公开(公告)号：US09850348B2

公开(公告)日：2017-12-26

申请号：US14763642

申请日：2014-01-30

申请人： DSM IP ASSETS B.V.

发明人： Eric Grolman ,  Rudy Rulkens ,  Konraad Albert Louise Hector Dullaert ,  Renier Henricus Maria Kierkels ,  Geert Adelina Rudolf Vanden Poel

IPC分类号： C08G69/30 ,  C08G69/32 ,  C07C209/68 ,  C07C51/41 ,  C08G69/26 ,  C08L77/06 ,  C08L77/10

CPC分类号： C08G69/32 ,  C07C51/412 ,  C07C209/68 ,  C08G69/26 ,  C08G69/265 ,  C08G69/30 ,  C08L77/06 ,  C08L77/10 ,  C07C63/333 ,  C07C63/38 ,  C07C63/28 ,  C07C211/12 ,  C07C211/09

摘要： The invention relates to a process for preparing a semi-aromatic polyamide from diamine and dicarboxylic acid, comprising steps of •(i) dosing a liquid diamine to an agitated powder comprising an aromatic dicarboxylic acid thereby forming a powder comprising a diamine/dicarboxylic acid salt (DD-salt), and •(ii) solid-state polymerizing the DD-salt to obtain the polyamide.

公开(公告)号：US09783473B2

公开(公告)日：2017-10-10

申请号：US15195349

申请日：2016-06-28

申请人： Rennovia, Inc.

发明人： Eric L. Dias ,  James A. W. Shoemaker ,  Thomas R. Boussie ,  Vincent J. Murphy

IPC分类号： C07C29/157 ,  C07D307/46 ,  C07D307/50 ,  C07C29/132 ,  C07D307/48 ,  C07C29/17 ,  C07C29/141 ,  C07C209/16

CPC分类号： C07C29/157 ,  C07C29/132 ,  C07C29/141 ,  C07C29/175 ,  C07C209/16 ,  C07D307/46 ,  C07D307/48 ,  C07D307/50 ,  C07C31/20 ,  C07C31/22 ,  C07C211/12

摘要： Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1,6-hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1,6-hexanediol wherein 1,2,6-hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1,2,6-hexanediol is then converted by hydrogenation in the presence of a catalyst comprising Pt to 1,6 hexanediol, each process then proceeding to the production of HMDA by known routes, such as amination of the 1,6 hexanediol. Catalysts useful for the direct and indirect production of 1,6-hexanediol are also disclosed.

公开(公告)号：US20170165641A1

公开(公告)日：2017-06-15

申请号：US15441732

申请日：2017-02-24

申请人： Rennovia Inc.

发明人： Eric L. Dias ,  Alfred Hagemeyer ,  Hong X. Jiang ,  James Longmire ,  James A.W. Shoemaker ,  Valery Sokolovskii ,  Guang Zhu ,  Vincent J. Murphy ,  Gary M. Diamond

IPC分类号： B01J21/18 ,  C09C1/56 ,  C09C1/48

CPC分类号： B01J21/18 ,  B01J23/06 ,  B01J23/18 ,  B01J23/22 ,  B01J23/28 ,  B01J23/34 ,  B01J23/40 ,  B01J23/42 ,  B01J23/52 ,  B01J23/6567 ,  B01J23/70 ,  B01J23/755 ,  B01J23/892 ,  B01J35/002 ,  B01J35/008 ,  B01J35/0086 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/084 ,  B01J37/10 ,  C04B35/532 ,  C04B35/636 ,  C04B35/6365 ,  C04B35/638 ,  C04B38/0615 ,  C04B2111/0081 ,  C04B2235/424 ,  C04B2235/5409 ,  C04B2235/6586 ,  C04B2235/96 ,  C07C29/149 ,  C07C29/60 ,  C07C51/235 ,  C07C51/377 ,  C07C209/16 ,  C09C1/48 ,  C09C1/56 ,  C07C211/12 ,  C07C55/14 ,  C07C59/285 ,  C07C31/20 ,  C04B38/0054

摘要： Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.

公开(公告)号：US20170028386A1

公开(公告)日：2017-02-02

申请号：US15291786

申请日：2016-10-12

申请人： Rennovia Inc.

发明人： Vincent J. Murphy ,  James Shoemaker ,  Guang Zhu ,  Raymond Archer ,  George Frederick Salem ,  Eric L. Dias

IPC分类号： B01J23/52 ,  B01J21/06 ,  C07C51/235 ,  B01J35/00 ,  B01J37/02 ,  B01J37/18 ,  B01J21/08 ,  B01J29/06

CPC分类号： B01J23/52 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/42 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/0211 ,  B01J37/0236 ,  B01J37/0248 ,  B01J37/18 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C59/285 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

摘要： Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.

摘要翻译： 公开了由铂和金组成的催化剂。 催化剂通常可用于选择性氧化由伯醇基团和至少一个仲醇基团组成的组合物，其中至少伯醇基团转化为羧基。 更具体地说，催化剂是负载催化剂，包括包含金的颗粒和包含铂的颗粒，其中铂与金的摩尔比在约100:1至约1:4的范围内，铂基本上以Pt（0）的形式存在， 并且含铂颗粒的尺寸在约2至约50nm的范围内。 还公开了将碳水化合物转化为羧酸或其衍生物的氧化化学催化转化的方法。 此外，公开了使用包含铂和金的催化剂将葡萄糖选择性氧化成葡糖二酸或其衍生物的方法。 此外，公开了用于生产这种催化剂的方法。

公开(公告)号：US20160326092A1

公开(公告)日：2016-11-10

申请号：US15102947

申请日：2014-12-12

申请人： BASF SE

发明人： Christoph MÜLLER ,  Martin BOCK ,  Marion DA SILVA ,  Rolf-Hartmuth FISCHER ,  Benoit BLANK ,  Alois KINDLER ,  Johann-Peter MELDER ,  Bernhard OTTO ,  Mathias SCHELWIES ,  Andreas HENNINGER

IPC分类号： C07C209/16 ,  B01J27/19 ,  B01J25/02 ,  C07C29/17 ,  C07C209/86

CPC分类号： C07C209/16 ,  B01J25/02 ,  B01J27/19 ,  C07C29/177 ,  C07C209/86 ,  C07C31/20 ,  C07C211/12

摘要： The invention relates to a method for producing hexamethylenediamine, wherein a) a muconic acid starting material is provided, which is selected from among muconic acid, esters of muconic acid, lactones of muconic acid, and mixtures thereof, b) the muconic acid starting material is subjected to a reaction with hydrogen in the presence of at least one hydrogenation catalyst in order to form 1,6-hexanediol, and c) the 1,6-hexanediol obtained in step b) is subjected to amination in the presence of an amination catalyst in order to obtain hexamethylenediamine. The invention further relates to hexamethylenediamine which can be produced by means of said method.

摘要翻译： 本发明涉及一种生产六亚甲基二胺的方法，其中a）提供了一种粘康酸起始物质，其选自粘康酸，粘康酸的酯，粘康酸的内酯及其混合物，b）粘康酸起始物质 在至少一种氢化催化剂的存在下与氢反应以形成1,6-己二醇，和c）将步骤b）中获得的1,6-己二醇在胺化反应中进行胺化 催化剂以获得六亚甲基二胺。 本发明还涉及可以通过所述方法制备的六亚甲基二胺。

公开(公告)号：US09475753B2

公开(公告)日：2016-10-25

申请号：US14234248

申请日：2012-07-26

申请人： Eric Grolman ,  Rudy Rulkens

发明人： Eric Grolman ,  Rudy Rulkens

IPC分类号： C07C209/68 ,  C07C211/09 ,  C07C211/12 ,  C07C51/41 ,  C07C55/14 ,  C07C55/20 ,  C07C63/28

CPC分类号： C07C209/68 ,  C07B2200/13 ,  C07C51/412 ,  C07C55/14 ,  C07C55/20 ,  C07C63/28 ,  C07C211/09 ,  C07C211/12 ,  C08G69/04 ,  C08G69/265 ,  C07C63/24 ,  C07C63/26 ,  C07C63/36

摘要： The present invention also relates to a process for preparing a diamine/dicarboxylic acid salt wherein the dicarboxylic acid comprises an aromatic dicarboxylic acid and is provided in a powder form; the diamine is provided in a liquid form gradually dosed to the dicarboxylic acid powder, while keeping the dicarboxylic acid powder in constant movement; the processing temperature is above 0° C. and below the boiling temperature of the diamine and the melting temperature of the acid and the salt, and the reaction mixture comprises at most 5 wt. % of water. The present invention also relates to an anhydrous diamine/dicarboxylic acid salt obtainable by the process according to invention, or any embodiment thereof as described above.

摘要翻译： 本发明还涉及一种制备二胺/二羧酸盐的方法，其中二羧酸包括芳族二羧酸并以粉末形式提供; 二胺以逐渐递送到二羧酸粉末的液体形式提供，同时保持二羧酸粉末恒定运动; 处理温度高于0℃，低于二胺的沸点温度和酸和盐的熔融温度，反应混合物至多为5重量％。 ％的水。 本发明还涉及通过本发明的方法获得的无水二胺/二羧酸盐或其如上所述的任何实施方案。

公开(公告)号：US09469587B2

公开(公告)日：2016-10-18

申请号：US14748459

申请日：2015-06-24

申请人： Korea Kumho Petrochemical Co., Ltd.

发明人： Kee Yoon Roh ,  Jung Hee Jang ,  Je Young Park

IPC分类号： C07C239/22 ,  C07C39/15 ,  C09D7/12 ,  C07C211/09 ,  C07C211/10 ,  C07C211/11 ,  C07C211/12 ,  C08G59/62

CPC分类号： C07C39/15 ,  C07C211/09 ,  C07C211/10 ,  C07C211/11 ,  C07C211/12 ,  C08G59/621

摘要： A styrenated phenol compound in which a hydrazine or a diaminoalkane compound binds to a styrenated phenol, and a method of preparing the same are provided. The styrenated phenol compound may have improved exterior quality and storage stability of a product by maintaining a hardening stimulation property and plasticity and preventing discoloration when mixed with a hardener for an epoxy paint.

摘要翻译： 其中肼或二氨基烷烃化合物与苯乙烯化苯酚结合的苯乙烯化酚化合物及其制备方法。 苯乙烯化酚化合物可以通过保持硬化刺激性能和可塑性以及当与环氧涂料的固化剂混合时防止变色来改善产品的外部质量和储存稳定性。

公开(公告)号：US20160068470A1

公开(公告)日：2016-03-10

申请号：US14687894

申请日：2015-04-15

申请人： Rennovia, Inc.

发明人： Eric L. DIAS ,  James A. W. SHOEMAKER ,  Thomas R. BOUSSIE ,  Vincent J. MURPHY

IPC分类号： C07C209/16 ,  C07D307/46 ,  C07C29/157

CPC分类号： C07C29/157 ,  C07C29/132 ,  C07C29/141 ,  C07C29/175 ,  C07C209/16 ,  C07D307/46 ,  C07D307/48 ,  C07D307/50 ,  C07C31/20 ,  C07C31/22 ,  C07C211/12

摘要： Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1,6-hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1,6-hexanediol wherein 1,2,6-hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1,2,6-hexanediol is then converted by hydrogenation in the presence of a catalyst comprising Pt to 1,6 hexanediol, each process then proceeding to the production of HMDA by known routes, such as amination of the 1,6 hexanediol. Catalysts useful for the direct and indirect production of 1,6-hexanediol are also disclosed.

公开(公告)号：US20150376098A1

公开(公告)日：2015-12-31

申请号：US14748459

申请日：2015-06-24

申请人： Korea Kumho Petrochemical Co., Ltd.

发明人： Kee Yoon ROH ,  Jung Hee JANG ,  Je Young PARK

IPC分类号： C07C39/15 ,  C07C211/09 ,  C07C209/00 ,  C07C211/11 ,  C07C211/12 ,  C07C37/00 ,  C09D7/12 ,  C07C211/10

CPC分类号： C07C39/15 ,  C07C211/09 ,  C07C211/10 ,  C07C211/11 ,  C07C211/12 ,  C08G59/621

摘要： A styrenated phenol compound in which a hydrazine or a diaminoalkane compound binds to a styrenated phenol, and a method of preparing the same are provided. The styrenated phenol compound may have improved exterior quality and storage stability of a product by maintaining a hardening stimulation property and plasticity and preventing discoloration when mixed with a hardener for an epoxy paint.

摘要翻译： 其中肼或二氨基烷烃化合物与苯乙烯化苯酚结合的苯乙烯化酚化合物及其制备方法。 苯乙烯化酚化合物可以通过保持硬化刺激性能和可塑性以及当与环氧涂料的固化剂混合时防止变色来改善产品的外部质量和储存稳定性。

公开(公告)号：US09216937B2

公开(公告)日：2015-12-22

申请号：US13691588

申请日：2012-11-30

申请人： Rennovia, Inc.

发明人： Raymond Archer ,  Gary M. Diamond ,  Eric L. Dias ,  Vincent J. Murphy ,  Miroslav Petro ,  John D. Super

IPC分类号： C07C55/12 ,  C07C51/377 ,  C07C69/42 ,  C07C51/347 ,  C07C51/09 ,  C07C209/00 ,  C07C51/41

CPC分类号： C07C51/347 ,  C07C51/09 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C55/14 ,  C07C211/12

摘要： The present disclosure relates generally to water concentration reduction processes within an adipic acid process. The present invention also includes process for converting a glucose-containing feed derived from a carbohydrate source to an adipic acid product wherein the process includes the steps of: converting glucose in the feed to a reaction product including a hydrodeoxygenation substrate and a first concentration of water; reducing the concentration of water in the reaction product to produce a feedstock including the hydrodeoxygenation substrate and second concentration of water, wherein the second concentration of water is less than the first concentration of water; and converting at least a portion of the hydrodeoxygenation substrate in the feedstock to an adipic acid product. Processes are also disclosed for producing hexamethylene diamine and caprolactam from the adipic acid product.

摘要翻译： 本公开一般涉及己二酸方法中的水浓缩还原方法。 本发明还包括将衍生自碳水化合物源的含葡萄糖的饲料转化为己二酸产物的方法，其中该方法包括以下步骤：将饲料中的葡萄糖转化为包括加氢脱氧底物和第一浓度的水的反应产物 ; 降低反应产物中的水浓度以产生包括加氢脱氧底物和第二浓度的水的原料，其中第二浓度的水小于第一浓度的水; 并将原料中的至少一部分加氢脱氧底物转化为己二酸产物。 还公开了从己二酸产物制备己二胺和己内酰胺的方法。