公开(公告)号：US3912775A

公开(公告)日：1975-10-14

申请号：US41529273

申请日：1973-11-13

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF ,  ZIRKER GUENTER ,  TRIEBSKORN BRUNO ,  MAROSI LASZLO ,  SCHWARZMANN MATTHIAS ,  DETHLEFSEN WINFRIED ,  KAEMPFER KNUT

IPC: B01J23/00 ,  B01J23/08 ,  B01J23/755 ,  B01J37/08 ,  C07B61/00 ,  C07C1/00 ,  C07C1/02 ,  C07C9/04 ,  C07C67/00 ,  C10K3/02 ,  C07C27/06

CPC classification number: B01J37/08 ,  B01J23/08 ,  B01J23/755 ,  C07C1/02 ,  C07C2527/236 ,  C10G11/02 ,  C07C9/04

Abstract: Gases of various origins which contain carbon monoxide and dioxide and hydrogen, for example the gases obtained by steam reforming or the rich gas process, refinery gases or coal gasification gases are methanized on a nickel catalyst. The object of this reaction is to obtain methane or gases which can be substituted for natural gas. To produce the catalyst, the compound Ni6Al2(OH)16.CO3.4H2O is obtained from aqueous solution. The catalyst is obtained from this compound after drying, calcination and subsequent reduction in a stream of hydrogen, whilst maintaining very specific temperature gradients between the drying stage and the calcination stage.

Abstract translation: 含有一氧化碳和二氧化碳和氢气的各种原料的气体，例如通过蒸汽重整或富气处理获得的气体，炼厂气体或煤气化气体在镍催化剂上甲烷化。 该反应的目的是获得可替代天然气的甲烷或气体。 为了制备催化剂，从水溶液中获得化合物Ni6Al2（OH）16.CO3·4H2O。 在干燥，煅烧和随后在氢气流中还原之后，从该化合物获得催化剂，同时在干燥阶段和煅烧阶段保持非常特定的温度梯度。