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    Process for the isomerization of alkenes having a terminal double bond to give alkenes having an internal double bond
    1.
    发明授权
    Process for the isomerization of alkenes having a terminal double bond to give alkenes having an internal double bond 失效
    具有末端双键的烯烃异构化的方法，得到具有内部双键的烯烃

    公开(公告)号：US5008466A

    公开(公告)日：1991-04-16

    申请号：US336926

    申请日：1989-04-12

    申请人： Bernhard Schleppinghoff ,  Hans-Dieter Kohler ,  Christian Gabel ,  Hans-Volker Scheef

    发明人： Bernhard Schleppinghoff ,  Hans-Dieter Kohler ,  Christian Gabel ,  Hans-Volker Scheef

    IPC分类号： C07C2/28 ,  C07C5/25 ,  C07C7/163 ,  C07C41/06

    CPC分类号： C07C41/06 ,  C07C2/28 ,  C07C5/2568 ,  C07C7/163 ,  C07C2531/08 ,  C07C2531/26

    摘要： Alkenes having a terminal double bond can be isomerized to give alkenes having an internal double bond if alkenes having a terminal double bond or hydrocarbon feedstock having a content of alkenes of this type having a terminal double bond are subjected to treatment, in the presence of hydrogen, over a macroporous or gel-like cation exchanger in the H.sup.+ form which contains 0.001 to 10 g of one or more metals of the VIth and/or VIIth and/or VIIIth sub-group of the periodic system of the elements in elementary form per liter of dry cation exchanger and which has a degree of crosslinking of 2 to 65% and a specific surface area of 5 to 750 m.sup.2 /g of dry exchange resin. The treatment is carried out in the liquid phase at a temperature from 0.degree. to 120.degree. C.

    摘要翻译： 如果具有末端双键的烯烃或具有末端双键的烯烃含量的烃原料在氢气存在下进行处理，则可以将具有末端双键的烯烃异构化，得到具有内部双键的烯烃 在H +形式的大孔或凝胶状阳离子交换剂中含有0.001至10g元素周期性系统的第VI和/或第VII和/或VIII族亚基中的一种或多种金属，基本形式为 升的干燥阳离子交换剂，其交联度为2〜65％，比表面积为5〜750m 2 / g的干交换树脂。 处理在液相中在0℃至120℃的温度下进行。

    Process for isolating cyclopentane and/or cyclopentene
    6.
    发明授权
    Process for isolating cyclopentane and/or cyclopentene 失效
    用于分离环戊烷和/或环戊烯的方法

    公开(公告)号：US06468399B2

    公开(公告)日：2002-10-22

    申请号：US09784853

    申请日：2001-02-16

    申请人： Arnd Stüwe ,  Rolf Dieter Wurtz ,  Michael Müller ,  Jens Herwig ,  Christian Gabel ,  Joachim Grub

    发明人： Arnd Stüwe ,  Rolf Dieter Wurtz ,  Michael Müller ,  Jens Herwig ,  Christian Gabel ,  Joachim Grub

    IPC分类号： B01D300

    CPC分类号： C07C13/10 ,  C07C9/18 ,  C07C13/12 ,  C07C2601/08 ,  C07C2601/10 ,  Y10S203/20

    摘要： Cyclopentane and/or cyclopentene and, if desired, isopentane can be obtained by distillative separation from a pre-benzene fraction or a C5 fraction which has in each case being partially hydrogenated to remove acetylene compounds and diolefins, wherein a) in a first fractional distillation, low boilers are removed as first top product and, either b1) the first bottom product is fed to a second fractional distillation and there cyclopentene is taken off as second top product and cyclopentane and higher-boiling hydrocarbons are taken off as second bottom product and this second bottom product is separated into cyclopentene and higher boilers in a third fractional distillation, or b2) the first bottom product is subjected to a catalytic hydrogenation and subsequently, in a fractional distillation, separated into cyclopentane as top product and higher boilers as bottom product, or b3) the first bottom product is subjected to a fractional distillation to separate off the relatively high boilers as bottom product and the top product is subjected to a catalytic hydrogenation to form cyclopentene.

    摘要翻译： 如果需要，可以通过蒸馏分离前苯馏分或C5馏分获得环戊烷和/或环戊烯，每个馏分在每种情况下都被部分氢化除去乙炔化合物和二烯烃，其中a）在第一分馏中， 作为第一顶级产品除去低锅炉，并且b）将第一底部产物进料至第二次分馏，并且将环戊烯作为第二顶部产物取出，将环戊烷和较高沸点烃作为第二底部产物取出， 底部产物在第三次分馏中分离成环戊烯和更高级的锅炉，orb2）第一个底部产物进行催化氢化，随后在分馏中分离成环戊烷作为顶部产物，较高的锅炉作为底部产物，orb3） 第一个底部产品进行分馏以分离相对较高的锅炉 作为底部产物，顶部产物进行催化氢化以形成环戊烯。

    Process for isolating cyclopentane and/or cyclopentene
    7.
    发明授权
    Process for isolating cyclopentane and/or cyclopentene 失效
    用于分离环戊烷和/或环戊烯的方法

    公开(公告)号：US06264799B1

    公开(公告)日：2001-07-24

    申请号：US09264145

    申请日：1999-03-05

    申请人： Arnd Stüwe ,  Rolf Dieter Wurtz ,  Michael Müller ,  Jens Herwig ,  Christian Gabel ,  Joachim Grub

    发明人： Arnd Stüwe ,  Rolf Dieter Wurtz ,  Michael Müller ,  Jens Herwig ,  Christian Gabel ,  Joachim Grub

    IPC分类号： B01D300

    CPC分类号： C07C13/10 ,  C07C9/18 ,  C07C13/12 ,  C07C2601/08 ,  C07C2601/10 ,  Y10S203/20

    摘要： Cyclopentane and/or cyclopentene and, if desired, isopentane can be obtained by distillative separation from a pre-benzene fraction or a C5 fraction which has in each case being partially hydrogenated to remove acetylene compounds and diolefins, wherein a) in a first fractional distillation, low boilers are removed as first top product and, either b1) the first bottom product is fed to a second fractional distillation and there cyclopentene is taken off as second top product and cyclopentane and higher-boiling hydrocarbons are taken off as second bottom product and this second bottom product is separated into cyclopentene and higher boilers in a third fractional distillation, or b2) the first bottom product is subjected to a catalytic hydrogenation and subsequently, in a fractional distillation, separated into cyclopentane as top product and higher boilers as bottom product, or b3) the first bottom product is subjected to a fractional distillation to separate off the relatively high boilers as bottom product and the top product is subjected to a catalytic hydrogenation to form cyclopentene.

    摘要翻译： 如果需要，可以通过蒸馏分离前苯馏分或C5馏分获得环戊烷和/或环戊烯，每个馏分在每种情况下都被部分氢化除去乙炔化合物和二烯烃，其中a）在第一分馏中， 作为第一顶级产品除去低锅炉，并且b）将第一底部产物进料至第二次分馏，并且将环戊烯作为第二顶部产物取出，将环戊烷和较高沸点烃作为第二底部产物取出， 底部产物在第三次分馏中分离成环戊烯和更高级的锅炉，orb2）第一个底部产物进行催化氢化，随后在分馏中分离成环戊烷作为顶部产物，较高的锅炉作为底部产物，orb3） 第一个底部产品进行分馏以分离相对较高的锅炉 作为底部产物，顶部产物进行催化氢化以形成环戊烯。