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公开(公告)号：US20200022367A1
公开(公告)日：2020-01-23
申请号：US16531446
申请日：2019-08-05
发明人： Robert H. BEDOUKIAN
IPC分类号： A01N43/16 , A01N31/06 , A01N37/02 , A01N37/36 , A01N37/42 , A01N43/08 , A01N35/06 , A01N49/00 , A01N37/06 , A01N37/18
摘要： Compounds are used as agents that deter feeding by insect pests, such as Hemiptera, Lepidoptera and Coleoptera. Feeding deterrence is obtained by contact of the insect pests with at least one of the compounds of the structure (I) wherein R is —OH, ═O, —OC(O)R4, —OR6, or —(OR6)2, each R6 is independently an alkyl group containing from 1 to 4 carbon atoms and R4 is a branched or straight chain, saturated or unsaturated, hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; X is O or CH2 with the proviso that when X is O, R can only be ═O; each Z is independently (CH) or (CH2); y is a numeral selected from 1 and 2; R1 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; R2 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms; R3 is selected from H, a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, —(CH2)nOH, —C(O)OR5, —CH2C(O)OR7, —CH2C(O)R8, —C(O)NR9R10, and —CH2C(O)NR11R12 where each of R5, R7, R8, R9, R10, R11 and R12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms and n is an integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (I) contain from 9 to 20 total carbon atoms in the compounds.
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公开(公告)号：US20180213773A1
公开(公告)日：2018-08-02
申请号：US15881053
申请日：2018-01-26
发明人： Robert H. BEDOUKIAN
IPC分类号： A01N31/06 , A01N43/16 , A01N43/08 , A01N31/02 , A01N37/42 , A01N37/36 , A01N37/18 , A01N49/00 , A01N35/06
CPC分类号： A01N31/06 , A01N31/02 , A01N35/06 , A01N37/18 , A01N37/36 , A01N37/42 , A01N43/08 , A01N43/16 , A01N49/00
摘要： This disclosure relates to a method for the control or repellency of biting arthropods. The method comprises bringing the biting arthropods into contact with a biting arthropod repellent formulation. The biting arthropod repellent formulation comprises nootkatol separate from, or in combination, or in synergistic combination, with skin or plant derived compounds and compounds structurally similar to them (e.g., ketones, cyclic ketones, esters, gamma or delta lactones, and branched and/or unsaturated carboxylic acids), and/or one or more repellents selected from the group consisting of DEET®, para-menthane-3,8-diol (PMD), Picaridin, ethyl 3-[acetyl(butyl)amino]propanoate (IR3535), and other nitrogen-containing repellents including amines, amides, and nitrogen-containing heterocyclic compounds. This disclosure also relates to a biting arthropod repellent formulation comprising nootkatol separate from, or in combination, or in synergistic combination, with the skin or plant derived compounds and compounds structurally similar to them, and/or the one or more repellents.
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3.发明申请公开(公告)号：US20180146668A1
公开(公告)日：2018-05-31
申请号：US15878455
申请日：2018-01-24
发明人： Robert H. BEDOUKIAN
IPC分类号： A01N43/16 , C07D309/18 , C07D307/28 , A01N43/08 , A01N35/06 , A01N31/06 , A01N37/36 , C07C49/603 , C07C35/18 , C07C35/06 , C07C235/74 , A01N37/42 , C07C49/647
CPC分类号： A01N43/16 , A01N31/06 , A01N35/06 , A01N37/36 , A01N37/42 , A01N43/08 , C07C35/06 , C07C35/18 , C07C49/603 , C07C49/647 , C07C235/74 , C07D307/28 , C07D309/18
摘要： Control and repellency of biting flies, house flies, ticks, ants, fleas, biting midges, cockroaches, spiders and stink bugs is obtained by contact of the insects with at least one of the compounds of the structure (I) wherein R is —OH, ═O, —OC(O)R4, —OR6, or —(OR6)2, wherein each R6 is independently an alkyl group containing from 1 to 4 carbon atoms and R4 is a branched or straight chain, saturated or unsaturated, hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; X is O or CH2, with the proviso that when X is O R can only be ═O: each Z is independently (CH) or (CH2); y is a numeral selected from 1 and 2; R1 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; R2 is H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms; R3 is H, a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, —(CH2)nOH, —C(O)OR5, —CH2C(O)OR7, —CH2C(O)R8, —C(O)NR9R10, or —CH2C(O)NR11R12 where each of R5, R7, R8, R9, R10, R11 and R12 is independently H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, and n is n integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (I) contain from 11 to 20 carbon atoms except where R is ═O, X═CH2 and y is 1 the compounds of structure (I) contain from 13 to 20 carbon atoms, with the proviso that when R3 is —CH2C(O)OR7 R1 and R2 must be H or a saturated hydrocarbyl group with zero double bonds. The invention also includes optical isomers, diastereomers and enantiomers of the compounds of structure (I).
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4.发明申请SYNERGISTIC FORMULATIONS FOR CONTROL AND REPELLENCY OF BITING ARTHROPODS 审中-公开用于控制和排斥的ARTHROPODS的协调制剂公开(公告)号：US20150133406A1
公开(公告)日：2015-05-14
申请号：US14540612
申请日：2014-11-13
发明人： Robert H. BEDOUKIAN
CPC分类号： A01N37/18 , A01N31/02 , A01N31/06 , A01N35/02 , A01N37/30 , A01N37/36 , A01N37/40 , A01N37/42 , A01N43/08 , A01N43/16 , A01N49/00 , A01N37/10
摘要： Control or repellency of biting arthropods, particularly biting insects, is accomplished by bringing the biting arthropods into contact with combinations of compounds identical or related to those found on human/animal skin or in plants acting synergistically with one another, or in combination with conventional repellents like DEET®, para-menthane-3,8-diol (PMD), sec-butyl-2-(2-hydroxyethyl) piperidine carboxylate (“Picaridin”), or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds, or any synergistic combination of DEET®, PMD, Picaridin, or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds.
摘要翻译： 咬人节肢动物（特别是叮咬昆虫）的控制或排斥是通过使咬咬的节肢动物与在人/动物皮肤或与植物相互作用的植物中相同或相关的化合物的组合接触或与常规驱避剂组合 如DEET，对薄荷烷-3,8-二醇（PMD），仲丁基-2-（2-羟乙基）哌啶羧酸酯（“哌啶”）或其它含氮驱虫剂，其选自胺，酰胺和含氮杂环 化合物，或DEET®，PMD，哌啶或其它含氮驱虫剂的选择胺，酰胺和含氮杂环化合物的任何协同组合。
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公开(公告)号：US20210100242A1
公开(公告)日：2021-04-08
申请号：US17064916
申请日：2020-10-07
发明人： Robert H. BEDOUKIAN
摘要： This disclosure relates to biting arthropod control or repellent formulations for the control or repellency of biting arthropods. The formulations comprise at least one sensate compound, wherein the at least one sensate compound is present in an effective amount sufficient to control or repel biting arthropods. This disclosure also relates to a method for the control or repellency of biting arthropods. The method comprises bringing the biting arthropods into contact with a biting arthropod control or repellent formulation. The biting arthropod control or repellent formulation comprises at least one sensate compound, wherein the at least one sensate compound is present in an effective amount sufficient to control or repel biting arthropods.
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公开(公告)号：US20210029993A1
公开(公告)日：2021-02-04
申请号：US17073933
申请日：2020-10-19
IPC分类号： A01N35/04 , A01N31/02 , A01N31/04 , A01N31/06 , A01N31/08 , A01N35/02 , A01N35/06 , A01N37/02 , A01N43/20 , A01N49/00 , A01N65/00
摘要： Certain components of citrus fruits and oxidation products of limonene are effective deterrents, repellents and/or spatial inhibitors for mosquitoes and biting midges. The compounds that have been found to be deterrents, repellents and inhibitors for mosquitoes and biting midges are at least two of neryl acetate, citronellyl acetate, geranyl acetate, hydroxy-p-cymene, citral, α-terpineol, citronellal, linaloyl acetate, citronellol, terpen-4-ol, tetrahydrocarvone, products of oxidized oxidized limonene inclusive of d- and l-carvone, (+) limonene oxide, (−) limonene oxide, cis and trans carveol, a diol and an aldehyde. The compounds are formulated into compositions, capable of releasing a spatially deterring/repelling/inhibiting effective amount of the compound effective against mosquitoes or biting midges, in an amount greater than about 75% by weight, based on the total weight of the composition. The compositions are formulated into delivery systems or vehicles (e.g., candles).
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公开(公告)号：US20190075793A1
公开(公告)日：2019-03-14
申请号：US16125089
申请日：2018-09-07
发明人： Robert H. BEDOUKIAN
IPC分类号： A01N43/08 , A01N43/16 , A01N37/18 , A01N35/06 , A01N37/02 , A01N31/06 , A01N27/00 , A01N25/14
摘要： Killing one or more agricultural pests is accomplished by bringing the agricultural pests into contact with a toxic amount of a formulation comprising: (I) one or more compounds selected from the group consisting of: (1) one or more compounds of structure (A), wherein the compounds of structure (A) comprise: wherein R is selected from the group consisting of —OH, ═O, —OC(O)R4, —OR6, —(OR6)2, wherein each R6 is independently selected from an alkyl group containing from 1 to 4 carbon atoms and R is a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; X is O or CH2, with the proviso that when X is O, then R can only be ═O; each Z is independently selected from the group consisting of (CH) and (CH2); y is a numeral selected from 1 and 2; R1 is selected from the group consisting of H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; R2 is selected from the group consisting of H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms; R3 is selected from the group consisting of H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, —(CH2)nOH, —C(O)OR5, —CH2C(O)OR7, —CH2C(O)R8, —C(O)NR9R10, —CH2C(O)NR11R12 where each of R5, R7, R8, R9, R10, R11 and R12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms and n is an integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (A) contain from 11 to 20 total carbon atoms; and (2) one or more sesquiterpenes selected from the group consisting of acyclic, monocyclic, bicyclic and tricyclic sesquiterpenes and derivatives thereof; and (II) one or more toxicant compounds selected from the group consisting of carbamates, organochlorines, pyrethroids, sulfoximines, neonicotinoids, pyridine azomethines, diamides, organophosphates, phenylpyrazoles, oxadiazines, and ketoenols. The formulation can be a synergistic formulation.
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公开(公告)号：US20160052855A1
公开(公告)日：2016-02-25
申请号：US14830262
申请日：2015-08-19
CPC分类号： C07C47/21 , C11B9/0015
摘要： A perfume composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. The isomers of 4,8-undecadienal comprise Z,Z-4,8-undecadienal, E,E-4,8-undecadienal, and mixed Z/E isomers of 4,8-undecadienal; the isomers of 4,9-dodecadienal comprise Z,Z-4,9-dodecadienal, E,E-4,9-dodecadienal, and mixed Z/E isomers of 4,9-dodecadienal; and the isomers of 4,10-tridecadienal comprise Z,Z-4,10-tridecadienal, E,E-4,10-tridecadienal, and mixed Z/E isomers of 4,10-tridecadienal. A composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. Processes for the preparation of the isomer mixtures of alkadienals are provided. The isomeric alkadienals have a range of fresh, watery, ozone, grapefruit, tangerine, orange peel, aldehydic notes of exceptional strength.
摘要翻译： 一种香料组合物，其包含有效量的至少一种选自4,8-十一碳烯醛及其异构体的链烷二烯，4,9-十二二烯醛及其异构体，以及4,10-十三碳二烯及其异构体。 4,8-十一碳二烯的异构体包括Z，Z-4,8-十一碳二烯醛，E，E-4,8-十一碳二烯醛，以及4,8-十一二烯醛的混合Z / E异构体; 4,9-十二碳二烯醛的异构体包含Z，Z-4,9-十二碳二烯醛，E，E-4,9-十二二烯醛和4,9-十二二烯醛的混合Z / E异构体; 4,10-十三碳二烯醛的异构体包含Z，Z-4,10-十三碳二烯醛，E，E-4,10-十三碳二烯醛和4,10-十三碳二烯醛的混合Z / E异构体。 一种组合物，其包含有效量的至少一种选自4,8-十一碳烯醛及其异构体的链烷二烯，4,9-十二二烯醛及其异构体，以及4,10-十三碳二烯及其异构体。 提供了制备烷二醛的异构体混合物的方法。 异构链烷二酮具有一系列新鲜，含水，臭氧，葡萄柚，橘子，橙皮，醛特别强度的醛类。
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9.发明申请公开(公告)号：US20190082690A1
公开(公告)日：2019-03-21
申请号：US16131412
申请日：2018-09-14
发明人： Robert H. BEDOUKIAN
IPC分类号： A01N43/16 , A01N37/02 , A01N37/36 , A01N37/42 , A01N43/08 , A01N31/06 , A01N37/18 , A01N35/06 , A01N49/00 , A01N37/06
摘要： Compounds are used as agents that deter feeding on crops by agricultural pests, such as hemiptera, lepidoptera and coleoptera, including, but not limited to, stink bugs, codling moth larvae and granary weevils. Feeding deterrence is obtained by contact of the insects with at least one of the compounds of the structure (I)wherein R is —OH, ═O, —OC(O)R4, —OR6 or —(OR6)2, wherein each R6 is independently an alkyl group containing from 1 to 4 carbon atoms and R4 is a branched or straight chain, saturated or unsaturated, hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; X is O or CH2 with the proviso that when X is O, R can only be ═O; each Z is independently (CH) or (CH2); y is a numeral selected from 1 and 2; R1 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; R2 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms; R3 is selected from H, a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, —(CH2)nOH, —C(O)OR5, —CH2C(O)OR7, —CH2C(O)R8, —C(O)NR9R10, and —CH2C(O)NR11R12 where each of R5, R7, R8, R9, R10, R11 and R12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms and n is an integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (I) contain from 9 to 20 total carbon atoms in the compounds.
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公开(公告)号：US20190075790A1
公开(公告)日：2019-03-14
申请号：US16128042
申请日：2018-09-11
发明人： Robert H. BEDOUKIAN
摘要： Killing one or more biting arthropods selected from the group consisting of mosquitoes, bed bugs and ticks is accomplished by bringing the biting arthropods into contact with a toxic amount of a formulation comprising: (1) one or more compounds of structure (I), wherein the compounds of structure (I) comprise: wherein R is selected from the group consisting of —OH, ═O, —OC(O)R4, —OR6, —(OR6)2, wherein each R6 is independently selected from an alkyl group containing from 1 to 4 carbon atoms and R4 is a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms: X is O or CH2, with the proviso that when X is O, then R can only be ═O; each Z is independently selected from the group consisting of (CH) and (CH2); y is a numeral selected from 1 and 2; R1 is selected from the group consisting of H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; R2 is selected from the group consisting of H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms; R3 is selected from the group consisting of H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, —(CH2)nOH, —C(O)OR5, —CH2C(O)OR7, —CH2C(O)R8, —C(O)NR9R10, —CH2C(O)NR11R12 where each of R5, R7, R8, R9, R10, R11 and R12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms and n is an integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (I) contain from 11 to 20 total carbon atoms; and (2) one or more toxicant compounds selected from the group consisting of pyrethroids, carbamates, and organophosphates. The formulation can be a synergistic formulation.
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