Process for preparing propylene polymer compositions

    公开(公告)号:US10851191B2

    公开(公告)日:2020-12-01

    申请号:US15580260

    申请日:2016-06-29

    申请人: BOREALIS AG

    IPC分类号: C08F210/06 C08F210/16

    摘要: The present invention relates to an olefin polymerization process, wherein propylene and a C4 to C10 a-olefin, preferably 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst so as to obtain a polypropylene, wherein the polypropylene comprises C4 to C10 a-olefin, preferably 1-butene-derived comonomer units in an amount of from 0.5 wt % to 15 wt % and ethylene-derived comonomer units in an amount of 0 wt % to 3 wt %, and wherein the Ziegler-Natta catalyst comprises i) an external donor of the formula (I): (R3)z(R2O)ySi(R1)x and ii) a solid Ziegler-Natta catalyst component being free of external carrier material.

    Polypropylene composition with excellent paint adhesion

    公开(公告)号:US10745548B2

    公开(公告)日:2020-08-18

    申请号:US16464973

    申请日:2017-12-14

    申请人: BOREALIS AG

    IPC分类号: C08L23/12 C08L23/16 C08F2/00

    摘要: The invention relates to a polypropylene composition (C) comprising: (i) 62 to 85 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO1) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 6.0 to 50.0 g/10 min; (ii) 10 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.1 to 5.5 g/10 min; (iii) 5 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of an inorganic filler (F); wherein (a) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower amount [in mol %] of C2 and/or C4 to C12 α-olefin derived comonomer units than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); (b) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower the intrinsic viscosity (IV) than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); and (c) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) has an intrinsic viscosity (IV) in the range of 6.0 to 15.0 dl/g.

    POLYPROPYLENE COMPOSITION WITH EXCELLENT PAINT ADHESION

    公开(公告)号:US20190315956A1

    公开(公告)日:2019-10-17

    申请号:US16464973

    申请日:2017-12-14

    申请人: BOREALIS AG

    IPC分类号: C08L23/16

    摘要: The invention relates to a polypropylene composition (C) comprising: (i) 62 to 85 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO1) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 6.0 to 50.0 g/10 min; (ii) 10 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.1 to 5.5 g/10 min; (iii) 5 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of an inorganic filler (F); wherein (a) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower amount [in mol %] of C2 and/or C4 to C12 α-olefin derived comonomer units than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); (b) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower the intrinsic viscosity (IV) than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); and (c) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) has an intrinsic viscosity (IV) in the range of 6.0 to 15.0 dl/g.

    POLYPROPYLENE POLYETHYLENE MIXTURE UPGRADING

    公开(公告)号:US20230279208A1

    公开(公告)日:2023-09-07

    申请号:US18014185

    申请日:2021-07-05

    申请人: Borealis AG

    IPC分类号: C08L23/14

    摘要: Use of a compatibilizer (B) for upgrading a polypropylene-polyethylene blend (A) comprising (A-1) polypropylene and (A-2) polyethylene wherein the weight ratio of polypropylene (A-1) to polyethylene (A-2) is in the range from 19:1 to 1:19 with respect to at least one or more of the following properties (i) elongation at break (ISO 527-1,2; F3/4), (ii) Charpy notched impact strength (1eA) (non-instrumented, ISO 179-1 at +23° C.), (iii) Charpy notched impact strength (1eA) (non-instrumented, ISO 179-1 at 0° C.), (iv) Charpy notched impact strength (1eA) (non-instrumented, ISO 179-1 at −20° C.), (v) puncture resistance (energy, IS07785-2 at +23° C.) and (vi) low temperature puncture resistance (energy, ISO 7765-2 at 0° C. or −20° C.), wherein compatibilizer (B) is used in an amount of 1 to 35 wt.-% preferably 2 to 25 wt.-%, more preferably 3 to 9 wt.-% with respect to the final composition.