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    Self-extinguishing thermoplastic compositions
    3.
    发明授权
    Self-extinguishing thermoplastic compositions 失效
    自消除热塑性组合物

    公开(公告)号：US3472799A

    公开(公告)日：1969-10-14

    申请号：US3472799D

    申请日：1966-07-18

    申请人： BASF AG

    发明人： BURGER HEINZ ,  DAUMILLER GUENTHER ,  GROHMANN JOHANNES ,  KASTNING ERNST-GUENTHER ,  MOHR HEINRICH ,  REUTER LOTHAR ,  WEBER HEINZ ,  WILLERSINN HERBERT

    IPC分类号： C08J9/00 ,  C08K5/02 ,  C08L25/02 ,  C08L25/04 ,  C08L25/06 ,  C08F47/10 ,  C09K3/28

    CPC分类号： C08J9/0095 ,  C08J2325/04 ,  C08K5/02 ,  C08K5/52 ,  C08L25/02 ,  C08L25/04 ,  C08L25/06 ,  Y10S521/907 ,  C08L2666/02 ,  C08L2666/04

    摘要： 1,147,684. Self-extinguishing thermoplastic compositions. BADISCHE ANILIN- & SODAFABRIK A.G. 19 July, 1966 [21 July, 1965], No. 32374/66. Headings C3C and C3P. A self-extinguishing composition consists of (a) a normally solid thermoplastic polymer or copolymer of styrene or substituted styrene which comprises at least 50% by wt. of the styrene or substituted styrene and less than 50% of one other olefinically unsaturated compound having intimately incorporated therewith (b) an organic bromide having a plurality of bromine atoms attached to carbon atoms and the bromine atoms making up more than 40% by wt. of the bromide, in such an amount that the composition has 0À1-5% wt. of bromine, and (c) 0À01-5% by wt. on (a) of a polymer consisting of repeating units of formula where R 1 is R 7 or XR 7 , R 7 is a C 1-6 aliphatic hydrocarbon, a phenylalkyl or phenyl radical which may be substituted by 1-5 chlorine atoms or a C 1-4 alkyl or alkoxy group and X is -O-, -CO- or -COO-; R 2 to R 6 are H, Cl or a C 1-4 alkyl or alkoxy group; and n is 3-200. The (a) polymer may be polystyrene or a copolymer of styrene and acrylonitrile. The (b) bromide may be hexabromocyclododecane or tris-(2,3-dibromopropyl) phosphate. The (c) polymer may be a polymerized diphenylmethane or ethylbenzene. The composition may be made by dissolving the three constituents in methylene chloride. The composition may also contain 3-10% of a foaming agent which is a volatile organic compound which does not dissolve the (a) polymer and has a boiling point below its softening point e.g. pentane, and may be foamed, e.g. in film form, using steam.

    Self-extinguishing thermoplastic compositions
    5.
    发明授权
    Self-extinguishing thermoplastic compositions 失效

    公开(公告)号：US3457204A

    公开(公告)日：1969-07-22

    申请号：US3457204D

    申请日：1966-07-08

    申请人： BASF AG

    发明人： BURGER HEINZ ,  DAUMILLER GUENTHER ,  GROHMANN JOHANNES ,  KASTNING ERNST-GUENTHER ,  WEBER HEINZ ,  WILLERSINN HERBERT

    IPC分类号： C08J9/00 ,  C08K5/00 ,  C08K5/02 ,  C08L25/04 ,  C08L65/00 ,  C08F31/04 ,  C08F47/08

    CPC分类号： C08J9/0095 ,  C08J2325/04 ,  C08K5/00 ,  C08K5/02 ,  C08L25/04 ,  C08L25/16 ,  C08L25/18 ,  C08L65/00 ,  Y10S521/907 ,  C08L2666/04

    摘要： 1,146,653. Self-extinguishing polymeric compositions. BADISCHE ANILIN- & SODAFABRIK A.G. 7 July, 1966 [9 July, 1965], No. 30552/66. Headings C3C and C3P. A self-extinguishing composition consists of (a) a normally solid thermoplastic polymer of at least 50% by wt. of styrene which may be substituted, and less than 50% of at least one other copolymerizable compound having the group having intimately incorporated therewith (b) an organic bromide, having a plurality of bromine atoms attached to carbon atoms and the bromine atoms constituting more than 40% of the bromide, in such an amount that the composition has a bromine content of 0À1-5%, and (c) 0À01-5% of (a) of a polymer which is prepared from (i) a compound of formula where R 1 , R 2 , R 4 and R 5 are H, halogen or a C 1-4 aliphatic hydrocarbon radical and at least two of the above Rs are where R 7 is a C 1-4 linear aliphatic hydrocarbon radical and R 8 is H or R 7 , and R 3 and R 6 are H or halogen atoms; or (ii) a mixture of the above compounds and a compound of the same formula where R 1 is where R 7 and R 8 are as before and the remaining Rs are H or halogen atoms. The (a) polymer may be polystyrene, a copolymer of styrene and acrylonitrile together with optionally polybutadiene, or a polymer obtained by polymerizing styrene in the presence of polybutadiene. Polymer (c) may be prepared by dehydropolymerization of p- or m-diisopropylbenzene with optionally isopropylbenzene, or 1,2,4-tri- or 1,2,4,5-tetra-isopropylbenzene. The bromide (b) may be hexabromocyclododecane or tris - (2,3 - dibromopropyl) - phosphate. The composition may be made by dissolving the three components in methylene chloride or by extruding the three components, with optionally kaolin; or by polymerizing styrene in the presence of an aq. mixture of polyvinylpyrrolidone, sodium pyrophosphate, benzoyl peroxide and the above (b) and (c) components. The composition may also contain a foaming agent, e.g. pentane or methyl chloride, and may be formed into a foamed sheet or strand.