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    SOLID COMPOSITION CONSISTING OF HETEROCYCLIC COMPOUNDS AND/OR OXIME ESTERS AND INERT POROUS CARRIER MATERIALS AND THE USE THEREOF AS STABLE BLEACH ACTIVATOR COMPONENT IN DETERGENTS, BLEACHES AND CLEANERS
    1.
    发明授权
    SOLID COMPOSITION CONSISTING OF HETEROCYCLIC COMPOUNDS AND/OR OXIME ESTERS AND INERT POROUS CARRIER MATERIALS AND THE USE THEREOF AS STABLE BLEACH ACTIVATOR COMPONENT IN DETERGENTS, BLEACHES AND CLEANERS 失效
    固体组合物包含杂环化合物和/或氧化剂和惰性载体材料及其作为洗涤剂，漂白剂和清洁剂中稳定的漂白活化剂组分的用途

    公开(公告)号：US06451753B2

    公开(公告)日：2002-09-17

    申请号：US09091238

    申请日：1998-06-16

    申请人： Günter Oetter ,  Thomas Wehlage ,  Elisabeth Kappes ,  Reinhard Müller ,  Dieter Boeckh ,  Michael Schönherr

    发明人： Günter Oetter ,  Thomas Wehlage ,  Elisabeth Kappes ,  Reinhard Müller ,  Dieter Boeckh ,  Michael Schönherr

    IPC分类号： C11D328

    CPC分类号： C11D3/3935 ,  C07D223/10 ,  C11D3/3907 ,  C11D3/392 ,  C11D17/0034

    摘要： A solid composition consisting essentially of 5-98 parts by weight of heterocyclic compounds I where L1 is groups with a cyclic carbamate, a lactonoxy or a lactam structure, X is a carbonyl, a doubled carbonyl or a heterocarbonyl group, and R1 is an organic radical or a second moiety L1, and/or oxime esters II where L2 is an oxime moiety where R2, R3 and Z4 are organic radicals or linkers, L3 is the radical R1, a second oxime moiety L2 or a carboxylic ester residue, carboxamide residue, phenolate residue, vinyloxy radical, sulfonamide residue, imidazole residue, amidolactam residue, cyclic carbamate residue, lactonoxy residue or lactam residue, and m is 0 or 1, and 2-95 parts by weight of inert porous carrier materials with an internal surface area of from 10 to 500 m2/g. The solid composition described is suitable as stable bleach activator component in detergents, bleaches and cleaners.

    摘要翻译： 基本上由5-98重量份的杂环化合物I其中L 1与环状氨基甲酸酯，内酯氧基或内酰胺结构基团组成的固体组合物，X是羰基，双羰基或杂羰基，R 1是有机基团或 第二部分L1和/或肟酯II其中L 2是肟部分，其中R 2和R 3是有机基团或连接基团，L 3是基团R 1，第二肟部分L 2或羧酸酯残基，甲酰胺残基，酚盐残基，乙烯基氧基， 磺酰胺残基，咪唑残基，酰胺内酰胺残基，环状氨基甲酸酯残基，内酯氧基残基或内酰胺残基，m为0或1，2-95重量份内表面积为10〜500m 2 / g的惰性多孔载体材料 所述的固体组合物适用于洗涤剂，漂白剂和清洁剂中的稳定的漂白活化剂组分。

    Cyclic amine based polymers and process for their production
    2.
    发明授权
    Cyclic amine based polymers and process for their production 有权
    循环胺基聚合物及其生产方法

    公开(公告)号：US6111056A

    公开(公告)日：2000-08-29

    申请号：US153307

    申请日：1998-09-15

    申请人： Soren Hildebrandt ,  Elisabeth Kappes ,  Dieter Boeckh ,  Rajan Panandiker ,  Sherri Randall ,  Eugene Paul Gosselink ,  William Conrad Wertz

    发明人： Soren Hildebrandt ,  Elisabeth Kappes ,  Dieter Boeckh ,  Rajan Panandiker ,  Sherri Randall ,  Eugene Paul Gosselink ,  William Conrad Wertz

    IPC分类号： C08G73/02 ,  C08G73/06 ,  C11D3/00 ,  C11D3/22 ,  C11D3/37 ,  C11D3/382 ,  C08G69/00 ,  C08F8/02 ,  C08G12/00 ,  C08L79/02

    CPC分类号： C08G73/0273 ,  C08G73/02 ,  C08G73/022 ,  C08G73/0616 ,  C11D3/0015 ,  C11D3/225 ,  C11D3/227 ,  C11D3/3723 ,  C11D3/3776

    摘要： A cyclic amine containing polymer substantially free of primary and secondary amino groups which is prepared by reacting:a) an amine selected from the group consisting of:i) cyclic amines having at least one nitrogen atom in the ring and at least one primary amino alkyl group bonded to the nitrogen atom of the ring, andii) mixtures of cyclic amines containing at least two nitrogen atoms which react with a cross-linking agent with at least one other amine containing 1-6 nitrogen atoms which react with a cross-linking agent, withb) at least one cross-linker selected from the group consisting of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms and mixtures of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms with at least one compound containing at least three groups which react with the primary amino group and said nitrogen atoms in a molar ratio of (a):(b) of from 2.5:1 to 1:1.5 thereby forming a cyclic amine containing polymer containing primary or secondary amino groups and reacting said cyclic amine based polymer, withc) an alkylating agent selected from the group consisting of epoxides, alkyl halides, arylalkyl halides, dimethyl sulfate, diethyl sulfate, mixtures of formic acid and an aldehyde, and mixtures of formic acid and a ketone, to convert more than 80% of the primary and secondary nitrogen groups into tertiary nitrogen groups.

    摘要翻译： 一种基本上不含伯和仲氨基的含环胺的聚合物，其通过以下方法制备：a）选自以下的胺：i）环中具有至少一个氮原子的环胺和至少一个伯氨基烷基 基团与环的氮原子键合，以及ii）含有至少两个氮原子的环状胺的混合物，其与交联剂与至少一种含有1-6个氮原子的其它胺反应，其与交联反应 其中b）至少一个选自至少一种含有两个与伯氨基和所述氮原子反应的基团的化合物的交联剂以及至少一种含有两个与主要氨基反应的基团的化合物的混合物 氨基和所述氮原子与至少一种含有至少三个与伯氨基和所述氮原子反应的化合物，其摩尔比为（a）：（b）为2 1.5:1至1:1.5，由此形成含有伯胺或仲氨基的含环胺的聚合物，并使所述环胺基聚合物与c）选自环氧化物，烷基卤，芳烷基卤化物，二甲基 硫酸盐，二乙基硫酸盐，甲酸和醛的混合物，以及甲酸和酮的混合物，将80％以上的初级和次级氮基团转化为叔氮基团。