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公开(公告)号：US10283761B2
公开(公告)日：2019-05-07
申请号：US15524400
申请日：2015-11-02
Applicant: BASF SE
Inventor： Ivana Krkljus , Aleksei Volkov , Carsten Sueling
IPC: H01M4/36 , H01M4/58 , H01M10/0525 , H01M2/16 , H01M4/62 , H01M10/0569 , H01M4/02
Abstract: Electrode material comprising (a) at least one compound of general formula (I) LiFe(1-y)M1yPO4 (I) y is in the range of from zero to 0.4 M1 is at least one element selected from Co, Mn, Ni, V, Mg, Nd, Zn and Y, that contains at least one further iron-phosphorous compound, and in the range of from 0.05 to 0.25% by weight of sulphur and in the range of from 0.003 to 0.5% by weight of Ti, (b) carbon in electrically conductive modification.
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公开(公告)号：US11670760B2
公开(公告)日：2023-06-06
申请号：US16808650
申请日：2020-03-04
Applicant: BASF SE
Inventor： Aleksei Volkov , Martin Schulz-Dobrick , Simon Schroedle , Jordan Lampert
CPC classification number: H01M4/364 , C01G53/50 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/623 , H01M4/625 , H01M10/0525 , C01P2004/50 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/11 , C01P2006/12 , C01P2006/14 , C01P2006/40 , H01M2004/028
Abstract: The present invention is directed towards a process for making a lithiated transition metal oxide, said process comprising the following steps:
(a) providing a precursor selected from mixed oxides, hydroxides, oxyhydroxides, and carbonates of nickel and at least one transition metal selected from manganese and cobalt, wherein at least 45 mole-% of the cations of the precursor are Ni cations,
(b) mixing said precursor with at least one lithium salt selected from LiOH, Li2O, Li2CO3, and LiNO3, thereby obtaining a mixture,
(c) adding at least one phosphorus compound of general formula (I)
XyH3-yPO4 (I)
wherein
X is selected from NH4 and Li,
y is 1 or 2,
to the mixture obtained in step (b),
wherein steps (b) and (c) may be performed consecutively or simultaneously,
(d) treating the mixture so obtained at a temperature in the range of from 650 to 950° C.-
Patent Agency Ranking
公开(公告)号：US10446833B2
公开(公告)日：2019-10-15
申请号：US15023046
申请日：2014-09-16
Applicant: BASF SE
Inventor： Ivana Krkljus , Aleksei Volkov , Carsten Sueling
IPC: H01M4/36 , H01M4/131 , H01M4/136 , H01M4/505 , H01M4/525 , H01M4/58 , H01M4/62 , C01G49/00 , C01G53/00 , C01D15/02 , H01M10/0525 , H01M4/02
Abstract: Electrode materials comprising (a) at least one compound of general formula (I) Li(1+x)[NiaCObMncM1d](1-x)O2 (I) the integers being defined as follows: x is in the range of from 0.01 to 0.05, a is in the range of from 0.3 to 0.6, b is in the range of from zero to 0.35, c is in the range of from 0.2 to 0.6, d is in the range of from zero to 0.05, a+b+c+d=1 M1 is at least one metal selected from Ca, Zn, Fe, Ti, Ba, Al, (b) at least one compound of general formula (II) LiFe(1-x)M2yPO4 (II) y is in the range of from zero to 0.8 M2 is at least one element selected from Ti, Co, Mn, Ni, V, Mg, Nd, Zn and Y, that contains at least one further iron-phosphorous compound, in form of a solid solution in compound (b) or in domains, (c) carbon in electrically conductive modification.
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公开(公告)号：US11165063B2
公开(公告)日：2021-11-02
申请号：US16509749
申请日：2019-07-12
Applicant: BASF SE
Inventor： Aleksei Volkov , Jordan Lampert , Thomas Michael Ryll , Ji-Yong Shin , Markus Hoelzle , Michael Eder
IPC: H01M4/02 , H01M4/525 , H01M10/0567 , H01M10/42 , C01G53/00 , H01M4/131 , H01M4/505 , H01M10/0525 , H01M10/052
Abstract: Process for making a particulate material of general formula (I), Li1+x(NiaCobMncMd)1−xO2 (I) wherein the integers are defined as follows: M is selected from Al and Ti, x is in the range of from 0.015 to 0.03, a is in the range of from 0.3 to 0.6, b is in the range of from 0.05 to 0.35, c is in the range of from 0.2 to 0.5, d is in the range of from 0.001 to 0.03, with a+b+c+d=1 said process comprising the following steps: (a) co-precipitating a mixed hydroxide of nickel, cobalt and manganese from a solution of water-soluble salts of nickel, cobalt and manganese by contacting such solution with a solution of alkali metal hydroxide, (b) adding an aqueous solution of an aluminate or titanate and thereby co-precipitating a layer of a mixed hydroxide of nickel and cobalt and manganese and aluminium or titanium on the particles formed in step (a), (c) removing particles of (NiaCobMncAld)(OH)2+d or (NiaCobMncTid)(OH)2+2d so obtained and drying them in the presence of oxygen, (d) mixing the particles obtained in step (c) with at least one Li compound selected from Li2O, LiOH and Li2CO3, (e) calcining the mixture obtained according to step (d) at a temperature in the range of from 920 to 950° C.
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公开(公告)号：US10707486B2
公开(公告)日：2020-07-07
申请号：US15751308
申请日：2016-08-10
Applicant: BASF SE
Inventor： Simon Schroedle , Thomas Michael Ryll , Aleksei Volkov , Ji-Yong Shin , Jordan K. Lampert
IPC: H01M4/52 , H01M4/525 , C01G53/00 , H01M4/505 , H01M4/131 , C01G53/04 , H01M10/0525 , H01M10/0567 , H01M10/42 , H01M10/052 , H01M4/02
Abstract: The present invention is directed towards a process for making a particulate material according to the general formula (I): NiaCObMncMd(O)x(OH)y, wherein M is selected from Al and Ti, x is in the range of from 0.01 to 0.9, y is in the range of from 1.1 to 1.99, a is in the range of from 0.3 to 0.85, b is in the range of from 0.05 to 0.4, c is in the range of from 0.1 to 0.5, d is in the range of from 0.001 to 0.03, with a+b+c+d=1 said process comprising the following steps: (a) providing an aqueous slurry of particles of aluminum hydroxide or titanium dioxide, (b) adding an aqueous solution of water-soluble salts of nickel, cobalt and manganese and a solution of alkali metal hydroxide to the slurry according to step (a), thereby co-precipitating a layer of a mixed hydroxide of nickel and cobalt and manganese hydroxide on the particles according to step (a), (c) removing particles of (NiaCObMncAld)(OH)2+d or (NiaCObMncTid)(OH)2+2d so obtained and drying them in the presence of oxygen.
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公开(公告)号：US10468678B2
公开(公告)日：2019-11-05
申请号：US15318887
申请日：2015-06-19
Applicant: BASF SE
Inventor： Aleksei Volkov , Jordan Lampert , Thomas Michael Ryll , Ji-Yong Shin , Markus Hoelzle , Michael Eder
IPC: H01M4/02 , H01M4/525 , H01M10/0567 , H01M10/42 , C01G53/00 , H01M4/505 , H01M10/0525
Abstract: Process for making a particulate material of general formula (I), wherein the integers are defined as follows: M is selected from Al and Ti, x is in the range of from 0.015 to 0.03, a is in the range of from 0.3 to 0.6, b is in the range of from 0.05 to 0.35, c is in the range of from 0.2 to 0.5, d is in the range of from 0.001 to 0.03, with a+b+c+d=1 said process comprising the following steps: (a) co-precipitating a mixed hydroxide of nickel, cobalt and manganese from a solution of water-soluble salts of nickel, cobalt and manganese by contacting such solution with a solution of alkali metal hydroxide, (b) adding an aqueous solution of an aluminate or titanate and thereby co-precipitating a layer of a mixed hydroxide of nickel and cobalt and manganese and aluminum or titanium on the particles formed in step (a), (c) removing particles of (Nia Cob Mnc Ald)(OH)2+d or (Nia Cob Mnc Tid)(OH)2+2d so obtained and drying them in the presence of oxygen, (d) mixing the particles obtained in step (c) with at least one Li compound selected from Li2O, LiOH and Li2CO3, (e) calcining the mixture obtained according to step (d) at a temperature in the range of from 920 to 950° C.
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公开(公告)号：US10026954B2
公开(公告)日：2018-07-17
申请号：US14770147
申请日：2014-06-30
Applicant: BASF SE
Inventor： Ivana Krkljus , Aleksei Volkov , Carsten Sueling
Abstract: Electrode materials comprising (a) at least one component of general formula (I) Li(1+x)[NiaCObMncM1d](1−x)O2 (I) the integers being defined as follows: x is in the range of from 0.01 to 0.05, a is in the range of from 0.3 to 0.6, b is in the range of from zero to 0.35, c is in the range of from 0.2 to 0.6, d is in the range of from zero to 0.05, a+b+c+d=1 M1 is at least one metal selected from Ca, Zn, Fe, Ti, Ba, Al, (b) at least one component of general formula (II) LiFe(1−y)M2yPO4.m lithium phosphate (II) y is in the range of from zero to 0.8 M2 is at least one element selected from Co, Mn, Ni, V, Mg, Nd, Zn, and Y, m is selected from 0.01 to 0.15 (c) carbon in electrically conductive modification.
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