Electrolytic condensation of carboxylic acids
    1.
    发明授权
    Electrolytic condensation of carboxylic acids 失效
    羧酸的电解冷凝

    公开(公告)号:US3787299A

    公开(公告)日:1974-01-22

    申请号:US3787299D

    申请日:1971-03-22

    Applicant: BASF AG

    Inventor: NOHE H BECK F HAUFE J

    CPC classification number: C25B3/10

    Abstract: Process for the electrochemical condensation of carboxylic acids in a solvent, in which the electrolyte is caused to flow at a rate of from 0.05 to 2 m/sec between pairs of electrodes which are impermeable to liquids and are spaced from 0.1 to 2 mm apart.

    Abstract translation: 在溶剂中电化学缩合羧酸的方法,其中使电解液以对液体不渗透的电极对之间以0.05至2m / sec的速率流动并且间隔0.1至2mm。

    Production of cycloalkanone oximes
    2.
    发明授权
    Production of cycloalkanone oximes 失效
    生产环烷基酮氧化物

    公开(公告)号:US3766038A

    公开(公告)日:1973-10-16

    申请号:US3766038D

    申请日:1971-12-15

    Applicant: BASF AG

    CPC classification number: B01D61/44 B01D2311/2684

    Abstract: A process for the production of cycloalkanone oximes by reaction of cycloalkanones with hydroxylammonium salts or mixtures thereof with ammonium salts and acids in aqueous solution. The free and combined acid is removed from the mixtures by electrodialysis before, during or after the oximation. The reaction of the cycloalkanone to the oxime is preferably carried out in the cathode chamber of an electrodialysis cell. Complete oximation of the cycloalkanone is achieved.

    Abstract translation: 通过环烷酮与羟基铵盐或其混合物与水溶液中的铵盐和酸的反应制备环烷酮肟的方法。 在肟化之前,期间或之后,通过电渗析从混合物中除去游离和组合的酸。 环烷酮与肟的反应优选在电渗析池的阴极室中进行。 实现了环烷酮的完全肟化。

    An electrocoating composition containing an acid binder present as the salt of an arylamine, alkynyl amine, quaternary ammonium hydroxide or phosphonium hydroxide
    3.
    发明授权
    An electrocoating composition containing an acid binder present as the salt of an arylamine, alkynyl amine, quaternary ammonium hydroxide or phosphonium hydroxide 失效
    含有酸性粘合剂的电动组合物作为亚氨基胺的盐,烷基胺,季铵氢氧化铵或氢氧化磷

    公开(公告)号:US3819548A

    公开(公告)日:1974-06-25

    申请号:US20470171

    申请日:1971-12-03

    Applicant: BASF AG

    CPC classification number: C09D5/4484 Y10S524/901

    Abstract: In an electrocoating process acid binders which are present at least partly in the form of their salts with basic compounds are used and the basic compounds used for salt formation consist of the extent of 0.1 to 50 percent of the neutralization equivalent of the acid binder of at least one arylamine and/or alkynylamine and/or quaternary ammonium hydroxide and/or phosphonium hydroxide with at least one aromatic ligand, and other conventional additives and non-basic corrosion inhibitors may be contained in the aqueous solution or dispersion of the coating composition. The process is suitable for the production of particularly corrosion-resistant coatings on metal articles.

    Abstract translation: 在电涂工艺中,使用至少部分以其与碱性化合物形式的盐形式存在的酸结合剂,用于形成盐的碱性化合物的组成范围为在酸性粘合剂的中和当量的0.1至50% 可以在涂料组合物的水溶液或分散体中含有至少一种芳基胺和/或炔基胺和/或具有至少一种芳族配体的氢氧化季铵和/或氢氧化鏻以及其它常规添加剂和非碱性缓蚀剂。 该方法适用于生产金属制品上特别耐腐蚀的涂层。

    Manufacture of sebacic acid diesters
    4.
    发明授权
    Manufacture of sebacic acid diesters 失效
    硫酸乳液的制造

    公开(公告)号:US3783112A

    公开(公告)日:1974-01-01

    申请号:US3783112D

    申请日:1971-05-10

    Applicant: BASF AG

    Inventor: BECK F HAUFE J NOHE H

    CPC classification number: C25B3/10

    Abstract: PROCESS FOR THE PRODUCTION OF SEBACIC ACID DIESTERS FROM ADIPIC ACID MONOESTERS OF HIGHER ALCOHOLS BY ELECTROCHEMICAL CONDENSATION IN METHANOLIC SOLUTION USING CONTINUOUS OR INTERMITTENT FLOW OF CURRENT, IN WHICH A SATURATED MONOOR POLYVALENT ETHER OR A LOWER ALKANOIC ACID IS ADDED TO THE REACTION MIXTURE.

    Electrolytic cell including bipolar electrodes having two spaced chambers in each electrode for feeding and withdrawing electrolyte from the cell
    5.
    发明授权
    Electrolytic cell including bipolar electrodes having two spaced chambers in each electrode for feeding and withdrawing electrolyte from the cell 失效
    电解槽包括在每个电极中具有两个间隔的电极的双极电极,用于从电池供给和取出电解质

    公开(公告)号:US3775283A

    公开(公告)日:1973-11-27

    申请号:US3775283D

    申请日:1971-07-29

    Applicant: BASF AG

    CPC classification number: C25B11/04 C25B3/10 C25B11/02

    Abstract: Bipolar electrodes having two chambers for inflow and outflow of the reaction mixture to be electrolyzed. The chambers are separated from each other by a distance which is considerably larger than their width and the inlets and outlets are on the same side of the electrode. Electrodes of this kind are suitable, for example, for the Kolbe synthesis of dicarboxylic esters from dicarboxylic half-esters. Such esters are useful as plasticizers.

    Abstract translation: 双极电极具有两个用于待电解的反应混合物的流入和流出室。 这些室彼此分开一个远大于其宽度的距离,并且入口和出口位于电极的同一侧。 这种电极例如适用于从二羧酸半酯合成二羧酸酯的科尔贝。 这些酯可用作增塑剂。

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