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    Fungicidal substituted ureidophenyl thioureas
    1.
    发明授权
    Fungicidal substituted ureidophenyl thioureas 失效
    杀真菌剂取代尿毒症

    公开(公告)号：US3920831A

    公开(公告)日：1975-11-18

    申请号：US39965373

    申请日：1973-09-21

    Applicant: BAYER AG

    Inventor： WIDDIG ARNO ,  KUHLE ENGELBERT ,  SASSE KLAUS ,  SCHEINPFLUG HANS ,  GREWE FERDINAND ,  KASPERS HELMUT ,  FROHBERGER PAUL-ERNST

    IPC: C07C335/28 ,  A01N9/12

    CPC classification number: C07C335/28

    Abstract: Ureidophenyl thioureas of the formula:

    in which EACH INDEPENDENTLY STANDS FOR A HALOGEN ATOM, ALKYL WITH 1-4 CARBON ATOMS OR ALKOXY WITH 1-4 CARBON ATOMS, N STANDS FOR 0, 1 OR 2, R stands for alkyl with 1-12 carbon atoms, R'' and R'''' each stands independently for a hydrogen atom or alkyl with 1-4 carbon atoms, and R'''''' stands for a hydrogen atom, alkyl with 1 or 2 carbon atoms (which may carry at least one substituent selected from halogen, cyano, alkoxy with up to 4 carbon atoms and alkoxycarbonyl with up to 5 carbon atoms), alkyl with 3 to 18 carbon atoms (which carries at least one substituent selected from halogen, cyano, alkoxy with up to 4 carbon atoms and alkoxycarbonyl with up to 5 carbon atoms), cycloalkyl with 5 to 8 ring carbon atoms, aralkyl (the aryl moiety of which may carry at least one substituent selected from halogen, lower alkyl and lower alkoxy), phenyl (which may carry at least one substituent selected from halogen, lower alkyl and lower alkoxy), acyl with up to 18 carbon atoms (which may be substituted by halogen and/or lower alkyl), aroyl (which may carry at least one substituent selected from halogen, lower alkyl and lower alkoxy), alkylsulfonyl with up to 18 carbon atoms, arylsulfonyl (which may carry at least one substituent selected from halogen, amino, lower alkyl and lower alkoxy) or dialkylamino with up to 4 carbon atoms, possess fungicidal properties.

    Reactive dyestuffs containing 2-chlorooxazole,2-chlorothiazole or 2-chlorobenzimidazole rings
    2.
    发明授权
    Reactive dyestuffs containing 2-chlorooxazole,2-chlorothiazole or 2-chlorobenzimidazole rings 失效
    含有2-氯代吗啉，2-氯代唑或2-氯代吗啉咪唑环的活性试剂

    公开(公告)号：US3515713A

    公开(公告)日：1970-06-02

    申请号：US3515713D

    申请日：1962-02-27

    Applicant: BAYER AG

    Inventor： SIEGEL EDGAR ,  SASSE KLAUS

    IPC: C09B62/343 ,  C09B62/347 ,  C09B62/38 ,  C09B62/40 ,  C09B62/42

    CPC classification number: C09B62/343 ,  C09B62/347 ,  Y10S8/918

    Abstract: The invention comprises reactive dyes of formula wherein F is an organic dye radical, Q is an -SO2-NR1-, -NR1-SO2-, -CO-NR1- or -NR1-CO- bridge member, R1 being hydrogen or C1-C5 alkyl, A is a six-membered carbocyclic ring, X is a hydrogen or chlorine atom or a methyl group, Y1 is a chlorine atom or an alkylsulphonyl or arylsulphonyl radical, Z is -O-, -S- or =N-CH3, m is 1 or 2 and n is 1, 2 or 3. The dyes may be prepared by condensing a dye or a diazo or coupling component containing an amino or amide group with a compound of formula wherein W is a carboxylic or sulphonic acid halide group and if an azo dye component is used forming the dye by the usual coupling reaction. Conversely dyestuff acid halides may be condensed with compounds of the above formula wherein W is an amino group. The dyes may be used to colour amide or hydroxyl group-containing fibres by the usual reactive dye processes. The preparation of monoazo, metallized azo, phthalocyanine and anthraquinone dyes is described in examples.

    Process for the preparation of 1-tert.-butyl-thiosemicarbazide compounds
    5.
    发明授权
    Process for the preparation of 1-tert.-butyl-thiosemicarbazide compounds 失效
    1-叔丁基 - 氨基硫脲化合物的制备方法

    公开(公告)号：US3907887A

    公开(公告)日：1975-09-23

    申请号：US35669473

    申请日：1973-05-02

    Applicant: BAYER AG

    Inventor： SASSE KLAUS

    IPC: A01N47/34 ,  C07C20060101 ,  C07C43/00 ,  C07C67/00 ,  C07C325/00 ,  C07C337/06 ,  C07D207/16 ,  C07D211/60 ,  C07D265/30 ,  C07D279/12 ,  C07D521/00 ,  C07C159/00

    CPC classification number: C07C337/06

    Abstract: 1-TERT.-BUTYL-THIOSEMICARBAZIDE COMPOUNDS OF THE FORMULA

    wherein R and R'' are hydrogen, aliphatic, cycloaliphatic or aromatic hydrocarbyl (optionally substituted) or where an R and R'' together with the nitrogen linking them can form a heterocyclic system ARE PRODUCED BY REACTING A THIOSEMICARBAZIDE OF THE FORMULA

    with tertiary butanol in the presence of a dehydrating agent at a temperature of from 0* to 100*C.

    Abstract translation: 式（I）R'其中R和R'是氢，脂族，脂环族或芳族烃基（任选取代的）或（其中R 1，R 2，R 3，R 4， 其中R和R'与连接它们的氮原子一起可以形成杂环体系，其通过在脱水剂存在下用叔丁醇反应制备式（II）R'的硫代化合物的硫代化合物 在0℃至100℃的温度下

    Beta-alkoxy-acrylic acid amides
    6.
    发明授权
    Beta-alkoxy-acrylic acid amides 失效
    β-氨基酸 - 丙烯酸

    公开(公告)号：US3574748A

    公开(公告)日：1971-04-13

    申请号：US3574748D

    申请日：1969-03-24

    Applicant: BAYER AG

    Inventor： MAYER DIETMAR ,  SASSE KLAUS ,  HAMMANN INGEBORG

    IPC: A01N37/36 ,  C07C103/30

    CPC classification number: A01N37/36

    Abstract: B-ALKOXY-ACRYLIC ACID AMIDES, I.E. B-(ALKOXY, CYCLOALKOXY, ALKYL-CYCLOALKOXY AND ALKYL-CYCLOALKYL-ALKOXY) ACRYLIC ACID N-(ALKYL, ALKENYL, CYCLOALKY, ALKYL-CYCLOAKYL, PHENYL-ALKYL AND CHLORO-PHENYL-ALKYL)-N-(UNSUBSTITUTED AND OPTIONALLY ALKYL, ALKENYL, CYCLOALKYL AND PHENYLALKYL)-AMIDES, WHICH POSSESS PESTICIDAL, ESPECIALLY INSECTICIDAL AND ACARICIDAL, PROPERTIES AND WHICH MAY BE PRODUCED BY REACTING THE CORRESPONDING B-ALKOXY-ACRILIC ACID CHLORIDE WITH THE APPROPRIATE AMINE.

    Substituted ureidophenyl thioureas
    10.
    发明授权
    Substituted ureidophenyl thioureas 失效
    取代的脲基苯基硫脲

    公开(公告)号：US3914284A

    公开(公告)日：1975-10-21

    申请号：US39965473

    申请日：1973-09-21

    Applicant: BAYER AG

    Inventor： WIDDIG ARNO ,  KUHLE ENGELBERT ,  SASSE KLAUS ,  SCHEINPFLUG HANS ,  GREWE FERDINAND ,  KASPERS HELMUT ,  FROHBERGER PAUL-ERNST

    IPC: C07C335/28 ,  C07C157/09

    CPC classification number: C07C335/28

    Abstract: Ureidophenyl thioureas of the formula:

    in which each X independently stands for a halogen atom, alkyl with 1-4 carbon atoms or alkoxy with 1-4 carbon atoms, n stands for 0, 1 or 2, R stands for alkyl with 1-12 carbon atoms, R'' and R'''' each stands independently for a hydrogen atom or alkyl with 1-4 carbon atoms, and R'''''' stands for a hydrogen atom, alkyl with 1 or 2 carbon atoms (which may carry at least one substituent selected from halogen, cyano, alkoxy with up to 4 carbon atoms and alkoxycarbonyl with up to 5 carbon atoms), alkyl with 3 to 18 carbon atoms (which carries at least one substituent selected from halogen, cyano, alkoxy with up to 4 carbon atoms and alkoxycarbonyl with up to 5 carbon atoms), cycloalkyl with 5 to 8 ring carbon atoms, aralkyl (the aryl moiety of which may carry at least one substituent selected from halogen, lower alkyl and lower alkoxy), phenyl (which may carry at least one substituent selected from halogen, lower alkyl and lower alkoxy), acyl with up to 18 carbon atoms (which may be substituted by halogen and/or lower alkyl), aroyl (which may carry at least one substituent selected from halogen, lower alkyl and lower alkoxy), alkylsulfonyl with up to 18 carbon atoms, arylsufonyl (which may carry at least one substituent selected from halogen, amino, lower alkyl and lower alkoxy) or dialkylamino with up to 4 carbon atoms, which possess fungicidial properties and which may be produced by conventional methods.

    Abstract translation: 下式的脲基苯基硫脲，其中每个X独立地代表卤素原子，具有1-4个碳原子的烷基，其中每个X独立地代表卤素原子， 原子或具有1-4个碳原子的烷氧基，n表示0,1或2，R表示具有1-12个碳原子的烷基，R'和R“各自独立地表示氢原子或具有1-4个碳原子的烷基 原子，R“”表示氢原子，具有1或2个碳原子的烷基（其可以携带至少一个选自卤素，氰基，具有至多4个碳原子的烷氧基和至多5个碳原子的烷氧基）的取代基） 具有3至18个碳原子的烷基（其携带至少一个选自卤素，氰基，具有至多4个碳原子的烷氧基和至多5个碳原子的烷氧基羰基）的取代基，具有5至8个环碳原子的环烷基，芳烷基（ 其芳基部分可以携带至少一个选自卤素，低级烷基和低级烷氧基的取代基），苯基（其可携带至少一个取代基 选自卤素，低级烷基和低级烷氧基），具有至多18个碳原子的酰基（其可被卤素和/或低级烷基取代），芳酰基（其可携带至少一个选自卤素，低级烷基和低级烷氧基 ），具有至多18个碳原子的烷基磺酰基，芳基磺酰基（其可以携带至少一个选自卤素，氨基，低级烷基和低级烷氧基的取代基）或具有至多4个碳原子的二烷基氨基，其具有杀真菌性质并且可以由 常规方法。

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