公开(公告)号：US20040265670A1

公开(公告)日：2004-12-30

申请号：US10608146

申请日：2003-06-30

Applicant: BASF Aktiengesellschaft ,  University of Michigan

Inventor： Ulrich Muller ,  Michael Hesse ,  Reinhard Hess ,  Rainer Senk ,  Markus Hoelzle ,  Omar M. Yaghi

IPC: H01M008/04 ,  B65D085/00

CPC classification number: H01M8/04216 ,  B01J20/226 ,  C01B3/0015 ,  F17C11/005 ,  F17C2221/033 ,  F17C2223/035 ,  F17C2223/036 ,  F17C2270/0763 ,  H01M8/04208 ,  Y02C10/08 ,  Y02E60/321 ,  Y02E60/327 ,  Y02E60/328 ,  Y10S502/526

Abstract: The present invention relates to a container for uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing, or uptaking, storing and releasing at least one gas, comprising at least one opening for allowing the at least one gas to enter and exit or at least one opening for allowing the at least one gas to enter and at least one opening for allowing the at least one gas to exit said container, and a gas-tight mechanism capable of storing the at least one gas under a pressure of from greater than 45 to 750 bar inside the container, said container further comprising a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound which is bound to said metal ion, as well as to a fuel cell comprising said container, and to a method of using said container or said fuel cell for supplying power to power plants, cars, trucks, busses, cell phones, and laptops.

Abstract translation: 本发明涉及一种用于吸收或储存或释放，吸收和储存或吸收和释放或储存和释放或吸收至少一种气体的容器，该容器包括至少一个开口，以允许 至少一个进入和离开的气体或用于允许至少一个气体进入的至少一个开口和用于允许至少一个气体离开所述容器的至少一个开口，以及能够将所述至少一个气体储存在所述容器中的气密机构 所述容器还包括金属 - 有机骨架材料，所述金属 - 有机骨架材料包含孔和至少一种金属离子和至少一种至少二齿有机化合物，所述至少二齿有机化合物与所述 金属离子，以及包括所述容器的燃料电池，以及使用所述容器或所述燃料电池向发电厂，汽车，卡车，公共汽车，手机和笔记本电脑供电的方法。

公开(公告)号：US20040053772A1

公开(公告)日：2004-03-18

申请号：US10243669

申请日：2002-09-16

Applicant: BASF Aktiengesellschaft

Inventor： Ulrich Muller ,  Georg Kurg ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Henrique Teles

IPC: B01J029/04 ,  C01B033/36

CPC classification number: C07D301/12 ,  B01J29/89

Abstract: The present invention relates to the manufacture of solid materials or shaped bodies containing at least one zeolite and being at least partly crystalline. Furthermore, the present invention relates to the solid materials or shaped bodies as such and to the use of these materials for reactions of compounds having at least one CnullC double bond with at least one hydroperoxide. Specifically, the present invention relates to a process for the manufacture of a solid material containing at least one zeolite and being at least partly crystalline, wherein the synthesis of the said solid material involves at least one partial step of contacting at least one transition metal oxide source with at least one epoxide or hydrolysate thereof prior to or during the at least partial crystallization of said solid material.

Abstract translation: 本发明涉及包含至少一种沸石并且至少部分结晶的固体材料或成形体的制造。 此外，本发明还涉及固体材料或成形体，以及这些材料用于具有至少一个C-C双键的化合物与至少一种氢过氧化物的反应的用途。 具体地说，本发明涉及制造含有至少一种沸石并且至少部分结晶的固体材料的方法，其中所述固体材料的合成涉及至少一个部分步骤，使至少一种过渡金属氧化物 来源，其在所述固体材料的至少部分结晶之前或期间具有至少一种环氧化物或水解产物。

公开(公告)号：US20040054199A1

公开(公告)日：2004-03-18

申请号：US10244527

申请日：2002-09-17

Applicant: BASF Aktiengesellschaft

Inventor： Ulrich Muller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Henrique Teles

IPC: C07D301/03

CPC classification number: C07D301/19 ,  B01J29/89 ,  B01J37/10 ,  B01J2229/36 ,  B01J2229/40 ,  C07D301/12 ,  Y02P20/125

Abstract: The present invention relates to a process for treating a solid material containing at least one zeolite and being at least partly crystalline or treating a shaped body obtained from said solid material wherein said solid material or shaped body is brought in contact with a composition containing water after at least one of the following steps of an integrated process for producing a solid material or a shaped body containing at least one zeolite: (i) after step (II) of separating the at least partly crystalline solid material from its mother liquor or (ii) after step (S) of shaping said solid material into a shaped body or (iii) after a step (C) of calcining said solid material or said shaped body. The present invention furthermore relates to the solid material obtainable by the inventive process and the shaped body obtainable by the inventive process. The present invention finally relates to the use of the solid material or the shaped body as mentioned above as a catalyst in chemical reactions, in particular in reactions of compounds containing at least one CnullC double bond with at least one hydroperoxide.

Abstract translation: 本发明涉及一种用于处理含有至少一种沸石并且至少部分结晶的固体材料或处理由所述固体材料获得的成形体的方法，其中所述固体材料或成形体与含有水的组合物接触 用于生产固体材料或含有至少一种沸石的成形体的整合方法中的至少一个步骤：（i）在从母液中分离出至少部分结晶固体材料的步骤（II）之后，或（ii ）在将所述固体材料成形为成形体的步骤（S）之后或（iii）在煅烧所述固体材料或所述成形体的步骤（C）之后。 本发明还涉及可通过本发明方法获得的固体材料和通过本发明方法获得的成形体。 本发明最终涉及如上所述的固体材料或成形体作为化学反应中的催化剂，特别是在含有至少一个C-C双键的化合物与至少一种氢过氧化物的反应中的应用。

公开(公告)号：US20040014591A1

公开(公告)日：2004-01-22

申请号：US10301607

申请日：2002-11-22

Applicant: BASF Aktiengesellschaft

Inventor： Ulrich Muller ,  Hartwig Voss ,  Erich Schubert ,  Friedrich Hill ,  Hermann Petersen

IPC: B01J029/06

CPC classification number: C01B21/1409 ,  B01J29/04 ,  B01J29/06 ,  B01J29/89 ,  C01B39/026 ,  C07C239/08 ,  C07C249/04 ,  C07D301/12

Abstract: In a process for concentrating an at least partially crystalline solid containing at least one zeolite in a mixture comprising at least one auxiliary, for example a template compound, and said solid, the mixture is ultrafiltrated in a step (II) to divide the mixture into a retentate and a permeate, the solids content in the retentate being higher than that in the mixture and the solids content in the permeate being lower than that in the mixture. This procedure allows auxiliaries, in particular template compounds, present in the permeate to be recycled into a crystallizing step (I) upstream of step (II).

Abstract translation: 在将包含至少一种沸石的至少部分结晶的固体在包含至少一种助剂例如模板化合物和所述固体的混合物中浓缩的方法中，在步骤（II）中将混合物超滤以将混合物分成 渗余物和渗透物，渗余物中的固体含量高于混合物中的固体含量，并且渗透物中的固体含量低于混合物中的固体含量。 该方法允许存在于渗透物中的助剂，特别是模板化合物再循环到步骤（II）上游的结晶步骤（I）中。