公开(公告)号：US20150360210A1

公开(公告)日：2015-12-17

申请号：US14834947

申请日：2015-08-25

Applicant: BASF SE

Inventor： Guido Henze ,  Heiko Urtel ,  Martin Sesing ,  Martin Karches ,  Peter Van Den Abeel ,  Kai Thiele

IPC: B01J23/96 ,  C01B7/04 ,  B01J23/46 ,  B01J38/68 ,  B01J21/20 ,  B01J21/04

CPC classification number: B01J23/96 ,  B01J21/04 ,  B01J21/20 ,  B01J23/462 ,  B01J23/892 ,  B01J23/8933 ,  B01J35/023 ,  B01J35/10 ,  B01J37/0201 ,  B01J38/42 ,  B01J38/54 ,  B01J38/68 ,  C01B7/04 ,  Y02P20/584

Abstract: The invention relates to a process for the catalytic oxidation of hydrogen chloride by means of oxygen to form chlorine in a fluidized-bed process in the presence of a catalyst comprising ruthenium on a particulate support composed of alpha-aluminum oxide having an average particle size of from 10 to 200 μm, wherein the catalyst support has a low surface roughness and can be obtained from a used catalyst which has been used in a fluidized-bed process for at least 500 hours of operation.

Abstract translation: 本发明涉及一种在流化床方法中，在包含钌的催化剂存在下，通过氧气催化氧化氯化氢以形成氯的方法，该催化剂由颗粒载体组成，所述颗粒载体由平均粒径为 10至200μm，其中催化剂载体具有低的表面粗糙度，并且可以从在流化床方法中使用的使用的催化剂获得至少500小时的操作。