公开(公告)号：US20040053772A1

公开(公告)日：2004-03-18

申请号：US10243669

申请日：2002-09-16

Applicant: BASF Aktiengesellschaft

Inventor： Ulrich Muller ,  Georg Kurg ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Henrique Teles

IPC: B01J029/04 ,  C01B033/36

CPC classification number: C07D301/12 ,  B01J29/89

Abstract: The present invention relates to the manufacture of solid materials or shaped bodies containing at least one zeolite and being at least partly crystalline. Furthermore, the present invention relates to the solid materials or shaped bodies as such and to the use of these materials for reactions of compounds having at least one CnullC double bond with at least one hydroperoxide. Specifically, the present invention relates to a process for the manufacture of a solid material containing at least one zeolite and being at least partly crystalline, wherein the synthesis of the said solid material involves at least one partial step of contacting at least one transition metal oxide source with at least one epoxide or hydrolysate thereof prior to or during the at least partial crystallization of said solid material.

Abstract translation: 本发明涉及包含至少一种沸石并且至少部分结晶的固体材料或成形体的制造。 此外，本发明还涉及固体材料或成形体，以及这些材料用于具有至少一个C-C双键的化合物与至少一种氢过氧化物的反应的用途。 具体地说，本发明涉及制造含有至少一种沸石并且至少部分结晶的固体材料的方法，其中所述固体材料的合成涉及至少一个部分步骤，使至少一种过渡金属氧化物 来源，其在所述固体材料的至少部分结晶之前或期间具有至少一种环氧化物或水解产物。

公开(公告)号：US20030166975A1

公开(公告)日：2003-09-04

申请号：US10309253

申请日：2002-12-04

Applicant: BASF Aktiengesellschaft

Inventor： Joaquim Henrique Teles

IPC: C07C041/03 ,  C07F015/00

CPC classification number: C07F15/065

Abstract: Process for preparing 1-methoxy-2-propanol by reacting propylene oxide with methanol in the presence of a racemic catalyst which comprises an asymmetric polydentate (tetradentate) ligand complexed with a metal atom, where the complex has an approximately planar geometry.

Abstract translation: 在外消旋催化剂存在下，使环氧丙烷与甲醇反应制备1-甲氧基-2-丙醇的方法，该外消旋催化剂包含与金属原子络合的不对称多齿（四齿）配体，其中复合物具有近似平面的几何形状。

公开(公告)号：US20040054199A1

公开(公告)日：2004-03-18

申请号：US10244527

申请日：2002-09-17

Applicant: BASF Aktiengesellschaft

Inventor： Ulrich Muller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Henrique Teles

IPC: C07D301/03

CPC classification number: C07D301/19 ,  B01J29/89 ,  B01J37/10 ,  B01J2229/36 ,  B01J2229/40 ,  C07D301/12 ,  Y02P20/125

Abstract: The present invention relates to a process for treating a solid material containing at least one zeolite and being at least partly crystalline or treating a shaped body obtained from said solid material wherein said solid material or shaped body is brought in contact with a composition containing water after at least one of the following steps of an integrated process for producing a solid material or a shaped body containing at least one zeolite: (i) after step (II) of separating the at least partly crystalline solid material from its mother liquor or (ii) after step (S) of shaping said solid material into a shaped body or (iii) after a step (C) of calcining said solid material or said shaped body. The present invention furthermore relates to the solid material obtainable by the inventive process and the shaped body obtainable by the inventive process. The present invention finally relates to the use of the solid material or the shaped body as mentioned above as a catalyst in chemical reactions, in particular in reactions of compounds containing at least one CnullC double bond with at least one hydroperoxide.

Abstract translation: 本发明涉及一种用于处理含有至少一种沸石并且至少部分结晶的固体材料或处理由所述固体材料获得的成形体的方法，其中所述固体材料或成形体与含有水的组合物接触 用于生产固体材料或含有至少一种沸石的成形体的整合方法中的至少一个步骤：（i）在从母液中分离出至少部分结晶固体材料的步骤（II）之后，或（ii ）在将所述固体材料成形为成形体的步骤（S）之后或（iii）在煅烧所述固体材料或所述成形体的步骤（C）之后。 本发明还涉及可通过本发明方法获得的固体材料和通过本发明方法获得的成形体。 本发明最终涉及如上所述的固体材料或成形体作为化学反应中的催化剂，特别是在含有至少一个C-C双键的化合物与至少一种氢过氧化物的反应中的应用。