摘要:
An amino acid based polymer, oligomer or copolymer containing at least 5 mol % of units of a basic amino acid selected from the group consisting of lysine, argenine, ortnithine, trgptophane and mixtures thereof and at least about 5 mol % of a polymerizable compound selected from the group consisting of aliphatic or cycloaliphatic amines, alicyclic amines, diamines, triamines, tetraamines, aliphatic amino alcohols or mixtures thereof, an a process for the production of the said polymer, oligomer or copolymer by condensing at a temperature of at least 120.degree. C. said basic amino acid with at least one of said polymerizable compounds.
摘要:
Condensation products of basic amino acids with copolymerizable compounds which are obtainable by condensing(a) a basic amino acid selected from the group consisting of lysine, arginine, ornithine, tryptophane and mixtures thereof,(b) a copolymerizable compound selected from the group consisting of saturated monobasic carboxylic acids, unsaturated mono-basic carboxylic acids, polybasic carboxylic acids, carboxylic acid anhydrides, diketenes, monohydroxycarboxylic acids, polyhydroxycarboxylic acids and mixtures thereof, and optionally(c) at least one compound selected from the group consisting of amines, lactams, non-proteinogenic acids, alcohols, alkoxylated alcohols, alkoxylated amines, amino sugars, carbohydrates and sugar carboxylic acidsin a molar ratio of (a):(b) of from 100:1 to 1:1 at a temperature of at least 120.degree. C., and a process for the production of said condensation products by condensing compounds (a) and (b) and optionally (c) at a temperature of from 120.degree. to 300.degree. C.
摘要:
A cyclic amine containing polymer substantially free of primary and secondary amino groups which is prepared by reacting:a) an amine selected from the group consisting of:i) cyclic amines having at least one nitrogen atom in the ring and at least one primary amino alkyl group bonded to the nitrogen atom of the ring, andii) mixtures of cyclic amines containing at least two nitrogen atoms which react with a cross-linking agent with at least one other amine containing 1-6 nitrogen atoms which react with a cross-linking agent, withb) at least one cross-linker selected from the group consisting of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms and mixtures of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms with at least one compound containing at least three groups which react with the primary amino group and said nitrogen atoms in a molar ratio of (a):(b) of from 2.5:1 to 1:1.5 thereby forming a cyclic amine containing polymer containing primary or secondary amino groups and reacting said cyclic amine based polymer, withc) an alkylating agent selected from the group consisting of epoxides, alkyl halides, arylalkyl halides, dimethyl sulfate, diethyl sulfate, mixtures of formic acid and an aldehyde, and mixtures of formic acid and a ketone, to convert more than 80% of the primary and secondary nitrogen groups into tertiary nitrogen groups.
摘要:
Amphoteric amine based polymers having a net cationic charge, wherein the polymers are obtained by reacting (a) at least one amine with (b) at least one crosslinking agent, in a molar ratio of (a):(b) of from 2:1 to 1:1.5 and (c) reacting the condensation products of (a) and (b), which are free of anionic groups, with an anionic group containing an alkylating agent or oxidizing their tertiary nitrogen atoms to N-oxides in such an amount that the resulting polymers still have a net cationic charge, and a process for the production of amphoteric amine based polymers having anet cationic charge by reacting the compounds of (a), (b) and (c) the amphoteric amine based polymers may be used as additives in detergents.
摘要:
Compositions than contain from about 1% to about 80% by weight of surfactants selected from the group consisting of nonionic, anionic, cationic, amphoteric or zwitteronic surfactants, or mixtures thereof; and from about 0.1% to about 10%, by weight of a mixture of amino acid based polymers, oligomers or copolymers of the general formula (I) wherein the polymer, oligomer, or copolymer contains at least about 5 mole % of one or more amino acids and an organic acid are disclosed. The compositions are useful as fabric treatment agents as they can impart fabric appearance and integrity benefits to fabrics.
摘要:
Modified polyaspartic acids are obtained by polycondensing (a) 1 to 99.9 mol % aspartic acid with (b) 99 to 0.1 mol % fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic poly-hydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugar carboxylic acids and/or non-proteinogenic aminocarboxylic acids, or by polymerizing monoethylenically unsaturated monomers in the presence of polyaspartic acids, in the manner of radically initiated graft copolymerization. Also disclosed is a process for preparing these modified polyaspartic acids, as well as the use of these modified polyaspartic acids as additives to washing and cleaning agents, as water conditioning agents and as deposit inhibitors during the condensation of sugar juice.
摘要:
Compositions and methods which utilize certain linear amine based polymer, oligomer, or copolymer materials as fabric treatment agents that can impart fabric appearance benefits to fabrics and textiles laundered in washing solutions which contain such materials.
摘要:
Detergent compositions and fabric conditioning compositions which utilize certain anionically modified, oxidized cyclic amine based polymers, oligomers or copolymer materials. These anionically modified, cyclic amine based polymers, oilgomers or copolymers materials can impart fabric appearance and integrity benefits to fabrics and textiles laundered in washing solutions which contain such materials.
摘要:
Detergent compositions and fabric conditioning compositions which utilize certain oxidized cyclic amine based polymers, oligomers, or copolymers are disclosed. These oxidized cyclic amine based polymers, oligomers, or copolymer materials serve as fabric treatment agents that can impart fabric appearance and integrity benefits to fabrics and textiles laundered in washing solutions which contain such materials.
摘要:
The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula: —(R1O)m(R2O)nR3 wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one —(R1O) unit is attached to the backbone prior to attachment of an —(R2O) unit and further provided m+n is at least 12.