-
公开(公告)号:US20230374195A1
公开(公告)日:2023-11-23
申请号:US18031396
申请日:2021-10-12
Applicant: BASF SE
Inventor: Thomas Schaub , Paul Neumann , Mona Al Batal , A. Stephen K. Hashmi , Wei Zhou , Andreas Thomas Haedler , Markus Schuette , Viktoriia Zubar
CPC classification number: C08G18/82 , C08J11/28 , B01J31/189 , B01J31/20 , C08J2375/04 , B01J2531/821 , B01J2231/641
Abstract: Spent polyurethanes are returned to the value chain by hydrogenating the spent polyurethanes in a hydrogen atmosphere in the presence of at least one homogeneous transition metal catalyst complex, wherein the transition metal is selected from metals of groups 7, 8, 9 and 10 of the periodic table of elements according to IUPAC, to obtain a polyamine and a polyol. The hydrogenation is carried out at a reaction temperature of at least 120° C. in a non-reducible solvent having a dipole moment of 10-1030 C·m or less.