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公开(公告)号:US10851191B2
公开(公告)日:2020-12-01
申请号:US15580260
申请日:2016-06-29
申请人: BOREALIS AG
发明人: Luigi Resconi , Pavel Shutov , Wilfried Toltsch
IPC分类号: C08F210/06 , C08F210/16
摘要: The present invention relates to an olefin polymerization process, wherein propylene and a C4 to C10 a-olefin, preferably 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst so as to obtain a polypropylene, wherein the polypropylene comprises C4 to C10 a-olefin, preferably 1-butene-derived comonomer units in an amount of from 0.5 wt % to 15 wt % and ethylene-derived comonomer units in an amount of 0 wt % to 3 wt %, and wherein the Ziegler-Natta catalyst comprises i) an external donor of the formula (I): (R3)z(R2O)ySi(R1)x and ii) a solid Ziegler-Natta catalyst component being free of external carrier material.
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公开(公告)号:US10745548B2
公开(公告)日:2020-08-18
申请号:US16464973
申请日:2017-12-14
申请人: BOREALIS AG
发明人: Claudia Kniesel , Pavel Shutov , Susanne Kahlen , Daniela Mileva , Floran Prades
摘要: The invention relates to a polypropylene composition (C) comprising: (i) 62 to 85 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO1) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 6.0 to 50.0 g/10 min; (ii) 10 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.1 to 5.5 g/10 min; (iii) 5 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of an inorganic filler (F); wherein (a) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower amount [in mol %] of C2 and/or C4 to C12 α-olefin derived comonomer units than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); (b) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower the intrinsic viscosity (IV) than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); and (c) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) has an intrinsic viscosity (IV) in the range of 6.0 to 15.0 dl/g.
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公开(公告)号:US20210139683A1
公开(公告)日:2021-05-13
申请号:US16621335
申请日:2018-06-26
申请人: BOREALIS AG
IPC分类号: C08L23/12
摘要: The present invention is directed to a heterophasic polypropylene composition (HECO1) and the use thereof to reduce the amount of flow marks of an injection moulded polyolefin composition. Further, the present invention is directed to a polyolefinn composition (C) comprising a polyolefin (PO), said heterophasic polypropylene composition (HECOl) and optionally a filler as well as an article comprising said polyolefin composition (C).
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公开(公告)号:US10647838B2
公开(公告)日:2020-05-12
申请号:US16070113
申请日:2017-01-27
申请人: BOREALIS AG
IPC分类号: C08L23/12 , C08F2/00 , C08F210/06 , C08L23/14
摘要: A heterophasic propylene copolymer (HECO) comprising a polypropylene matrix having a melt flow rate MFR2 (230° C.) in the range of 40 to 120 g/10 min and a comonomer content in the range of 30 to 75 mol-% for the preparation of molded articles with low CLTE.
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公开(公告)号:US20190315956A1
公开(公告)日:2019-10-17
申请号:US16464973
申请日:2017-12-14
申请人: BOREALIS AG
发明人: Claudia Kniesel , Pavel Shutov , Susanne Kahlen , Daniela Mileva , Floran Prades
IPC分类号: C08L23/16
摘要: The invention relates to a polypropylene composition (C) comprising: (i) 62 to 85 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO1) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 6.0 to 50.0 g/10 min; (ii) 10 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.1 to 5.5 g/10 min; (iii) 5 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of an inorganic filler (F); wherein (a) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower amount [in mol %] of C2 and/or C4 to C12 α-olefin derived comonomer units than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); (b) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower the intrinsic viscosity (IV) than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); and (c) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) has an intrinsic viscosity (IV) in the range of 6.0 to 15.0 dl/g.
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公开(公告)号:US20230279208A1
公开(公告)日:2023-09-07
申请号:US18014185
申请日:2021-07-05
申请人: Borealis AG
IPC分类号: C08L23/14
CPC分类号: C08L23/14 , C08L2205/03 , C08L2207/02 , C08L2205/08 , C08L2207/20
摘要: Use of a compatibilizer (B) for upgrading a polypropylene-polyethylene blend (A) comprising (A-1) polypropylene and (A-2) polyethylene wherein the weight ratio of polypropylene (A-1) to polyethylene (A-2) is in the range from 19:1 to 1:19 with respect to at least one or more of the following properties (i) elongation at break (ISO 527-1,2; F3/4), (ii) Charpy notched impact strength (1eA) (non-instrumented, ISO 179-1 at +23° C.), (iii) Charpy notched impact strength (1eA) (non-instrumented, ISO 179-1 at 0° C.), (iv) Charpy notched impact strength (1eA) (non-instrumented, ISO 179-1 at −20° C.), (v) puncture resistance (energy, IS07785-2 at +23° C.) and (vi) low temperature puncture resistance (energy, ISO 7765-2 at 0° C. or −20° C.), wherein compatibilizer (B) is used in an amount of 1 to 35 wt.-% preferably 2 to 25 wt.-%, more preferably 3 to 9 wt.-% with respect to the final composition.
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公开(公告)号:US11053380B2
公开(公告)日:2021-07-06
申请号:US16621335
申请日:2018-06-26
申请人: BOREALIS AG
摘要: The present invention is directed to a heterophasic polypropylene composition (HECO1) and the use thereof to reduce the amount of flow marks of an injection moulded polyolefin composition. Further, the present invention is directed to a polyolefin composition (C) comprising a polyolefin (PO), said heterophasic polypropylene composition (HECO1) and optionally a filler as well as an article comprising said polyolefin composition (C).
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公开(公告)号:US20190031869A1
公开(公告)日:2019-01-31
申请号:US16070113
申请日:2017-01-27
申请人: BOREALIS AG
IPC分类号: C08L23/12 , C08L23/14 , C08F2/00 , C08F210/06
摘要: A heterophasic propylene copolymer (HECO) comprising a polypropylene matrix having a melt flow rate MFR2 (230° C.) in the range of 40 to 120 g/10 min and a comonomer content in the range of 30 to 75 mol-% for the preparation of molded articles with low CLTE.
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公开(公告)号:US10100186B2
公开(公告)日:2018-10-16
申请号:US15113922
申请日:2015-02-03
申请人: BOREALIS AG
发明人: Jingbo Wang , Pavel Shutov , Johanna Lilja , Markus Gahleitner
IPC分类号: C08L23/16 , C08L23/14 , C08J5/18 , C08F210/06
摘要: The present invention is directed to a new heterophasic propylene copolymer (RAHECO) and an unoriented film comprising the heterophasic propylene copolymer (RAHECO) as well as a container comprising the unoriented film. The present invention is further directed to the use of the heterophasic propylene copolymer (RAHECO) for improving the balance between softness and haze of an unoriented film.
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公开(公告)号:US20180134826A1
公开(公告)日:2018-05-17
申请号:US15580260
申请日:2016-06-29
申请人: BOREALIS AG
发明人: Luigi Resconi , Pavel Shutov , Wilfried Toltsch
IPC分类号: C08F210/06 , C08F210/16
CPC分类号: C08F210/06 , C08F210/16 , C08F2800/20 , C08F210/08 , C08F2500/12 , C08F2500/26 , C08F4/6494 , C08F4/6465 , C08F4/6546 , C08F4/6492
摘要: The present invention relates to an olefin polymerization process, wherein propylene and a C4 to C10 a-olefin, preferably 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst so as to obtain a polypropylene, wherein the polypropylene comprises C4 to C10 a-olefin, preferably 1-butene-derived comonomer units in an amount of from 0.5 wt % to 15 wt % and ethylene-derived comonomer units in an amount of 0 wt % to 3 wt %, and wherein the Ziegler-Natta catalyst comprises i) an external donor of the formula (I): (R3)z(R2O)ySi(R1)x and ii) a solid Ziegler-Natta catalyst component being free of external carrier material.
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