公开(公告)号：US20160009566A1

公开(公告)日：2016-01-14

申请号：US14441778

申请日：2013-05-21

申请人： BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY ,  JIANGYIN RUIFA CHEMICAL CO., LTD.

发明人： Yanjun LIN ,  Kaitao LI ,  Bo NING ,  Dianqing LI ,  Xue DUAN ,  Chenfa WEN ,  Xuchang TAN

IPC分类号： C01G9/02 ,  C01F7/00 ,  C07F15/04 ,  B01J19/18

CPC分类号： C01G9/02 ,  B01F7/1635 ,  B01J8/0005 ,  B01J8/006 ,  B01J8/20 ,  B01J8/222 ,  B01J19/18 ,  B01J2208/00106 ,  B01J2208/00867 ,  B01J2219/185 ,  C01B13/366 ,  C01F7/004 ,  C01F7/005 ,  C01G9/006 ,  C01G53/006 ,  C01P2002/22 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/50 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2004/62 ,  C07F15/04

摘要： The present invention belongs to the synthesis technology field of inorganic functional materials, and particularly provides a self-balanced high-pressure and high-shear autoclave and its application in the preparation of layered double hydroxides (LDHs). In this invention, by imbedding the handpiece of emulsification mill into the autoclave, and by taking the motor driving system outside of the autoclave, the pressure of the autoclave can be highly stable by the use of self-balanced seal gland. These characters solve the problem that the typical emulsification mill cannot be used in high-pressure system, and ensure the crystallization under the high-pressure and high-shear conditions. Such autoclave takes the advantages of additional equipment, and eliminates the volume effect in the amplification process. By the use of this new autoclave, the reaction time can be shorten from 24 hours to 2-6 hours, the reaction temperature can be reduced from 180° C. to 140° C. The LDHs products with small particle size and narrow size distribution are obtained. These results are better than those prepared at the laboratory level.

摘要翻译： 本发明属于无机功能材料的合成技术领域，特别提供了一种自平衡的高压高剪切高压釜及其在层状双氢氧化物（LDH）的制备中的应用。 在本发明中，通过将乳化机的手持件嵌入高压釜中，并且通过将电动机驱动系统置于高压釜外部，通过使用自平衡密封压盖，高压釜的压力可以高度稳定。 这些特点解决了典型乳化机不能在高压系统中使用的问题，确保了在高压高剪切条件下的结晶。 这种高压釜具有附加设备的优点，并消除了放大过程中的体积效应。 通过使用这种新的高压釜，反应时间可以从24小时缩短到2-6小时，反应温度可以从180℃降低到140℃。具有小粒度和窄尺寸分布的LDHs产物 获得。 这些结果比实验室水平好。