公开(公告)号：US3414606A

公开(公告)日：1968-12-03

申请号：US53932066

申请日：1966-04-01

Applicant: BASF AG

Inventor： SIEGFRIED WINDERL ,  HERWIG HOFFMANN ,  CHRISTOF PALM ,  HEINZ NOHE ,  KARL BAER ,  HARTWIG HARDERS

IPC: B01J23/16 ,  B01J23/30 ,  B01J23/68 ,  B01J23/70 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89

CPC classification number: B01J23/8878 ,  B01J23/16 ,  B01J23/687 ,  B01J23/70 ,  B01J23/8885 ,  B01J23/8993 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08

公开(公告)号：US3270059A

公开(公告)日：1966-08-30

申请号：US25890563

申请日：1963-02-15

Applicant: BASF AG

Inventor： SIEGFRIED WINDERL ,  ERICH HAARER ,  HUBERT CORR ,  PAUL HORNBERGER

IPC: B01J23/38 ,  B01J23/70 ,  C07C209/16 ,  C07C211/10 ,  C07C211/11 ,  C07C211/12

CPC classification number: C07C209/16 ,  B01J23/38 ,  B01J23/70 ,  C07C211/10 ,  C07C211/11 ,  C07C211/12

公开(公告)号：US2961457A

公开(公告)日：1960-11-22

申请号：US78367158

申请日：1958-12-30

Applicant: BASF AG

Inventor： HEINZ POHLEMANN ,  SIEGFRIED WINDERL ,  HERBERT STUMMEYER ,  HEINRICH ADOLPHI

IPC: C07F9/113 ,  C07F9/14 ,  C07F9/173 ,  C07F9/20 ,  C07F9/572

CPC classification number: C07F9/5721 ,  C07F9/113 ,  C07F9/1403 ,  C07F9/173 ,  C07F9/20

Abstract: The invention comprises compounds of the general formula:- in which R and R1 are C1-C4 alkyl groups, X is an oxygen or sulphur atom and Y is C1-C4 alkoxy, allyloxy, phenoxy, nitrophenoxy, mono-or dialkylamino with 1 to 4 carbon atoms in the alkyl groups, cycloalkylamino, anilino, pyrrolidino, piperidino, C1-C4 alkylmercapto, C1-C4 alkyl sulphonyl, phenylmercapto or phenyl sulphonyl group. They may be obtained by reacting a compound of the formula (RO) (R1O) P(X) Hal in which Hal is a halogen atom, e.g. chlorine, bromine, or iodine, and R, R1 and X are as defined above with a 1-substituted butene-(3)-ol-(2) of the formula HO.CH.(CH2Y).CH =CH2 in which Y is as defined above. The reation may be carried out in the presence of an inert organic diluent, e.g. an aromatic, aliphatic or cycloaliphatic hydrocarbon or an aliphatic chlorohydrocarbon and it is advantageous to effect the reaction in the presence of an agent which binds hydrogen halide, e.g. pyridine, aniline, methylaniline, triethylamine, tripropylamine or other amine whose boiling point is above the reaction temperature or an alkali metal carbonate or bicarbonate. The reaction is preferably effected at about 10 to 130 DEG C. e.g. at 15 to 75 DEG C. Examples are given for the production of compounds in which R and R1 are each ethyl, X is S and Y is -NHC3H7, N(C2H5)2, SC2H5, p.NH.C6H5. p.SO2C6H5, SO2C2H5, phenoxy, cyclooctylamino, pyrrolidine, p.S.C6H5, ethoxy, allyloxy, and p.nitrophenoxy respectively. Examples are also given for the production of (CH3O)2P(S)O.CH(CH2SC2H5) CH=CH2 and the corresponding O,O- diisopropyl and O,O-dibutyl compounds, (CH3O)2 P(O)O CH(CH2.O. C6H5)CH=CH2, (iso C3H7O)2 P(S)OCH (CH2S.C6H5) CH=CH2, and (C2H5O)2 P(O)O CH(CH2SC2H5)CH=CH2. The products have insecticidal properties.

公开(公告)号：US3326872A

公开(公告)日：1967-06-20

申请号：US41285564

申请日：1964-11-20

Applicant: BASF AG

Inventor： HEINZ WEBER ,  PAUL SCHNEIDER ,  SIEGFRIED WINDERL ,  ERICH FLICKINGER

IPC: C08F10/06

CPC classification number: C08F10/06 ,  C08F4/6293

公开(公告)号：US3297520A

公开(公告)日：1967-01-10

申请号：US15725461

申请日：1961-12-05

Applicant: BASF AG

Inventor： HEINER DICKHAEUSER ,  HEINZ POHLEMANN ,  HERBERT STUMMEYER ,  HEINRICH ADOLPHI ,  SIEGFRIED WINDERL

IPC: C07F9/165

CPC classification number: C07F9/1651