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1.发明授权Preparation of polyamide from diisocyanate with alkali metal lactamate catalyst 失效用二异氰酸酯与碱金属氨基甲酸酯催化剂制备聚酰胺
公开(公告)号：US4094866A
公开(公告)日：1978-06-13
申请号：US769313
申请日：1977-02-17
申请人： Besir K. Onder
发明人： Besir K. Onder
CPC分类号： C08G18/341 , C08G18/225 , C08G18/345 , C08G18/346 , C08G69/00 , C08G73/1035
摘要： The use of certain catalysts provide for an improved process for the preparation of soluble polyimides, polyamides, and polyamideimides. The catalysts are compounds of formula ##STR1## wherein M represents an alkali metal, and n is an integer from 2 to 5 inclusive. The improved process comprises reacting organic diisocyanates with polycarboxylic compounds consisting of tetracarboxylic acids or the intramolecular dianhydrides thereof, tricarboxylic acids or the monoanhydrides thereof, dicarboxylic acids, and mixtures thereof, in the presence of said catalysts. The polymers are obtained in solution at low reaction temperatures and short reaction times thereby avoiding side-reactions which otherwise would be detrimental to polymer molecular weight and ultimate polymer properties.
摘要翻译： 使用某些催化剂提供了制备可溶性聚酰亚胺，聚酰胺和聚酰胺酰亚胺的改进方法。 催化剂是式IMA的化合物，其中M表示碱金属，n是2至5的整数，包括端值。 改进的方法包括在所述催化剂存在下，使有机二异氰酸酯与由四羧酸或其分子内二酸酐，三羧酸或其一酸酐，二羧酸及其混合物组成的多元羧酸化合物反应。 聚合物在低反应温度和较短的反应时间下在溶液中得到，从而避免副反应，否则这将对聚合物分子量和最终聚合物性能有害。
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2.发明授权Copolyamide from arylene diamine and mixture of alkylene dicarboxylic acids 失效来自亚芳基二胺的共聚酰胺和亚烷基二羧酸的混合物
公开(公告)号：US4065441A
公开(公告)日：1977-12-27
申请号：US664763
申请日：1976-03-08
CPC分类号： C08G69/265
摘要： Novel copolyamides having the recurring unit ##STR1## are disclosed wherein x, in 50 percent to 85 percent of the recurring units, is an integer from 6 to 10 inclusive, and, in 15 percent to 50 percent of the recurring units is 4, and Ar is an arylene radical. The copolyamides are characterized by ease of melt processing such as in molding, extruding, and injection molding, while at the same time possessing good physical properties, and being further characterized by their ease of conversion from the amorphous to the crystalline state which, in turn, gives rise to a high degree of versatility in their fabrication.
摘要翻译： 公开了具有重复单元“IMAGE”的新型共聚酰胺，其中x，在50％至85％的重复单元中，为6至10的整数，其中15％至50％的重复单元为4，和 Ar是亚芳基。 共聚酰胺的特征在于易于熔融加工，例如在模塑，挤出和注射成型中，同时具有良好的物理性能，并且进一步的特征在于它们易于从无定形转变成结晶状态， ，在其制造中产生高度的多功能性。
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3.发明授权Preparation of polyamideimide from organic diisocyanate with alkali metal salt of alcohol as catalyst 失效用有机二异氰酸酯与醇的碱金属盐作催化剂制备聚酰胺酰亚胺
公开(公告)号：US4061623A
公开(公告)日：1977-12-06
申请号：US735758
申请日：1976-10-26
申请人： Besir K. Onder
发明人： Besir K. Onder
CPC分类号： C08G73/1035 , C08G18/225 , C08G18/341 , C08G18/345 , C08G18/346
摘要： The use of certain catalysts provide for an improved process for the preparation of soluble polyimides, polyamides, and polyamideimides. The catalysts are alkali metal salts of formula MOR, wherein R represents alkyl or aryl and M represents an alkali metal. The improved process comprises reacting organic diisocyanates with polycarboxylic compounds consisting of tetracarboxylic acids or the intramolecular dianhydrides thereof, tricarboxylic acids or the monoanhydrides thereof, dicarboxylic acids, and mixtures thereof, in the presence of said catalysts. The polymers are obtained in solution at low reaction temperatures and short reaction times thereby avoiding side-reactions which otherwise would be detrimental to polymer molecular weight and ultimate polymer properties.
摘要翻译： 使用某些催化剂提供了制备可溶性聚酰亚胺，聚酰胺和聚酰胺酰亚胺的改进方法。 催化剂是式MOR的碱金属盐，其中R代表烷基或芳基，M代表碱金属。 改进的方法包括在所述催化剂存在下，将有机二异氰酸酯与由四羧酸或其分子内二酸酐，三羧酸或其一酸酐，二羧酸及其混合物组成的多元羧酸化合物反应。 聚合物在低反应温度和较短的反应时间下在溶液中得到，从而避免副反应，否则这将对聚合物分子量和最终聚合物性能有害。
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4.发明授权Alkali metal lactamate catalyst for the polymerization of diisocyanate with tetracarboxylic acid/dianhydride 失效用四羧酸/二酐聚合二异氰酸酯的碱金属乳酸胺催化剂
公开(公告)号：US4021412A
公开(公告)日：1977-05-03
申请号：US521745
申请日：1974-11-07
申请人： Besir K. Onder
发明人： Besir K. Onder
CPC分类号： C08G18/341 , C08G18/225 , C08G18/345 , C08G18/346 , C08G69/00 , C08G73/1035
摘要： The use of certain catalysts provide for an improved process for the preparation of soluble polyimides, polyamides, and polyamideimides. The catalysts are compounds of formula ##STR1## wherein M represents an alkali metal, and n is an integer from 2 to 5 inclusive. The improved process comprises reacting organic diisocyanates with polycarboxylic compounds consisting of tetracarboxylic acids or the intramolecular dianhydrides thereof, tricarboxylic acids or the monoanhydrides thereof, dicarboxylic acids, and mixtures thereof, in the presence of said catalysts. The polymers are obtained in solution at low reaction temperatures and short reaction times thereby avoiding side-reactions which otherwise would be detrimental to polymer molecular weight and ultimate polymer properties.
摘要翻译： 使用某些催化剂提供了制备可溶性聚酰亚胺，聚酰胺和聚酰胺酰亚胺的改进方法。 催化剂是式IMA的化合物，其中M表示碱金属，n是2至5的整数，包括端值。 改进的方法包括在所述催化剂存在下，将有机二异氰酸酯与由四羧酸或其分子内二酸酐，三羧酸或其一酸酐，二羧酸及其混合物组成的多元羧酸化合物反应。 聚合物在低反应温度和较短的反应时间下在溶液中得到，从而避免副反应，否则这将对聚合物分子量和最终聚合物性能有害。
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5.发明授权Polyamide from arylene diamine, isophthalic acid and alkylene dicarboxylic acid 失效来自亚芳基二胺，间苯二甲酸和亚烷基二羧酸的聚酰胺
公开(公告)号：US4072665A
公开(公告)日：1978-02-07
申请号：US664764
申请日：1976-03-08
申请人： Besir K. Onder
发明人： Besir K. Onder
CPC分类号： C08G69/00 , C08G69/265 , Y10T428/31725
摘要： Novel copolyamides having the recurring unit ##STR1## are disclosed wherein R, in 60 percent to 85 percent of the recurring units, is --CH.sub.2 --.sub.x wherein x is an integer from 7 to 12 inclusive, and, in 15 percent to 40 percent of the recurring units, R is m-phenylene; and Ar is an arylene radical. The copolyamides are characterized by ease of melt processing such as in molding, extruding, and injection molding, while at the same time possessing good high temperature stability, and being further characterized by unexpectedly high impact and flexural strengths.
摘要翻译： 公开了具有重复单元“IMAGE”的新型共聚酰胺，其中60％至85％的重复单元中的R为-CH 2-x，其中x为7至12的整数，其中，15％至40％ 重复单元，R是间亚苯基; Ar是亚芳基。 共聚酰胺的特征在于易于熔融加工，例如在模塑，挤出和注射成型中，同时具有良好的高温稳定性，并且进一步的特征在于意想不到的高冲击强度和弯曲强度。
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6.发明授权Preparation of polyamide from organic diisocyanate with alkali metal salt of alcohol as catalyst 失效用有机二异氰酸酯与醇的碱金属盐作催化剂制备聚酰胺
公开(公告)号：US4061622A
公开(公告)日：1977-12-06
申请号：US735757
申请日：1976-10-26
申请人： Besir K. Onder
发明人： Besir K. Onder
CPC分类号： C08G73/1035 , C08G18/225 , C08G18/341 , C08G18/345 , C08G18/346
摘要： The use of certain catalysts provide for an improved process for the preparation of soluble polyimides, polyamides, and polyamideimides. The catalysts are alkali metal salts of formula MOR, wherein R represents alkyl or aryl and M represents an akali metal. The improved process comprises reacting organic diisocyanates with polycarboxylic compounds consisting of tetracarboxylic acids or the intramolecular dianhydrides thereof, tricarboxylic acids or the monoanhydrides thereof, dicarboxylic acids, and mixtures thereof, in the presence of said catalysts. The polymers are obtained in solution at low reaction temperatures and short reaction times thereby avoiding side-reactions which otherwise would be detrimental to polymer molecular weight and ultimate polymer properties.
摘要翻译： 使用某些催化剂提供了制备可溶性聚酰亚胺，聚酰胺和聚酰胺酰亚胺的改进方法。 催化剂是式MOR的碱金属盐，其中R代表烷基或芳基，M代表碱金属。 改进的方法包括在所述催化剂存在下，将有机二异氰酸酯与由四羧酸或其分子内二酸酐，三羧酸或其一酸酐，二羧酸及其混合物组成的多元羧酸化合物反应。 聚合物在低反应温度和较短的反应时间下在溶液中得到，从而避免副反应，否则这将对聚合物分子量和最终聚合物性能有害。
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7.发明授权Preparation of polyamideimide from diisocyanate with alkali metal lactamate catalyst 失效用二异氰酸酯与碱金属氨基甲酸酯催化剂制备聚酰胺酰亚胺
公开(公告)号：US4094864A
公开(公告)日：1978-06-13
申请号：US769312
申请日：1977-02-17
申请人： Besir K. Onder
发明人： Besir K. Onder
CPC分类号： C08G18/341 , C08G18/225 , C08G18/345 , C08G18/346 , C08G69/00 , C08G73/1035
摘要： The use of certain catalysts provide for an improved process for the preparation of soluble polyimides, polyamides, and polyamideimides. The catalysts are compounds of formula ##STR1## WHEREIN M represents an alkali metal, and n is an integer from 2 to 5 inclusive. The improved process comprises reacting organic diisocyanates with polycarboxylic compounds consisting of tetracarboxylic acids or the intramolecular dianhydrides thereof, tricarboxylic acids or the monoanhydrides thereof, dicarboxylic acids, and mixtures thereof, in the presence of said catalysts. The polymers are obtained in solution at low reaction temperatures and short reaction times thereby avoiding side-reactions which otherwise would be detrimental to polymer molecular weight and ultimate polymer properties.
摘要翻译： 使用某些催化剂提供了制备可溶性聚酰亚胺，聚酰胺和聚酰胺酰亚胺的改进方法。 催化剂是式（I）的化合物，其中M表示碱金属，n是2-5的整数。 改进的方法包括在所述催化剂存在下，将有机二异氰酸酯与由四羧酸或其分子内二酸酐，三羧酸或其一酸酐，二羧酸及其混合物组成的多元羧酸化合物反应。 聚合物在低反应温度和较短的反应时间下在溶液中得到，从而避免副反应，否则这将对聚合物分子量和最终聚合物性能有害。
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8.发明授权
公开(公告)号：US3985934A
公开(公告)日：1976-10-12
申请号：US575658
申请日：1975-05-08
CPC分类号： D01F6/78 , D01D5/253 , Y10T428/2969 , Y10T428/2973 , Y10T428/2978
摘要： High temperature resistant aromatic copolyimide fibers are disclosed together with processes for their preparation by wet and dry spinning techniques from solvent soluble copolyimides. The latter are prepared from benzophenone-3,3',4,4'-tetracarboxylic acid dianhydride and a mixture of 4,4'-methylenebis(phenyl isocyanate) and toluene diisocyanate (2,4-, or 2,6-isomer, or mixtures thereof). The wet spinning process can be stopped at any one of the stages taught, to yield useful fibers. The choice of coagulant fluid in the spin bath controls the fiber cross-section which in turn controls certain fiber characteristics. When glycerine or a low molecular weight aliphatic glycol is employed as coagulant fluid, the high temperature fiber obtained has advantageous properties which are otherwise difficult or impossible to obtain.
摘要翻译： 公开了耐高温芳族共聚酰亚胺纤维及其通过溶剂可溶共聚酰亚胺的湿法和干法纺丝技术制备的方法。 后者由二苯甲酮-3,3'，4,4'-四羧酸二酐和4,4'-亚甲基双（苯基异氰酸酯）和甲苯二异氰酸酯（2,4-或2,6-异构体， 或其混合物）。 可以在所教导的任何一个阶段停止湿法纺丝过程，以产生有用的纤维。 旋转浴中絮凝剂的选择控制纤维横截面，从而控制某些纤维特性。 当使用甘油或低分子量脂肪族二醇作为絮凝剂时，获得的高温纤维具有其他困难或不可能获得的有利性质。
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公开(公告)号：US4017459A
公开(公告)日：1977-04-12
申请号：US614838
申请日：1975-09-19
申请人： Besir K. Onder
发明人： Besir K. Onder
IPC分类号： C08G73/14
CPC分类号： C08G73/14
摘要： Polyamide-imides are described which are derived by conventional procedures from 2,2-bis[4-(p-aminophenoxy)-phenyl]propane (or the corresponding diisocyanate) and trimellitic acid (preferably through the anhydride acid chloride). Copolyamide-imides derived from trimellitic acid, the above diamine (or diisocyanate) and certain other aromatic diamines or diisocyanates (4,4'-diaminodiphenyl ether, m-phenylene diamine and corresponding diisocyanates are preferred) are also described. The above polyamide-imides are engineering thermoplastics which, unlike closely related polyamides and polyimides, can be extruded and injection molded to form parts having good mechanical properties.
摘要翻译： 描述了通过常规方法由2,2-双[4-（对氨基苯氧基） - 苯基]丙烷（或相应的二异氰酸酯）和偏苯三酸（优选通过酸酐酰氯）衍生的聚酰胺 - 酰亚胺。 还描述了衍生自偏苯三酸，上述二胺（或二异氰酸酯）和某些其它芳族二胺或二异氰酸酯（4,4'-二氨基二苯醚，间苯二胺和相应的二异氰酸酯）的共聚酰胺 - 酰亚胺。 上述聚酰胺 - 酰亚胺是工程热塑性塑料，其与密切相关的聚酰胺和聚酰亚胺不同，可以挤出和注射成型以形成具有良好机械性能的部件。
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10.发明授权Preparation of polyimide from organic diisocyanate with alkali metal salt of alcohol as catalyst 失效用有机二异氰酸酯与醇的碱金属盐作催化剂制备聚酰亚胺
公开(公告)号：US4001186A
公开(公告)日：1977-01-04
申请号：US521744
申请日：1974-11-07
申请人： Besir K. Onder
发明人： Besir K. Onder
CPC分类号： C08G73/1035 , C08G18/225 , C08G18/341 , C08G18/345 , C08G18/346
摘要： The use of certain catalysts provide for an improved process for the preparation of soluble polyimides, polyamides, and polyamideimides. The catalysts are alkali metal salts of formula MOR, wherein R represents alkyl or aryl and M represents an alkali metal. The improved process comprises reacting organic diisocyanates with polycarboxylic compounds consisting of tetracarboxylic acids or the intramolecular dianhydrides thereof, tricarboxylic acids or the monoanhydrides thereof, dicarboxylic acids, and mixtures thereof, in the presence of said catalysts. The polymers are obtained in solution at low reaction temperatures and short reaction times thereby avoiding side-reactions which otherwise would be detrimental to polymer molecular weight and ultimate polymer properties.
摘要翻译： 使用某些催化剂提供了制备可溶性聚酰亚胺，聚酰胺和聚酰胺酰亚胺的改进方法。 催化剂是式MOR的碱金属盐，其中R代表烷基或芳基，M代表碱金属。 改进的方法包括在所述催化剂存在下，将有机二异氰酸酯与由四羧酸或其分子内二酸酐，三羧酸或其一酸酐，二羧酸及其混合物组成的多元羧酸化合物反应。 聚合物在低反应温度和较短的反应时间下在溶液中得到，从而避免副反应，否则这将对聚合物分子量和最终聚合物性能有害。
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