公开(公告)号：US20190284313A1

公开(公告)日：2019-09-19

申请号：US16318749

申请日：2017-07-14

Applicant: BASF SE

Inventor： Rosa CORBERAN ROC ,  Klaus MUEHLBACH ,  Thomas WETTLING ,  Sergei V. KOSTJUK ,  Irina VASILENKO ,  Dmitryi SHIMAN ,  Ivan BERAZIANKA

IPC: C08F10/10 ,  C08F4/14 ,  C08F4/26 ,  C08K5/3472 ,  C08K5/3445 ,  C08K5/353 ,  C08K5/19 ,  C08K5/50 ,  C08F4/18

Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.

公开(公告)号：US20200317832A1

公开(公告)日：2020-10-08

申请号：US16074229

申请日：2017-02-13

Applicant: BASF SE

Inventor： Rosa CORBERAN ROC ,  Klaus MUEHLBACH ,  Thomas WETTLING ,  Sergei V. KOSTJUK ,  Irina VASILENKO

IPC: C08F110/10

Abstract: The present invention relates to a process for preparing high- reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %, which comprises polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or an alkylaluminum halide-donor complex effective as a polymerization catalyst, wherein the aluminum trihalide or alkylaluminum halide is treated with at least one inorganic hydrate.

公开(公告)号：US20190062472A1

公开(公告)日：2019-02-28

申请号：US16073586

申请日：2017-02-13

Applicant: BASF SE

Inventor： Rosa CORBERAN ROC ,  Klaus MUEHLBACH ,  Thomas WETTLING ,  Sergei V. KOSTJUK ,  Irina VASILENKO ,  Dmitryi SHIMAN

IPC: C08F110/10

Abstract: The present invention relates to a process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per homo- or copolymer chain end of at least 70 mol % which comprises polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or of an alkylaluminum halide-donor complex, said complex comprising, as the donor, a mixture of at least two organic compounds with at least one ether function each.

公开(公告)号：US20200207887A1

公开(公告)日：2020-07-02

申请号：US16634697

申请日：2018-08-07

Applicant: BASF SE

Inventor： Rosa CORBERAN ROC ,  Klaus MUEHLBACH ,  Thomas WETTLING ,  Sergei V. KOST JUK ,  Irina VASILENKO ,  Dmitryi SHIMAN

IPC: C08F10/10

Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.

公开(公告)号：US20160145362A1

公开(公告)日：2016-05-26

申请号：US14905658

申请日：2014-07-07

Applicant: BASF SE

Inventor： Thomas WETTLING ,  Stefan HIRSCH ,  Markus BRYM ,  Markus WEIS

IPC: C08F110/10 ,  C08F8/28 ,  C08F8/32 ,  C08F8/46 ,  C08F8/00 ,  C08F8/30

CPC classification number: C08F110/10 ,  C08F8/00 ,  C08F8/28 ,  C08F8/30 ,  C08F8/32 ,  C08F8/46 ,  C08F210/10 ,  C08F2800/20 ,  C08F4/14 ,  C08F210/08 ,  C08F236/06 ,  C08F2500/02

Abstract: A polyisobutylene having a total content of vinylidene double bonds of more than 50 mol % and a number-average molecular weight of 500 to 10 000 daltons, where at least 10% of all the vinylidene double bonds in the polyisobutylene are part of one or more side chains composed of at least 2 carbon atoms from the main polyisobutylene chain. Such a polyisobutylene is suitable for production of fuel and lubricant additives.

Abstract translation: 具有大于50摩尔％和数均分子量为500至10000道尔顿的亚乙烯基双键的总含量的聚异丁烯，其中聚异丁烯中所有亚乙烯基双键的至少10％是一个或多个的一部分 由主聚异丁烯链至少2个碳原子构成的侧链。 这种聚异丁烯适用于生产燃料和润滑剂添加剂。