含有醚氧原子的具有直链或支链结构的C1-20多氟亚烷基。

公开(公告)号：US20080287694A1

公开(公告)日：2008-11-20

申请号：US11829579

申请日：2007-07-27

申请人： Takashi OKAZOE ,  Atsushi Watakabe ,  Masahiro Ito ,  Kunio Watanabe ,  Takeshi Eriguchi ,  Kimiaki Kashiwagi ,  Shu-zhong Wang

发明人： Takashi OKAZOE ,  Atsushi Watakabe ,  Masahiro Ito ,  Kunio Watanabe ,  Takeshi Eriguchi ,  Kimiaki Kashiwagi ,  Shu-zhong Wang

IPC分类号： C07D317/30 ,  C07D317/18

CPC分类号： C08F24/00 ,  C07D317/18 ,  C07D317/24 ,  C07D317/42

摘要： A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided.A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. wherein RA is a bivalent organic group such as a fluoroalkylene group, RAF is a group having RA fluorinated, or the same group as RA, each of RB to RD which are independent of one another, is a hydrogen atom, etc., each of RBF to RDF is a fluorine atom, etc., RE is a monovalent organic group, REF is a group having RE fluorinated, or the same group as RE, E is a bivalent connecting group, EF is the same group as E, or a group having E fluorinated, EF1 is a group formed by scission of EF, each of X1 to X3 is a hydrogen atom, etc., and each of X1F to X3F is a fluorine atom, etc.

摘要翻译： 提供具有高聚合反应性的含氟磺酰基的化合物，其制备方法，由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过聚合含磺酰基的可聚合单体获得的聚合物 。 化合物（3）被氟化以形成化合物（4），然后使化合物（4）进行分解反应以制备化合物（5）。 将化合物（5）的优选化合物（5-1）热分解，得到聚合反应性高的化合物（7-1）。 其中R A是二价有机基团，例如氟代亚烷基，R AF是​​具有氟代的基团，或与氟代亚烷基相同的基团 各自独立的R B，R D，D各自为氢原子等，R a， 另一方面，BF> BF 是氟原子等，R E是一价有机基团，R EF是 氟化的基团或与R E相同的基团，E是二价连接基团，E是与 E或具有E氟化基团的基团，是通过将X 1和X 2各自分开形成的基团。 > 3是氢原子等，X 1〜X 3各自为氟原子等。

公开(公告)号：US08470943B2

公开(公告)日：2013-06-25

申请号：US13563802

申请日：2012-08-01

申请人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

发明人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

IPC分类号： H01M8/10 ,  C08F16/24

CPC分类号： H01M8/1067 ,  B01D71/32 ,  B01D71/44 ,  B01D71/72 ,  B01D71/76 ,  C08F216/1466 ,  C08F228/02 ,  C08J5/2268 ,  C08J2327/18 ,  C08J2365/00 ,  C08J2387/00 ,  C08L65/00 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/0525 ,  H01M10/0565

摘要： A solid polymer electrolyte material made of a copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1): CF2═CF(Rf)jSO2X  (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM {wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

摘要翻译： 一种由共聚物制成的固体聚合物电解质材料，该共聚物包含基于通过自由基聚合在主链中具有脂环结构的聚合物的基于含氟单体A的重复单元和基于下式（1）的含氟单体B的重复单元， CF 2 = CF（R f）j SO 2 X（1）其中j为0或1，X为氟原子，氯原子或OM（其中M为氢原子，碱金属原子或NR1R2R3R4基团 R 1，R 2，R 3和R 4可以相同或不同，为氢原子或一价有机基团}}，R f为可含有醚氧原子的具有直链或支链结构的C1-20多氟亚烷基。

公开(公告)号：US07271229B2

公开(公告)日：2007-09-18

申请号：US10830140

申请日：2004-04-23

申请人： Takashi Okazoe ,  Atsushi Watakabe ,  Masahiro Ito ,  Kunio Watanabe ,  Takeshi Eriguchi ,  Kimiaki Kashiwagi ,  Shu-zhong Wang

发明人： Takashi Okazoe ,  Atsushi Watakabe ,  Masahiro Ito ,  Kunio Watanabe ,  Takeshi Eriguchi ,  Kimiaki Kashiwagi ,  Shu-zhong Wang

IPC分类号： G08F228/02

CPC分类号： C08F24/00 ,  C07D317/18 ,  C07D317/24 ,  C07D317/42

摘要： A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer

摘要翻译： 具有高聚合反应性的含氟磺酰基的化合物，其制备方法，由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过使含磺酰基的可聚合单体聚合而获得的聚合物

公开(公告)号：US06610789B2

公开(公告)日：2003-08-26

申请号：US09782020

申请日：2001-02-14

申请人： Atsushi Watakabe ,  Takeshi Eriguchi

发明人： Atsushi Watakabe ,  Takeshi Eriguchi

IPC分类号： C08F1418

CPC分类号： H01M4/621 ,  C08F6/001 ,  C08F259/08 ,  C08F293/00 ,  C08F293/005 ,  C08L53/00 ,  H01M4/622 ,  H01M4/623 ,  H01M4/8605 ,  H01M8/1004 ,  H01M8/1007 ,  H01M8/1023 ,  H01M8/1039 ,  H01M2008/1095 ,  H01M2300/0082

摘要： A polymer electrolyte fuel cell comprising a membrane-form polymer electrolyte, a cathode disposed on one side of the polymer electrolyte, and an anode disposed on the other side of the polymer electrolyte, wherein the cathode comprises a catalyst and an ion exchange resin, and the ion exchange resin is made of a polymer comprising the following segments A and segments B: Segments A: segments made of a polymer having sulfonic acid groups; and Segments B: segments made of a fluoropolymer having substantially no ion exchange groups.

摘要翻译： 一种聚合物电解质燃料电池，其特征在于，包含膜状高分子电解质，设置在所述高分子电解质一侧的阴极和位于所述高分子电解质的另一侧的阳极，所述阴极包含催化剂和离子交换树脂， 离子交换树脂由包含以下片段A和片段B的聚合物制成：片段A：由具有磺酸基的聚合物制成的片段; 和附图B：由基本上不含离子交换基团的含氟聚合物制成的链段。

公开(公告)号：US08263710B2

公开(公告)日：2012-09-11

申请号：US13214273

申请日：2011-08-22

申请人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

发明人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

IPC分类号： C08F14/18 ,  C08F16/24

CPC分类号： H01M8/1067 ,  B01D71/32 ,  B01D71/44 ,  B01D71/72 ,  B01D71/76 ,  C08F216/1466 ,  C08F228/02 ,  C08J5/2268 ,  C08J2327/18 ,  C08J2365/00 ,  C08J2387/00 ,  C08L65/00 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/0525 ,  H01M10/0565

摘要： A solid polymer electrolyte material made of a copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1): CF2═CF(Rf)jSO2X  (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM {wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

摘要翻译： 一种由共聚物制成的固体聚合物电解质材料，该共聚物包含基于通过自由基聚合在主链中具有脂环结构的聚合物的基于含氟单体A的重复单元和基于下式（1）的含氟单体B的重复单元， ：CF2 = CF（Rf）jSO2X（1）其中j为0或1，X为氟原子，氯原子或OM（其中M为氢原子，碱金属原子或NR1R2R3R4基团 R 1，R 2，R 3和R 4可以相同或不同，为氢原子或一价有机基团}}，R f为可含有醚氧原子的具有直链或支链结构的C1-20多氟亚烷基。

公开(公告)号：US07709665B2

公开(公告)日：2010-05-04

申请号：US11829579

申请日：2007-07-27

申请人： Takashi Okazoe ,  Atsushi Watakabe ,  Masahiro Ito ,  Kunio Watanabe ,  Takeshi Eriguchi ,  Kimiaki Kashiwagi ,  Shu-zhong Wang

发明人： Takashi Okazoe ,  Atsushi Watakabe ,  Masahiro Ito ,  Kunio Watanabe ,  Takeshi Eriguchi ,  Kimiaki Kashiwagi ,  Shu-zhong Wang

IPC分类号： C07D317/00

CPC分类号： C08F24/00 ,  C07D317/18 ,  C07D317/24 ,  C07D317/42

摘要： A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided.A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. wherein RA is a bivalent organic group such as a fluoroalkylene group, RAF is a group having RA fluorinated, or the same group as RA, each of RB to RD which are independent of one another, is a hydrogen atom, etc., each of RBF to RDF is a fluorine atom, etc., RE is a monovalent organic group, REF is a group having RE fluorinated, or the same group as RE, E is a bivalent connecting group, EF is the same group as E, or a group having E fluorinated, EF1 is a group formed by scission of EF, each of X1 to X3 is a hydrogen atom, etc., and each of X1F to X3F is a fluorine atom, etc.

摘要翻译： 提供具有高聚合反应性的含氟磺酰基的化合物，其制备方法，由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过聚合含磺酰基的可聚合单体获得的聚合物 。 化合物（3）被氟化以形成化合物（4），然后使化合物（4）进行分解反应以制备化合物（5）。 将化合物（5）的优选化合物（5-1）热分解，得到聚合反应性高的化合物（7-1）。 其中RA是二价有机基团，例如氟代亚烷基，RAF是具有RA氟化的基团，或与RA相同的基团，每个RB与RD彼此独立，为氢原子等 RBF与RDF是氟原子等，RE是一价有机基团，REF是具有RE氟化的基团，或与RE相同的基团，E是二价连接基团，EF与E相同，或者 具有E氟原子的基团，EF1是通过EF的断裂形成的基团，X1〜X3各自为氢原子等，X1F〜X3F各自为氟原子等。

公开(公告)号：US20080014490A1

公开(公告)日：2008-01-17

申请号：US11671665

申请日：2007-02-06

申请人： Atsushi WATAKABE ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

发明人： Atsushi WATAKABE ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

IPC分类号： H01M8/10

CPC分类号： H01M8/1067 ,  B01D71/32 ,  B01D71/44 ,  B01D71/72 ,  B01D71/76 ,  C08F216/1466 ,  C08F228/02 ,  C08J5/2268 ,  C08J2327/18 ,  C08J2365/00 ,  C08J2387/00 ,  C08L65/00 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/0525 ,  H01M10/0565

摘要： A solid polymer electrolyte material made of a copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1): CF2═CF(Rf)jSO2X  (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM {wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

摘要翻译： 一种由共聚物制成的固体聚合物电解质材料，该共聚物包含基于通过自由基聚合在主链中具有脂环结构的聚合物的基于含氟单体A的重复单元和基于下式（1）的含氟单体B的重复单元， ：<？in-line-formula description =“In-line Formulas”end =“lead”？> CF -CF（R） 其中j为0或1，X为氟原子，X为1或2， ，氯原子或OM（其中M为氢原子，碱金属原子或NR 1 R 2 O 3 R 3的基团） 4（其中R 1，R 2，R 3和R 4中的每一个） 其可以相同或不同，是氢原子或一价有机基团）}，并且R f是具有直链的C 1〜20个多氟亚烷基 或可以含有醚氧原子的支链结构。

公开(公告)号：US20120301813A1

公开(公告)日：2012-11-29

申请号：US13563802

申请日：2012-08-01

申请人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

发明人： Atsushi Watakabe ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

IPC分类号： H01M8/10

CPC分类号： H01M8/1067 ,  B01D71/32 ,  B01D71/44 ,  B01D71/72 ,  B01D71/76 ,  C08F216/1466 ,  C08F228/02 ,  C08J5/2268 ,  C08J2327/18 ,  C08J2365/00 ,  C08J2387/00 ,  C08L65/00 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/0525 ,  H01M10/0565

摘要： A solid polymer electrolyte material made of a s copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1): CF2═CF(Rf)jSO2X  (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM {wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

摘要翻译： 一种由共聚物制成的固体高分子电解质材料，其包含基于通过自由基聚合在其主链中具有脂环结构的聚合物的基于含氟单体A的重复单元和基于下式（1）的含氟单体B的重复单元， ：CF2 = CF（Rf）jSO2X（1）其中j为0或1，X为氟原子，氯原子或OM（其中M为氢原子，碱金属原子或NR1R2R3R4基团 R 1，R 2，R 3和R 4可以相同或不同，为氢原子或一价有机基团}}，R f为可含有醚氧原子的具有直链或支链结构的C1-20多氟亚烷基。