Manufacture of sebacic acid diesters
    1.
    发明授权
    Manufacture of sebacic acid diesters 失效
    硫酸乳液的制造

    公开(公告)号:US3783112A

    公开(公告)日:1974-01-01

    申请号:US3783112D

    申请日:1971-05-10

    Applicant: BASF AG

    Inventor: BECK F HAUFE J NOHE H

    CPC classification number: C25B3/10

    Abstract: PROCESS FOR THE PRODUCTION OF SEBACIC ACID DIESTERS FROM ADIPIC ACID MONOESTERS OF HIGHER ALCOHOLS BY ELECTROCHEMICAL CONDENSATION IN METHANOLIC SOLUTION USING CONTINUOUS OR INTERMITTENT FLOW OF CURRENT, IN WHICH A SATURATED MONOOR POLYVALENT ETHER OR A LOWER ALKANOIC ACID IS ADDED TO THE REACTION MIXTURE.

    Electrolytic cell including bipolar electrodes having two spaced chambers in each electrode for feeding and withdrawing electrolyte from the cell
    2.
    发明授权
    Electrolytic cell including bipolar electrodes having two spaced chambers in each electrode for feeding and withdrawing electrolyte from the cell 失效
    电解槽包括在每个电极中具有两个间隔的电极的双极电极,用于从电池供给和取出电解质

    公开(公告)号:US3775283A

    公开(公告)日:1973-11-27

    申请号:US3775283D

    申请日:1971-07-29

    Applicant: BASF AG

    CPC classification number: C25B11/04 C25B3/10 C25B11/02

    Abstract: Bipolar electrodes having two chambers for inflow and outflow of the reaction mixture to be electrolyzed. The chambers are separated from each other by a distance which is considerably larger than their width and the inlets and outlets are on the same side of the electrode. Electrodes of this kind are suitable, for example, for the Kolbe synthesis of dicarboxylic esters from dicarboxylic half-esters. Such esters are useful as plasticizers.

    Abstract translation: 双极电极具有两个用于待电解的反应混合物的流入和流出室。 这些室彼此分开一个远大于其宽度的距离,并且入口和出口位于电极的同一侧。 这种电极例如适用于从二羧酸半酯合成二羧酸酯的科尔贝。 这些酯可用作增塑剂。

    Electrolytic condensation of carboxylic acids
    3.
    发明授权
    Electrolytic condensation of carboxylic acids 失效
    羧酸的电解冷凝

    公开(公告)号:US3787299A

    公开(公告)日:1974-01-22

    申请号:US3787299D

    申请日:1971-03-22

    Applicant: BASF AG

    Inventor: NOHE H BECK F HAUFE J

    CPC classification number: C25B3/10

    Abstract: Process for the electrochemical condensation of carboxylic acids in a solvent, in which the electrolyte is caused to flow at a rate of from 0.05 to 2 m/sec between pairs of electrodes which are impermeable to liquids and are spaced from 0.1 to 2 mm apart.

    Abstract translation: 在溶剂中电化学缩合羧酸的方法,其中使电解液以对液体不渗透的电极对之间以0.05至2m / sec的速率流动并且间隔0.1至2mm。

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