Softener active derived from acylated triethanolamine
    5.
    发明授权
    Softener active derived from acylated triethanolamine 有权
    由酰化三乙醇胺衍生的柔软剂

    公开(公告)号:US06486121B2

    公开(公告)日:2002-11-26

    申请号:US09424135

    申请日:1999-11-18

    IPC分类号: C11D162

    CPC分类号: C11D3/0015 C11D1/62

    摘要: Fabric softener compounds having the formula: [RC(O)]nN+(R1)mX− wherein each R in a compound is a C6-C22 hydrocarbyl group, preferably having an IV from about 70 to about 140 based upon the IV of the equivalent fatty acid, n is a number from 1 to three on the weight average in any mixture of compounds, each R1 in a compound is a C1-3 alkyl or hydroxy alkyl group, the total of n and the number of R1 groups that are hydroxyethyl groups equaling 3, n+m=4 and X is a softener compatible anion, preferably methyl sulfate, the compound, or mixtures of such compounds, having (a) either a Hunter “L” transmission of at least about 85, typically from about 85 to about 95, preferably from about 90 to about 95, more preferably above about 95, if possible, (b) only non-detectable levels, at the conditions of use, of odorous compounds selected from the group consisting of: isopropyl acetate, which should be, less than about 5, preferably less than about 3, and more preferably less than about 2, &eegr;g/L.; 2,2′-ethylidenebis(oxy)bispropane, which should be less than about 200, preferably less than about 100, more preferably less than about 10, and even more preferably less than about 5, &eegr;g/L.; 1,3,5-trioxane, which should be less than about 50, preferably less than about 20, more preferably less than about 10, and even more preferably less than about 7, &eegr;g/L.; and/or each short chain fatty acid (4-12, especially 6-10, carbon atoms) ester, especially methyl esters, which should be less than about 4, preferably less than about 3, and more preferably less than about 2, &eegr;g/L. or (c) preferably, both. The fabric softener actives are preferably prepared in the presence of chelating agent and/or antioxidant, as disclosed herein. Such materials are new. Solvents can be present.

    摘要翻译: 具有下式的织物柔软剂化合物:[RC(O)] nN +(R1)mX-其中化合物中的每个R是C6-C22烃基,优选具有约70至约140的IV,基于当量的IV 脂肪酸,n是任何化合物混合物中重量平均值为1至3的数,化合物中的每个R 1为C 1-3烷基或羟基烷基,n为总数,R 1基团为羟乙基 基团等于3,n + m = 4,X是柔软剂相容的阴离子,优选甲基硫酸盐,化合物或这些化合物的混合物,其具有(a)至少约85的亨特“L”透射率,通常为约 如果可能的话,(85)至约95,优选约90-约95,更优选高于约95,(b)在使用条件下,只有不可检测的含量选自乙酸异丙酯, 其应当小于约5,优选小于约3,更优选小于约2,etag / L 。 2,2'-亚乙基双(氧)双丙烷,其应小于约200,优选小于约100,更优选小于约10,甚至更优选小于约5,etag / L。 1,3,5-三恶烷,其应当小于约50,优选小于约20,更优选小于约10,甚至更优选小于约7,etag / L。 和/或每个短链脂肪酸(4-12,特别是6-10个碳原子)酯,特别是甲酯,其应当小于约4,优选小于约3,更优选小于约2,etag / L。 或(c)优选两者。 织物柔软剂活性剂优选在本文公开的螯合剂和/或抗氧化剂存在下制备。 这些材料是新的。 溶剂可以存在。