公开(公告)号：US20210261423A1

公开(公告)日：2021-08-26

申请号：US17254050

申请日：2019-06-18

Applicant: BASF SE

Inventor： Andrei-Nicolae PARVULESCU ,  Robert MCGUIRE ,  Ulrich MUELLER ,  Toshiyuki YOKOI ,  Hermann GIES ,  Bernd MARLER ,  Dirk DEVOS ,  Ute KOLB ,  Feng-Shou XIAO ,  Weiping ZHANG ,  Xiangju MENG ,  Yong WANG

IPC: C01B39/48 ,  C01B39/02 ,  B01J29/70 ,  B01J35/00 ,  C07C1/20 ,  B01J6/00 ,  B01J37/30

Abstract: A process for preparing a zeolitic material having an AEI-type framework structure having SiO2 and X2O3 in its framework, X standing for a trivalent element, may involve: (1) preparing a mixture of structure directing agent(s) and a first zeolitic material with SiO2 and X2O3 in its framework, the first zeolitic material having a FER, TON, MTT, FAU, GIS, MOR, BEA, MFI, and LTA framework; (2) heating the mixture to obtain a second zeolitic material having an AEI-type framework with SiO2 and X2O3 in its framework; (3) optionally calcining the second zeolitic material; (4) optionally subjecting the zeolitic material from (2) or (3) to ion-exchange, preferably ion-exchanging ionic extra-framework element(s) in the zeolite framework for H+ and/or NH4+; (5) calcining the zeolitic material from (2), (3), or (4) at greater than 600 to 900° C., the calcining atmosphere containing less than 10 vol.-% of H2O. Such zeolites can convert oxygenates to olefins.

公开(公告)号：US20210101800A1

公开(公告)日：2021-04-08

申请号：US16971875

申请日：2019-02-21

Applicant: BASF SE

Inventor： Mathias FEYEN ,  Ulrich MUELLER ,  Xinhe BAO ,  Weiping ZHANG ,  Dirk DE VOS ,  Hermann GIES ,  Feng-Shou XIAO ,  Toshiyuki YOKOI ,  Ute KOLB ,  Bernd MARLER ,  Yong WANG ,  Trees DE BAERDEMAEKER ,  Chuan SHI ,  Xiulian PAN ,  Xiangju MENG ,  Antje GRUENEWALD-LUEKE

IPC: C01B39/48 ,  B01J29/70

Abstract: Provided is a crystalline layered silicate, having an X-ray diffraction pattern comprising reflections at 2-theta values of (5.3±0.2)°, (8.6±0.2)°, (9.8±0.2)°, (21.7±0.2)° and (22.7±0.2). Also provided are a process for preparing the crystalline layered silicate and uses of the layered silicate. The process comprises steps of: (i) preparing a synthesis mixture comprising water, a source of Si, and a structure directing agent comprising a diethyldimethylammonium compound; (ii) subjecting the synthesis mixture obtained from (i) to hydrothermal synthesis conditions comprising heating the synthesis mixture obtained from (i) to a temperature in the range of from 110 to 180° C. and keeping the synthesis mixture at a temperature in this range under autogenous pressure for 1 to 6 days, obtaining a mother liquor comprising the crystalline layered silicate.

公开(公告)号：US20200276571A1

公开(公告)日：2020-09-03

申请号：US16765606

申请日：2018-11-08

Applicant: BASF SE

Inventor： Mathias FEYEN ,  Ulrich MUELLER ,  Xinhe BAO ,  Weiping ZHANG ,  Dirk DE VOS ,  Hermann GIES ,  Feng-Shou XIAO ,  Toshiyuki YOKOI ,  Ute KOLB ,  Bernd MARLER ,  Yong WANG ,  Trees DE BAERDEMAEKER ,  Chuan SHI ,  Xiangju MENG ,  Xiulian PAN

IPC: B01J37/08 ,  B01J37/30 ,  B01J29/76 ,  C01B39/48

Abstract: Provided are a process for the preparation of an iron containing zeolitic material having an AEI framework structure using a quaternary phosphonium cation, as well as an iron containing zeolitic material per se as obtainable or obtained according to the process. Furthermore, an exhaust gas treatment system comprising the iron containing zeolitic material and the use of the iron containing zeolitic material as a catalyst are provided.

公开(公告)号：US20210053041A1

公开(公告)日：2021-02-25

申请号：US16967918

申请日：2019-01-23

Applicant: BASF SE

Inventor： Mathias FEYEN ,  Ulrich MUELLER ,  Xinhe BAO ,  Weiping ZHANG ,  Dirk DE VOS ,  Hermann GIES ,  Feng-Shou XIAO ,  Toshiyuki YOKOI ,  Ute KOLB ,  Bernd MARLER ,  Yong WANG ,  Trees DE BAERDEMAEKER ,  Chuan SHI ,  Xiangju MENG ,  Xiulian PAN

IPC: B01J29/89 ,  C01B37/00 ,  B01J37/00 ,  B01J37/04 ,  B01J37/10

Abstract: A process for preparing a zeolitic material comprising Ti, having framework type CHA and having a framework structure which comprises Si and O, said process comprising (i) preparing a pre-synthesis mixture comprising water, a CHA framework structure directing agent, and a zeolitic material comprising Ti, having framework type MFI and having a framework structure which comprises Si and O; (ii) removing water from the pre-synthesis mixture obtained from (i) by heating the pre-synthesis mixture to a temperature of less than 100° C. at a pressure of less than 1 bar (abs); (iii) hydrothermally crystallizing the zeolitic material comprising Ti, having framework type CHA and having a framework structure which comprises Si and O.

公开(公告)号：US20200223705A1

公开(公告)日：2020-07-16

申请号：US16631911

申请日：2018-08-03

Applicant: BASF SE

Inventor： Mathias FEYEN ,  Ulrich MUELLER ,  Xinhe BAO ,  Weiping ZHANG ,  Dirk DE VOS ,  Hermann GIES ,  Feng-Shou XIAO ,  Toshiyuki YOKOI ,  Ute KOLB ,  Bernd MARLER ,  Yong WANG ,  Trees DE BAERDEMAEKER ,  Chuan SHI ,  Xiulian PAN ,  Xiangju MENG

IPC: C01B39/46 ,  B01J29/76

Abstract: A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and 0, wherein the transition metal M is a transition metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In. A process for preparing such a zeolitic material. Use of such a zeolitic material.

公开(公告)号：US20190300375A1

公开(公告)日：2019-10-03

申请号：US16463263

申请日：2017-12-13

Applicant: BASF SE

Inventor： Robert MCGUIRE ,  Mathias FEYEN ,  Ulrich MUELLER ,  Xinhe BAO ,  Weiping ZHANG ,  Dirk DE VOS ,  Hermann GIES ,  Feng-Shou XIAO ,  Toshiyuki YOKOI ,  Ute KOLB ,  Bernd MARLER ,  Chuan SHI ,  Xiulian PAN ,  Xiangju MENG ,  Stefan MAURER ,  Yu DAI ,  Yong WANG ,  Trees DE BAERDEMAEKER

IPC: C01B39/48 ,  B01J29/70 ,  B01J29/76 ,  B01J35/10 ,  B01J37/30 ,  B01D53/94 ,  B01J37/08

Abstract: A process for preparing a zeolitic material containing YO2 and X2O3, where Y and X represent a tetravalent element and a trivalent element, respectively, is described. The process includes (1) a step of preparing a mixture containing one or more structure directing agents, seed crystals, and a first zeolitic material containing YO2 and X2O3 and having FAU-, GIS-, MOR-, and/or LTA-type framework structures; and (2) a step of heating the mixture for obtaining a second zeolitic material containing YO2 and X2O3 and having a different framework structure than the first zeolitic material. The mixture prepared in (1) and heated in (2) contains 1000 wt % or less of H2O based on 100 wt % of YO2 in the framework structure of the first zeolitic material. A zeolitic material obtainable and/or obtained by the process and its use are also described.

公开(公告)号：US20220324716A1

公开(公告)日：2022-10-13

申请号：US17594875

申请日：2020-05-14

Applicant: BASF SE

Inventor： Andrei-Nocolae PARVULESCU ,  Ulrich MUELLER ,  Toshiyuki YOKOI ,  Ute KOLB ,  Yong WANG ,  Yasar KRYSIAK

IPC: C01B39/46

Abstract: A process for the production of a zeolitic material comprising one or more zeolite intergrowth phases of one or more zeolites having a CHA-type framework structure comprising SiO2 and X2O3, and one or more zeolites having an AFT-type framework CT structure comprising SiO2 and X2O3, wherein X is a trivalent element, and wherein said process comprises: (1) preparing a mixture comprising one or more sources for SiO2, one or more sources for X2O3, and seed crystals comprising a zeolitic material, said zeolitic material comprising SiO2 and X2O3 in its framework structure and having a CHA-type framework structure; (2) heating the mixture prepared in (1) for obtaining a zeolitic material comprising one or more zeolite intergrowth phases; and (R) subjecting the zeolitic material obtained in (2) to a procedure for removing at least a portion of X from the framework structure of the zeolitic material.