公开(公告)号：US20140065040A1

公开(公告)日：2014-03-06

申请号：US14018520

申请日：2013-09-05

Applicant: BASF SE

Inventor： Torsten Katz ,  Karsten Bartling

IPC: B01D53/40

CPC classification number: B01D53/40 ,  B01D53/1418 ,  B01D53/1425 ,  B01D53/1456 ,  B01D53/1493 ,  B01D2252/204 ,  B01D2257/30 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2258/05 ,  C10L3/102

Abstract: A process for separating off acid gases from a water-comprising fluid stream wherein the water-comprising fluid stream is contacted in an absorption zone with an absorbent, producing a deacidified fluid stream and an acid gas-loaded absorbent; the deacidified fluid stream is contacted in a scrubbing zone with an aqueous scrubbing liquid, producing a deaminated, deacidified fluid stream and an amine-loaded scrubbing liquid which is cooled, producing an absorber top condensate; the loaded absorbent is passed into a desorption zone producing a regenerated absorbent and desorbed acid gases; the regenerated absorbent is returned to the absorption zone in order to form an absorbent circuit, to which the amine-loaded scrubbing liquid and the absorber top condensate are introduced; and the desorbed acid gases are conducted through an enrichment zone and the acid gases exiting at the top of the enrichment zone are cooled, producing a desorber top condensate.

Abstract translation: 一种从含水流体物流中分离酸性气体的方法，其中含水流体物流在吸收区域与吸收剂接触，产生脱酸流体物流和含酸性气体的吸收剂; 脱水流体流在洗涤区与含水洗涤液体接触，产生脱氨基脱酸流体物流和冷却的胺负载洗涤液体，产生吸收塔顶部冷凝物; 负载的吸收剂进入解吸区，产生再生吸收剂和解吸的酸性气体; 再生的吸收剂返回到吸收区，以形成引入胺负载的洗涤液和吸收塔顶部冷凝物的吸收回路; 并且解吸的酸性气体通过富集区域传导，并且在富集区域顶部排出的酸性气体被冷却，产生解吸顶部冷凝物。

公开(公告)号：US09295942B2

公开(公告)日：2016-03-29

申请号：US14018520

申请日：2013-09-05

Applicant: BASF SE

Inventor： Torsten Katz ,  Karsten Bartling

IPC: B01D53/14 ,  B01D53/40 ,  C10L3/10

CPC classification number: B01D53/40 ,  B01D53/1418 ,  B01D53/1425 ,  B01D53/1456 ,  B01D53/1493 ,  B01D2252/204 ,  B01D2257/30 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2258/05 ,  C10L3/102

Abstract: A process for separating off acid gases from a water-comprising fluid stream wherein the water-comprising fluid stream is contacted in an absorption zone with an absorbent, producing a deacidified fluid stream and an acid gas-loaded absorbent; the deacidified fluid stream is contacted in a scrubbing zone with an aqueous scrubbing liquid, producing a deaminated, deacidified fluid stream and an amine-loaded scrubbing liquid which is cooled, producing an absorber top condensate; the loaded absorbent is passed into a desorption zone producing a regenerated absorbent and desorbed acid gases; the regenerated absorbent is returned to the absorption zone in order to form an absorbent circuit, to which the amine-loaded scrubbing liquid and the absorber top condensate are introduced; and the desorbed acid gases are conducted through an enrichment zone and the acid gases exiting at the top of the enrichment zone are cooled, producing a desorber top condensate.

Abstract translation: 一种从含水流体物流中分离酸性气体的方法，其中含水流体物流在吸收区域与吸收剂接触，产生脱酸流体物流和含酸性气体的吸收剂; 脱水流体流在洗涤区与含水洗涤液体接触，产生脱氨基脱酸流体物流和冷却的胺负载洗涤液体，产生吸收塔顶部冷凝物; 负载的吸收剂进入解吸区，产生再生吸收剂和解吸的酸性气体; 再生的吸收剂返回到吸收区，以形成引入胺负载的洗涤液和吸收塔顶部冷凝物的吸收回路; 并且解吸的酸性气体通过富集区域传导，并且在富集区域顶部排出的酸性气体被冷却，产生解吸顶部冷凝物。

公开(公告)号：US20130259789A1

公开(公告)日：2013-10-03

申请号：US13782290

申请日：2013-03-01

Applicant: BASF SE ,  RESEARCH TRIANGLE INSTITUTE

Inventor： Torsten Katz ,  Christian Riemann ,  Karsten Bartling ,  Sean Taylor Rigby ,  Luke James Ivor Coleman ,  Marty Alan Lail

IPC: B01D53/50

CPC classification number: B01D53/507

Abstract: A process for removing sulphur oxides from a fluid stream, such as flue gas, that comprises a) providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the non-aqueous absorption liquid being incompletely miscible with water: b) treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex: c) causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; d) separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Abstract translation: 一种从流体流如烟道气中除去硫氧化物的方法，其包括：a）提供含有至少一种疏水性胺的非水性吸收液体，所述非水性吸收液体与水不完全混溶：b） 吸收区中的流体物流与非水吸收液体一起将至少部分硫氧化物转移到非水吸收液体中并形成硫氧化物疏水胺络合物：c）使非水吸收液体 与水性液体液液接触，由此至少部分硫氧化物 - 疏水胺络合物被水解以释放疏水性胺和亚硫酸水解产物，并且至少部分硫代水解产物转移到水性 液体; d）将水性液体与非水性吸收液体分离。 该过程减轻了烟气中二氧化硫和氧气引起的吸收降解问题。

公开(公告)号：US09073826B2

公开(公告)日：2015-07-07

申请号：US13687156

申请日：2012-11-28

Applicant: BASF SE

Inventor： Klaus Ebel ,  Tobias Voitl ,  Andreas Keller ,  Stefan Rüdenauer ,  Karsten Bartling ,  Bjorn Langlotz ,  Jochen Steiner

IPC: C07C303/22 ,  C07C309/15 ,  C07C303/32 ,  C07C303/44

CPC classification number: C07C303/22 ,  C07C303/32 ,  C07C303/44 ,  C07C309/15

Abstract: A process for preparing salts of acrylamido-2-methylpropanesulfonic acid (A) using the steps of: preparing a solution of a contaminated salt of acrylamido-2-methyl-propanesulfonic acid (A) in an anhydrous organic solvent (L) using at least one basic component (B) selected from the group of alkali metal oxides, alkaline earth metal oxides, alkali metal hydroxides, alkaline earth metal hydroxides and amines of the formula (I) NRaRbRc  (I) where the Ra, Rb and Rc radicals are each independently: hydrogen, C1-C4-alkyl, hydroxy-C1-C4-alkyl or C1-C4-alkoxy, where the molar ratio of compound (A) to the basic component (B) is 1:1 to 1:3, recovering the dissolved salt of compound (A) by crystallization or by precipitation, by altering the temperature and/or the pressure and/or the concentration of the salt in the solution. This leads to salts which are low in by-products and are particularly suitable for polymerization.

Abstract translation: 一种使用以下步骤制备丙烯酰氨基-2-甲基丙磺酸（A）的盐的方法：使用至少在无水有机溶剂（L）中制备丙烯酰胺基-2-甲基 - 丙磺酸（A）的污染盐的溶液 选自碱金属氧化物，碱土金属氧化物，碱金属氢氧化物，碱土金属氢氧化物和式（I）NRaRbRc（I）的胺的一种碱性组分（B），其中R a，R b和R c基团各自为 独立地：氢，C1-C4-烷基，羟基-C1-C4-烷基或C1-C4-烷氧基，其中化合物（A）与碱性组分（B）的摩尔比为1:1至1:3，回收 化合物（A）的溶解盐通过结晶或沉淀，改变溶液中盐的温度和/或压力和/或浓度。 这导致副产物低的盐，特别适用于聚合。

公开(公告)号：US08691171B2

公开(公告)日：2014-04-08

申请号：US13782290

申请日：2013-03-01

Applicant: BASF SE ,  Research Triangle Institute

Inventor： Torsten Katz ,  Christian Riemann ,  Karsten Bartling ,  Sean Taylor Rigby ,  Luke James Ivor Coleman ,  Marty Alan Lail

IPC: B01D53/50

CPC classification number: B01D53/507

Abstract: A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Abstract translation: 一种从流体物流如烟道气中除去硫氧化物的方法，包括：提供含有至少一种疏水性胺的非水性吸收液体，该液体与水不完全混溶; 用非水吸收液处理吸收区中的流体物流，将至少部分硫氧化物转移到非水吸收液体中并形成硫氧化物疏水性胺络合物; 使得非水性吸收液体与水性液体液液接触，由此至少部分硫氧化物 - 疏水性胺络合物被水解以释放疏水性胺和亚硫酸盐水解产物，并且至少部分硫化物 水解产物转移到水性液体中; 从非水性吸收液中分离含水液体。 该过程减轻了烟气中二氧化硫和氧气引起的吸收降解问题。

公开(公告)号：US20130137893A1

公开(公告)日：2013-05-30

申请号：US13687156

申请日：2012-11-28

Applicant: BASF SE

Inventor： Klaus Ebel ,  Tobias Voitl ,  Andreas Keller ,  Stefan Rüdenauer ,  Karsten Bartling ,  Bjorn Langlotz ,  Jochen Steiner

IPC: C07C303/22 ,  C07C309/15

CPC classification number: C07C303/22 ,  C07C303/32 ,  C07C303/44 ,  C07C309/15

Abstract: A process for preparing salts of acrylamido-2-methylpropanesulfonic acid (A) using the steps of: preparing a solution of a contaminated salt of acrylamido-2-methyl-propanesulfonic acid (A) in an anhydrous organic solvent (L) using at least one basic component (B) selected from the group of alkali metal oxides, alkaline earth metal oxides, alkali metal hydroxides, alkaline earth metal hydroxides and amines of the formula (I) NRaRbRc  (I) where the Ra, Rb and Rc radicals are each independently: hydrogen, C1-C4-alkyl, hydroxy-C1-C4-alkyl or C1-C4-alkoxy, where the molar ratio of compound (A) to the basic component (B) is 1:1 to 1:3, recovering the dissolved salt of compound (A) by crystallization or by precipitation, by altering the temperature and/or the pressure and/or the concentration of the salt in the solution. This leads to salts which are low in by-products and are particularly suitable for polymerization.

Abstract translation: 一种使用以下步骤制备丙烯酰氨基-2-甲基丙磺酸（A）的盐的方法：使用至少在无水有机溶剂（L）中制备丙烯酰氨基-2-甲基 - 丙磺酸（A）的污染盐的溶液 选自碱金属氧化物，碱土金属氧化物，碱金属氢氧化物，碱土金属氢氧化物和式（I）NRaRbRc（I）的胺的一种碱性组分（B），其中R a，R b和R c基团各自为 独立地：氢，C1-C4-烷基，羟基-C1-C4-烷基或C1-C4-烷氧基，其中化合物（A）与碱性组分（B）的摩尔比为1:1至1:3，回收 化合物（A）的溶解盐通过结晶或沉淀，改变溶液中盐的温度和/或压力和/或浓度。 这导致副产物低的盐，特别适用于聚合。