利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

9 条记录 (耗时 0.033 秒)

    Methods for purifying 2-aryl-3,3-bis(hydroxyaryl)phthalimidines
    1.
    发明申请
    Methods for purifying 2-aryl-3,3-bis(hydroxyaryl)phthalimidines 有权
    2-芳基-3,3-双（羟基芳基）苯二酰亚胺的纯化方法

    公开(公告)号：US20070135612A1

    公开(公告)日：2007-06-14

    申请号：US11300225

    申请日：2005-12-14

    申请人： Balakrishnan Ganesan ,  Pradeep Nadkarni ,  Arun S. ,  Ramanarayanan G.V. ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Singh

    发明人： Balakrishnan Ganesan ,  Pradeep Nadkarni ,  Arun S. ,  Ramanarayanan G.V. ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Singh

    IPC分类号： C08G64/00 ,  C07D209/44

    CPC分类号： C07D209/46 ,  C08G64/12

    摘要： A method for purifying a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprises contacting a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine with a purification agent, removing a 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound from the crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine, and producing a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine product comprising less than 200 parts per million of the 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound. The purification agent is selected from the group consisting of an acidic material, an organic acid chloride, an organic anhydride, or a combination thereof. The 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound has a formula: wherein each R1 is independently selected from a group consisting of a hydrocarbyl radical, a nitro radical, and a halogen atom; “a” is an integer from 0 to 4; and Ar1 and Ar2 are independently at each occurrence an aromatic radical. The purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines have low color, and are useful for preparing polymers, such as polycarbonates having a low color. The polycarbonates are useful for producing articles.

    摘要翻译： 纯化2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶的方法包括使粗2-二芳基-3,3-双（羟基芳基）苯并二氮吡啶与纯化剂接触，除去2-芳基-3-（氨基芳基 ）-3-（羟基芳基）苯并二氮嘧啶化合物，并制备纯化的2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶产物，其包含小于200份 百万的2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并嘧啶化合物。 净化剂选自酸性物质，有机酰氯，有机酸酐或其组合。 2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并二氮嘧啶化合物具有下式：其中每个R 1独立地选自烃基，硝基和 卤素原子; “a”是从0到4的整数; 且Ar 1和Ar 2在每次出现时独立地为芳族基团。 纯化的2-芳基-3,3-双（羟基芳基）苯二甲酰亚胺具有低的颜色，并且可用于制备聚合物，例如具有低颜色的聚碳酸酯。 聚碳酸酯可用于制造制品。

    Purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines
    4.
    发明授权
    Purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines 有权
    纯化的2-芳基-3,3-双（羟基芳基）苯二甲酰亚胺

    公开(公告)号：US07563817B2

    公开(公告)日：2009-07-21

    申请号：US11300225

    申请日：2005-12-14

    申请人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Vikram Singh

    发明人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Vikram Singh

    IPC分类号： A61K31/405 ,  C07D209/34

    CPC分类号： C07D209/46 ,  C08G64/12

    摘要： A method for purifying a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprises contacting a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine with a purification agent, removing a 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound from the crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine, and producing a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine product comprising less than 200 parts per million of the 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound. The purification agent is selected from the group consisting of an acidic material, an organic acid chloride, an organic anhydride, or a combination thereof. The 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound has a formula: wherein each R1 is independently selected from a group consisting of a hydrocarbyl radical, a nitro radical, and a halogen atom; “a” is an integer from 0 to 4; and Ar1 and Ar2 are independently at each occurrence an aromatic radical. The purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines have low color, and are useful for preparing polymers, such as polycarbonates having a low color. The polycarbonates are useful for producing articles.

    摘要翻译： 纯化2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶的方法包括使粗2-二芳基-3,3-双（羟基芳基）苯并二氮吡啶与纯化剂接触，除去2-芳基-3-（氨基芳基 ）-3-（羟基芳基）苯并二氮嘧啶化合物，并制备纯化的2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶产物，其包含小于200份 百万的2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并嘧啶化合物。 净化剂选自酸性物质，有机酰氯，有机酸酐或其组合。 2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并二氮嘧啶化合物具有下式：其中每个R 1独立地选自烃基，硝基和卤素原子; “a”是从0到4的整数; Ar 1和Ar 2在每次出现时独立地为芳族基团。 纯化的2-芳基-3,3-双（羟基芳基）苯二甲酰亚胺具有低的颜色，并且可用于制备聚合物，例如具有低颜色的聚碳酸酯。 聚碳酸酯可用于制造制品。

    METHODS FOR PRODUCING AND PURIFYING 2-HYDROCARBYL-3,3-BIS(4-HYDROXYARYL)PHTHALIMIDINE MONOMERS AND POLYCARBONATES DERIVED THEREFROM
    5.
    发明申请
    METHODS FOR PRODUCING AND PURIFYING 2-HYDROCARBYL-3,3-BIS(4-HYDROXYARYL)PHTHALIMIDINE MONOMERS AND POLYCARBONATES DERIVED THEREFROM 审中-公开
    2-烃基-3,3-双（4-羟基）苯基咪唑单体和衍生自其的聚碳酸酯的生产和纯化方法

    公开(公告)号：US20080033123A1

    公开(公告)日：2008-02-07

    申请号：US11848009

    申请日：2007-08-30

    申请人： Veeraraghavan Srinivasan ,  Suresh Shanmugam ,  Gautam Chatterjee ,  Anantharaman Dhanabalan ,  Vinod Rai

    发明人： Veeraraghavan Srinivasan ,  Suresh Shanmugam ,  Gautam Chatterjee ,  Anantharaman Dhanabalan ,  Vinod Rai

    IPC分类号： C08G64/04 ,  C07D209/44 ,  C08F6/00

    CPC分类号： C08G64/12 ,  C07D209/34

    摘要： Disclosed herein is a method for producing a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine. The method comprises forming a reaction mixture comprising at least one substituted or unsubstituted phenolphthalein, at least one substituted or unsubstituted primary hydrocarbyl amine, and an acid catalyst; and heating the reaction mixture to a temperature of less than 180° C. to remove a distillate comprising water and form a crude 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine product; where the 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine has a formula: where R1 is selected from the group consisting of a hydrogen and a hydrocarbyl group, and R2 is selected from the group consisting of a hydrogen, a hydrocarbyl group, and a halogen.

    摘要翻译： 本文公开了一种2-烃基-3,3-双（4-羟基芳基）苯并二氮吡啶的制备方法。 该方法包括形成包含至少一种取代或未取代的酚酞，至少一种取代或未取代的伯烃基胺和酸催化剂的反应混合物; 并将反应混合物加热至低于180℃的温度以除去包含水的馏出物并形成粗2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶产物; 其中2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶具有下式：其中R 1选自氢和烃基， 2 H选自氢，烃基和卤素。

    Methods for producing and purifying 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine monomers and polycarbonates derived therefrom
    8.
    发明申请
    Methods for producing and purifying 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine monomers and polycarbonates derived therefrom 有权
    2-烃基-3,3-双（4-羟基芳基）苯并嘧啶单体和衍生自其的聚碳酸酯的制备和纯化方法

    公开(公告)号：US20050222334A1

    公开(公告)日：2005-10-06

    申请号：US10815880

    申请日：2004-03-31

    申请人： Veeraraghavan Srinivasan ,  Suresh Shanmugam ,  Gautam Chatterjee ,  Anantharaman Dhanabalan ,  Vinod Rai

    发明人： Veeraraghavan Srinivasan ,  Suresh Shanmugam ,  Gautam Chatterjee ,  Anantharaman Dhanabalan ,  Vinod Rai

    IPC分类号： C08L1/00

    CPC分类号： C08G64/12 ,  C07D209/34

    摘要： Disclosed herein is a method for producing a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine. The method comprises forming a reaction mixture comprising at least one substituted or unsubstituted phenolphthalein, at least one substituted or unsubstituted primary hydrocarbyl amine, and an acid catalyst; and heating the reaction mixture to a temperature of less than 180° C. to remove a distillate comprising water and form a crude 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine product; where the 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine has a formula: where R1 is selected from the group consisting of a hydrogen and a hydrocarbyl group, and R2 is selected from the group consisting of a hydrogen, a hydrocarbyl group, and a halogen.

    摘要翻译： 本文公开了一种2-烃基-3,3-双（4-羟基芳基）苯并二氮吡啶的制备方法。 该方法包括形成包含至少一种取代或未取代的酚酞，至少一种取代或未取代的伯烃基胺和酸催化剂的反应混合物; 并将反应混合物加热至低于180℃的温度以除去包含水的馏出物并形成粗2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶产物; 其中2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶具有下式：其中R 1选自氢和烃基， 2 H选自氢，烃基和卤素。

    Methods for producing and purifying 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine monomers and polycarbonates derived therefrom
    9.
    发明授权
    Methods for producing and purifying 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine monomers and polycarbonates derived therefrom 有权
    2-烃基-3,3-双（4-羟基芳基）苯并嘧啶单体和衍生自其的聚碳酸酯的制备和纯化方法

    公开(公告)号：US07277230B2

    公开(公告)日：2007-10-02

    申请号：US10815880

    申请日：2004-03-31

    申请人： Veeraraghavan Srinivasan ,  Suresh Shanmugam ,  Gautam Chatterjee ,  Anantharaman Dhanabalan ,  Vinod Kumar Rai

    发明人： Veeraraghavan Srinivasan ,  Suresh Shanmugam ,  Gautam Chatterjee ,  Anantharaman Dhanabalan ,  Vinod Kumar Rai

    IPC分类号： C08F6/00 ,  C08G64/04

    CPC分类号： C08G64/12 ,  C07D209/34

    摘要： Disclosed herein is a method for producing a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine. The method comprises forming a reaction mixture comprising at least one substituted or unsubstituted phenolphthalein, at least one substituted or unsubstituted primary hydrocarbyl amine, and an acid catalyst; and heating the reaction mixture to a temperature of less than 180° C. to remove a distillate comprising water and form a crude 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine product; where the 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine has a formula: where R1 is selected from the group consisting of a hydrogen and a hydrocarbyl group, and R2 is selected from the group consisting of a hydrogen, a hydrocarbyl group, and a halogen.

    摘要翻译： 本文公开了一种2-烃基-3,3-双（4-羟基芳基）苯并二氮吡啶的制备方法。 该方法包括形成包含至少一种取代或未取代的酚酞，至少一种取代或未取代的伯烃基胺和酸催化剂的反应混合物; 并将反应混合物加热至低于180℃的温度以除去包含水的馏出物并形成粗2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶产物; 其中2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶具有下式：其中R 1选自氢和烃基， 2 H选自氢，烃基和卤素。