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公开(公告)号：US11493488B2
公开(公告)日：2022-11-08
申请号：US16638129
申请日：2018-08-16
Applicant: BP Exploration Operating Company Limited
Inventor： John William Couves , Christianne Clare Wicking
Abstract: A method for analysing a crude oil to determine the amount of organic acid compounds contained in the crude oil includes extracting the organic acid compounds from a sample of crude oil to form an extract and determining the amount of the extracted organic acids In addition, the method includes dissolving the extract in a polar solvent to form a solution of the extracted organic acid compounds Further, the method includes introducing a sample of the solution of the extracted organic acid to an apparatus including a reversed phase liquid chromatography (LC) column and a mass spectrometer (MS) arranged in series. The reversed phase LC column contains a hydrophobic sorbent and the mobile phase for the LC column includes a polar organic solvent. Still further, the method includes separating the organic acid compounds in the LC column of the LC-MS apparatus and continuously passing the separated organic acid compounds from the LC column to the MS of the LC-MS apparatus to ionize the organic acid compounds and to obtain a chromatogram with mass spectral data over time for the ionized organic acid compounds. Moreover, the method includes determining the area(s) under the peak(s) in an extracted ion chromatogram derived from the mass spectral data assigned to one or more organic acid compounds. The method also includes determining the amount of the organic acid compound(s) in the sample by comparing the area under the peak(s) assigned to the organic acid compound(s) with the area under a peak in an extracted ion chromatogram assigned to a specific amount of a standard organic acid compound. In addition, the method includes extrapolating from the amount of the organic acid compound(s) in the sample to provide the total amount of the organic acid compound(s) in the extract.
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公开(公告)号：US10815777B2
公开(公告)日：2020-10-27
申请号：US16086662
申请日：2017-03-14
Applicant: BP Exploration Operating Company Limited
Inventor： Ian Ralph Collins , John William Couves , Michael Graham Hodges , Christian Schack Pedersen , Peter Anthony Salino , Christianne Clare Wicking
Abstract: A method for detecting incremental oil production from an oil-bearing reservoir includes taking a baseline sample of the oil and analyzing the baseline sample of oil to establish a baseline compositional signature for the oxygen-containing organic compounds in the oil. In addition, the method includes commencing a low salinity waterflood by injecting a low salinity water into the reservoir from an injection well. Further, the method includes recovering oil from a production well. Still further, the method includes taking post-flood samples of the oil produced from the production well over time. The method also includes analyzing the post-flood samples of oil to establish post-flood compositional signatures for the oxygen-containing organic compounds in the oil. Moreover, the method includes identifying a difference between one or more of the post-flood compositional signatures and the baseline compositional signature that is characteristic of incremental oil released by the low salinity waterflood.
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公开(公告)号：US20200240963A1
公开(公告)日：2020-07-30
申请号：US16638129
申请日：2018-08-16
Applicant: BP Exploration Operating Company Limited
Inventor： John William Couves , Christianne Clare Wicking
IPC: G01N30/72 , G01N33/28 , G01N1/38 , B01J20/281 , G01N30/86
Abstract: A method for analysing a crude oil to determine the amount of organic acid compounds contained in the crude oil includes extracting the organic acid compounds from a sample of crude oil to form an extract and determining the amount of the extracted organic acids In addition, the method includes dissolving the extract in a polar solvent to form a solution of the extracted organic acid compounds Further, the method includes introducing a sample of the solution of the extracted organic acid to an apparatus including a reversed phase liquid chromatography (LC) column and a mass spectrometer (MS) arranged in series. The reversed phase LC column contains a hydrophobic sorbent and the mobile phase for the LC column includes a polar organic solvent. Still further, the method includes separating the organic acid compounds in the LC column of the LC-MS apparatus and continuously passing the separated organic acid compounds from the LC column to the MS of the LC-MS apparatus to ionize the organic acid compounds and to obtain a chromatogram with mass spectral data over time for the ionized organic acid compounds. Moreover, the method includes determining the area(s) under the peak(s) in an extracted ion chromatogram derived from the mass spectral data assigned to one or more organic acid compounds. The method also includes determining the amount of the organic acid compound(s) in the sample by comparing the area under the peak(s) assigned to the organic acid compound(s) with the area under a peak in an extracted ion chromatogram assigned to a specific amount of a standard organic acid compound. In addition, the method includes extrapolating from the amount of the organic acid compound(s) in the sample to provide the total amount of the organic acid compound(s) in the extract.
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公开(公告)号：US20190100996A1
公开(公告)日：2019-04-04
申请号：US16086662
申请日：2017-03-14
Applicant: BP Exploration Operating Company Limited
Inventor： Ian Ralph Collins , John William Couves , Michael Graham Hodges , Christian Schack Pedersen , Peter Anthony Salino , Christianne Clare Wicking
Abstract: A method for detecting incremental oil production from an oil-bearing reservoir includes taking a baseline sample of the oil and analyzing the baseline sample of oil to establish a baseline compositional signature for the oxygen-containing organic compounds in the oil. In addition, the method includes commencing a low salinity waterflood by injecting a low salinity water into the reservoir from an injection well. Further, the method includes recovering oil from a production well. Still further, the method includes taking post-flood samples of the oil produced from the production well over time. The method also includes analyzing the post-flood samples of oil to establish post-flood compositional signatures for the oxygen-containing organic compounds in the oil. Moreover, the method includes identifying a difference between one or more of the post-flood compositional signatures and the baseline compositional signature that is characteristic of incremental oil released by the low salinity waterflood.
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