公开(公告)号：US3903207A

公开(公告)日：1975-09-02

申请号：US24028272

申请日：1972-03-31

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  HAMMANN INGEBORG

IPC: C07F9/24 ,  A01N9/36

CPC classification number: C07F9/2458

Abstract: N-(O,S-dialkyl(thiono)-thiolphosphoryl)-iminoformic acid alkyl esters of the general formula acid alkyl esters of the general formula

in which X is oxygen of R, R'' and R'''' each independently is lower alkyl with 1 to 6 carbon atoms, WHICH POSSESS INSECTICIDAL AND ACARICIDAL PROPERTIES.

Abstract translation: 通式为X的阳离子N-（O，S-二烷基（硫代） - 硫代磷酰基） - 亚氨基酸烷基酯通式X RO平行角PN = CH-OR“（I）R'S，其中X为氧 的R，R'和R“各自独立地为具有1至6个碳原子的低级烷基，具有无毒的杀虫剂和杀虫剂性质。

公开(公告)号：US3682943A

公开(公告)日：1972-08-08

申请号：US3682943D

申请日：1970-08-12

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  HAMMANN INGEBORG

IPC: A01N57/16 ,  A01N57/24 ,  A01N57/32 ,  C07D277/40 ,  C07D513/04 ,  C07F9/16 ,  C07F9/32 ,  C07F9/6561 ,  C07D99/06

CPC classification number: C07D513/04 ,  C07D277/40 ,  C07F9/6561

Abstract: O,O-dialkyl or -aryl-O-(5-methyl-thiazolo-(3,2-b)-triazol-2-y/)phosphoric acid esters and thionophosphoric acid esters as well as their phosphonic and phosphinic acid counterparts and amido esters having the formula WHEREIN R and R'' are alkyl, alkoxy, alkylamino or phenyl, which possesss arthropodicidal, e.g., insecticidal and acaricidal, properties, and process for their preparation.

Abstract translation: O，O-二烷基或芳基-O- [5-甲基 - 噻唑并（3,2-b） - 三唑-2-基] - 磷酸酯和硫代磷酸酯，以及它们的膦酸和次膦酸对应物 具有式WHEREIN R和R'的酰氨基酯是烷基，烷氧基，烷基氨基或苯基，它们具有杀虫剂，杀虫剂和杀螨剂的性质及其制备方法。

公开(公告)号：US3880958A

公开(公告)日：1975-04-29

申请号：US33801073

申请日：1973-03-05

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  HAMMANN INGEBORG

IPC: A01N57/16 ,  A01N57/28 ,  C07F9/24 ,  C07F9/58 ,  A01N9/36

CPC classification number: C07F9/2458

Abstract: IN WHICH R and R'' each independently is lower alkyl, and R'''' is alkyl or alkenyl with up to 6 carbon atoms, CYCLOALKYL WITH 4 TO 6 CARBON ATOMS OR A NITROGEN-CONTAINING HETEROCYCLIC STRUCTURE, WHICH POSSESS INSECTICIDAL AND ACARICIDAL PROPERTIES.

N-(N''-substituted-aminomethylidene)-O,S-dialkylthiolphosphoric acid diester-imides of the formula

Abstract translation: 式（I）中的N-（N'-取代 - 氨基亚甲基）-O，S-二烷基硫醇磷酸二酯 - 酰亚胺R和R'各自独立地为低级烷基，R“为具有至多6个碳原子的烷基或链烯基， 具有4至6个碳原子的环烷基或含有杀虫剂和杀虫剂性质的含氮的杂环结构。

公开(公告)号：US3626039A

公开(公告)日：1971-12-07

申请号：US3626039D

申请日：1968-05-08

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT

IPC: C07F9/165 ,  C07F9/20 ,  C07F9/24 ,  C07F9/6578 ,  C07D105/04 ,  C07F9/26

CPC classification number: C07F9/6578 ,  C07F9/165 ,  C07F9/20 ,  C07F9/24

Abstract: Reacting 2-chloro-(optionally 4-chloro lower alkyl)-1,3- (dioxa, oxa-thia or oxa-aza)-2-(phospholanes or phosphorinanes) with alkyl, oxo-alkyl (i.e. carbonyl-alkyl or aldehydo-alkyl), haloalkyl, phenyl or alkyl-, halo- and/or nitro-substituted phenyl sulfenylchlorides, for example at about -20 to +50* C., optionally in the presence of an inert organic solvent, to form the corresponding (O-, S- and N- chloro-substituted alkyl)-S(alkyl, oxo-alkyl, haloalkyl, phenyl and alkyl-, halo- and/or nitro- substituted phenyl)-diester chlorides and ester amide chlorides, which are known intermediates usable in the known way for producing known insecticides, fungicides and other plant protection agents.

公开(公告)号：US3706820A

公开(公告)日：1972-12-19

申请号：US3706820D

申请日：1971-03-04

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  HAMMANN INGEBORG

IPC: A01N57/04 ,  C07F9/165 ,  C07F9/40 ,  C07F9/24 ,  A01N9/36

CPC classification number: C07F9/1651 ,  A01N57/04 ,  C07F9/4075

Abstract: S-ALKYLMERCAPTOMETHYL-THIO- OR -DITHIO-PHOSPHORIC OR -PHOSPHONIC ACID ESTERS OF THE GENERAL FORMULA:

CH3-C(-CH2CL)(-CN)-S-CH2-S-P(=X)(-R1)-O-R

IN WHICH: R IS A LOWER ALKYL RADICAL, R1 IS A LOWER ALKYL OR ALKOXY RADICAL, AND X IS AN OXYGEN OR SULFUR ATOM, TO A PROCESS FOR THEIR PREPARATION AND TO THEIR USE AS INSECTICIDES OR ACARICIDES.

公开(公告)号：US3686369A

公开(公告)日：1972-08-22

申请号：US3686369D

申请日：1969-07-17

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  SCHEINPFLUG HANS ,  KUME TOYOHIKO ,  YASUI KAZUOMI

IPC: A01N57/14 ,  C07F9/18 ,  A01N9/36 ,  C07F9/08

CPC classification number: A01N57/14 ,  C07F9/18

Abstract: O-alkyl-S-alkyl-S-phenyl-phosphorodithiolates, i.e. O-alkyl-Salkyl-S-(optionally chloro and methyl -substituted)- phenyl- phosphorodithiolates or -dithiolphosphates, which possess fungicidal properties and which may be produced by conventional methods.

Abstract translation: O-烷基-S-烷基-S-苯基 - 二硫代硫醇盐，即O-烷基-S-烷基-S-（任选氯代和甲基取代的） - 苯基 - 二硫代磷酸盐或二硫代磷酸盐，其具有杀真菌性质，并且可以是 通过常规方法生产。

公开(公告)号：US3922324A

公开(公告)日：1975-11-25

申请号：US48979574

申请日：1974-07-16

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  HAMMANN INGEBORG ,  HOMEYER BERNHARD

IPC: C07F9/44 ,  C07F9/24 ,  A01N9/36

CPC classification number: C07F9/44

Abstract: O-aryl-thionoalkanephosphonic acid ester-formamidines or iminoethers of the formula

in which R is lower alkyl, R'' is lower alkoxy, mono-lower alkyl-amino or di-lower-amino, and Ar is optionally halogen-substituted phenyl, which possess insecticidal, acaricidal and nematocidal properties.

Abstract translation: O-芳基 - 硫代烷基膦酸酯 - 甲酰胺或式Aros PARALLEL ANGLE PN = CH-R'（I）R的亚胺基醚，其中R是低级烷基，R'是低级烷氧基，单低级烷基 - 氨基或二 - 低级氨基，Ar任选为卤素取代的苯基，其具有杀虫，杀螨和杀线虫性质。

公开(公告)号：US3705930A

公开(公告)日：1972-12-12

申请号：US3705930D

申请日：1970-04-22

Applicant: BAYER AG

Inventor： SCHLOR HANSHELMUT ,  HOFFMANN HELLMUT ,  REGEL ERIK ,  SCHEINPFLUG HANS

IPC: C07F9/18 ,  A01N9/36 ,  C07F9/16

CPC classification number: C07F9/18

Abstract: S-MONOALKYL-S,S-DIPHENYL- OR S,S-DIALKYL-S-PHENYL-TRITHIOLPHOSPHORIC ACID ESTERS IN WHICH EACH ALKYL GROUP HAS FROM 1 TO 4 CARBON ATOMS, E.G., S-METHYL (OR -THYL, -PROYL, -BUTYL)-S,S-DIPHENYLTRITHIOLPHOSPHORIC ACID ESTER, S,S,-DIMETHYL (OR -DIETHYL, -DI-PROPYL, DI-BTYL-)PHENYLTRITHIOLPHOSPHORIC ACID ESTER, HAVE EXCEPTIONAL FUNGICIDAL ACTIVITY, ESPECIALLY AGAINST RICE PATHOGENS, AND FURTHER EXHIBIT INSECTICIDAL AND ACARICIDAL EFFECTIVENESS.

公开(公告)号：US3591663A

公开(公告)日：1971-07-06

申请号：US3591663D

申请日：1968-05-08

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  SCHEINPFLUG HANS

IPC: A01N57/14 ,  A01N57/02 ,  A01N57/10 ,  C07F9/165 ,  C07F9/177 ,  C07F9/18 ,  C07F9/24 ,  C07F9/6571 ,  C07F9/6584 ,  C07F9/08 ,  A01N9/36

CPC classification number: C07F9/657154 ,  A01N57/02 ,  A01N57/10 ,  C07F9/177 ,  C07F9/18 ,  C07F9/24 ,  C07F9/65842

Abstract: O-CHLOROALKYL-S-(ALKYL, CYCLOALKYL, PHENYL AND CHLORO-, ALKYL-, NITRO- AND/OR ALKYLMERCAPTO-SUBSTITUTED PHENYL)(O- AND S-(ALKYL, CYCLOALKYL, PHENYL AND CHLORO-, ALKYL, NITRO- AND/OR ALKYLMERCAPTO-SUBSTITUTED PHENYL) AS WELL AS N-ALKYL AND N,N-DIALKYL)-THIOL AND -DITHIOL-PHOSPHORIC ACID ESTERS AND -THIOL-PHOSPHORIC ACID ESTER AMIDES, WHICH POSSESS FUNGICIDAL PROPERTIES AND WHICH MAY BE PRODUCED BY REACTING THE CORRESPONDING O-CHLOROALKYL-S-(ALKYL, CYCLOALKYL, PHENYL AND CHLORO-, ALKYL-, NITRO- AND/OR ALKYLMERCAPTO-SUBSTITUTED PHENYL)-THIOL-PHOSPHORIC ACID DIESTER CHLORIDE WITH THE APPROPRIATE ALCOHOL, MERCAPTAN, PHENOL, THIOPHENOL, N-ALKYL AMINE OR N,N-DIALKYLAMINE, IN THE PRESENCE OF AN ACID BINDING AGENT OR WITH THE SECOND COMPONENT IN THE FORM OF ITS SALT, E.G. ALKALI METAL OR AMMONIUM SALT.

公开(公告)号：US3888951A

公开(公告)日：1975-06-10

申请号：US43183374

申请日：1974-01-09

Applicant: BAYER AG

Inventor： HOFFMANN HELLMUT ,  HAMMANN INGEBORG ,  HOMEYER BERNHARD

IPC: A01N57/26 ,  A01N57/30 ,  C07F9/44 ,  C07F9/24 ,  A01N9/36

CPC classification number: C07F9/44

Abstract: O-aryl-thionoalkanephosphonic acid ester-formamidines or iminoethers of the formula

IN WHICH R is lower alkyl, R'' is lower alkoxy, mono-lower alkyl-amino or di-lower-amino, and Ar is optionally halogen-substituted phenyl, WHICH POSSESS INSECTICIDAL, ACARICIDAL AND NEMATOCIDAL PROPERTIES.