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1.发明申请GAS TURBINE TOPPING DEVICE IN A SYSTEM FOR MANUFACTURING SULFURIC ACID AND METHOD OF USING TURBINE TO RECOVER ENERGY IN MANUFACTURE OF SULFURIC ACID 有权用于制造硫酸的系统中的气体涡轮机顶板装置和使用涡轮机回收能量的方法来制造硫酸公开(公告)号：US20090077944A1
公开(公告)日：2009-03-26
申请号：US12237470
申请日：2008-09-25
申请人： Bogdan Wojak
发明人： Bogdan Wojak
CPC分类号： C01B17/54 , C01B17/0473 , C01B17/74 , F02C6/10 , F02C6/18 , Y02A50/2327 , Y02A50/2328 , Y02E20/12 , Y02P20/129 , Y02P20/13 , Y02P20/131 , Y10T137/0318
摘要： A gas turbine topping device, which is disposed upstream of a steam-raising section, is used for generating power in the manufacture of sulphuric acid. A sulfur-burning combustor generates hot sulfur dioxide while a pressure-exchanging ejector mixes the hot combustion gases with a cooler gas (e.g. pressurized air, pressurized N2 or recycled sulfur dioxide (SO2) to form a mixed working gas having a temperature below the maximum allowable temperature (metallurgical limit) of the blades of the turbine. The turbine drives an oxygen compressor which supplies oxygen to a bubbling chamber which also receives S8 to produce sulfur vapor for combustion. By using stoichiometric quantities, sulfur dioxide is delivered in requisite quantities to a sulfuric acid plant without any harmful emissions. Useful amounts of electrical power can thus be generated by the gas turbine topping device as well as the downstream steam turbine by harnessing the enormous amount of waste heat involved in the manufacture of sulfuric acid.
摘要翻译： 设置在蒸汽提升部分的上游的燃气轮机顶部装置用于在硫酸的制造中产生动力。 硫燃烧的燃烧器产生热二氧化硫，而压力交换喷射器将热燃烧气体与较冷气体（例如加压空气，加压的N 2或再循环的二氧化硫（SO 2））混合，形成温度低于最大值的混合工作气体 涡轮机驱动氧气压缩机，该氧气压缩机将氧气供应到也接收S8以产生硫蒸汽用于燃烧的发泡室，通过使用化学计量的量将二氧化硫以必需的量输送到 一个没有任何有害排放物的硫酸设备，因此可以通过燃气轮机顶部装置以及下游的蒸汽轮机，通过利用大量的硫酸制造所涉及的废热产生有用的电力。
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公开(公告)号：US10066834B2
公开(公告)日：2018-09-04
申请号：US14762846
申请日：2013-04-15
申请人： Bogdan Wojak
发明人： Bogdan Wojak
CPC分类号： F23J15/02 , B01D53/62 , B01D53/75 , B01D2251/508 , C04B7/367 , F23L7/007 , Y02C10/04 , Y02E20/326 , Y02E20/344 , Y02P40/18
摘要： A system for carbon capture includes an oxy-fuel combustor for combusting a hydrocarbon with pure oxygen to produce heat energy and carbon dioxide, a COS converter for converting the carbon dioxide to COS, a transport means for transporting the COS, a sulphur recovery unit for recovering sulphur from the COS and an adjunct sulphur-burning power plant for combusting the sulphur to generate energy for powering one or more carbon capture and storage processes.
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公开(公告)号：US20100242478A1
公开(公告)日：2010-09-30
申请号：US12680099
申请日：2008-07-25
申请人： Bogdan Wojak
发明人： Bogdan Wojak
CPC分类号： C01B17/54 , C01B17/0473 , C01B17/74 , F02C6/10 , F02C6/18 , Y02A50/2327 , Y02A50/2328 , Y02E20/12 , Y02P20/129 , Y02P20/13 , Y02P20/131 , Y10T137/0318
摘要： A method for generating energy from sulphur combustion without causing harmful emissions to the environment entails steps of evaporating liquid sulphur to generate sulphur dioxide gas and sulphur vapor, combusting the sulphur vapor with oxygen gas to generate heat, and reducing (either at high temperature or catalytically) the sulphur dioxide to carbon dioxide and sulphur vapor by reacting the sulphur dioxide with carbonyl sulfide. The carbonyl sulphide can be generated by reacting hydrogen sulfide with recycled carbon dioxide that is recycled by condensing sulphur vapor, carbon dioxide and water to yield liquid sulphur, elemental sulphur, steam and carbon dioxide. Energy in the hot reactor products (SO2 gas and sulphur vapor S2) and steam can be harnessed using this emission-free process. Likewise, this process can be used to produce elemental sulphur and/or carbon monoxide without polluting the atmosphere. Furthermore, this process can be used for the transshipment by pipeline of sulphur by transporting it as carbonyl sulphide.
摘要翻译： 用于从硫燃烧产生能量而不会对环境产生有害排放的方法需要蒸发液体硫以产生二氧化硫气体和硫蒸气的步骤，用氧气将硫蒸汽燃烧以产生热量，并且在高温或催化下还原 ）通过二氧化硫与硫化羰反应将二氧化硫转化成二氧化碳和硫蒸气。 羰基硫化物可以通过使硫化氢与再循环的二氧化碳反应生成，再循环的二氧化碳通过冷凝硫蒸汽，二氧化碳和水再循环，得到液体硫，元素硫，蒸汽和二氧化碳。 使用这种无排放工艺可以利用热反应堆产品（SO2气体和硫蒸气S2）和蒸汽的能源。 同样，该方法可用于生产元素硫和/或一氧化碳，而不会污染大气。 此外，该方法可用于通过将其作为羰基硫化物运输将硫酸盐管道转运。
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4.发明授权Gas turbine topping device in a system for manufacturing sulfuric acid and method of using turbine to recover energy in manufacture of sulfuric acid 有权用于制造硫酸的系统中的燃气轮机顶部装置以及使用涡轮在硫酸制造中回收能量的方法公开(公告)号：US07543438B2
公开(公告)日：2009-06-09
申请号：US12237470
申请日：2008-09-25
申请人： Bogdan Wojak
发明人： Bogdan Wojak
CPC分类号： C01B17/54 , C01B17/0473 , C01B17/74 , F02C6/10 , F02C6/18 , Y02A50/2327 , Y02A50/2328 , Y02E20/12 , Y02P20/129 , Y02P20/13 , Y02P20/131 , Y10T137/0318
摘要： A gas turbine topping device, which is disposed upstream of a steam-raising section, is used for generating power in the manufacture of sulphuric acid. A sulfur-burning combustor generates hot sulfur dioxide while a pressure-exchanging ejector mixes the hot combustion gases with a cooler gas (e.g. pressurized air, pressurized N2 or recycled sulfur dioxide (SO2) to form a mixed working gas having a temperature below the maximum allowable temperature (metallurgical limit) of the blades of the turbine. The turbine drives an oxygen compressor which supplies oxygen to a bubbling chamber which also receives S8 to produce sulfur vapor for combustion. By using stoichiometric quantities, sulfur dioxide is delivered in requisite quantities to a sulfuric acid plant without any harmful emissions. Useful amounts of electrical power can thus be generated by the gas turbine topping device as well as the downstream steam turbine by harnessing the enormous amount of waste heat involved in the manufacture of sulfuric acid.
摘要翻译： 设置在蒸汽提升部分的上游的燃气轮机顶部装置用于在硫酸的制造中产生动力。 硫燃烧的燃烧器产生热二氧化硫，而压力交换喷射器将热燃烧气体与较冷气体（例如加压空气，加压的N 2或再循环的二氧化硫（SO 2））混合，形成温度低于最大值的混合工作气体 涡轮机驱动氧气压缩机，该氧气压缩机将氧气供应到也接收S8以产生硫蒸汽用于燃烧的发泡室，通过使用化学计量的量将二氧化硫以必需的量输送到 一个没有任何有害排放物的硫酸设备，因此可以通过燃气轮机顶部装置以及下游的蒸汽轮机，通过利用大量的硫酸制造所涉及的废热产生有用的电力。
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公开(公告)号：US09802153B2
公开(公告)日：2017-10-31
申请号：US15174504
申请日：2016-06-06
申请人： Bogdan Wojak
发明人： Bogdan Wojak
IPC分类号： C25B1/22 , C25B1/02 , C25B9/08 , B01D53/62 , B01D53/86 , C01C1/04 , C10G2/00 , C07C1/12 , C07C29/151 , C25B1/04
CPC分类号： B01D53/62 , B01D53/8681 , B01D2251/508 , B01D2258/0283 , C01C1/04 , C07C1/12 , C07C29/151 , C07C29/1516 , C07C273/04 , C10G2/50 , C25B1/02 , C25B1/04 , C25B1/22 , C25B9/08 , Y02E60/366 , C07C31/04
摘要： Disclosed herein is a system and method for sulphur-assisted carbon capture and utilization. The system includes a sulphur depolarized electrolyser (SDE) for receiving electricity, H2O and SO2 and for electrolysing the H2O and SO2 to produce hydrogen and sulphuric acid (H2SO4), a decomposition reactor for receiving and decomposing the H2SO4 into SO3 and H2O, wherein the H2O is recycled to the SDE, a sulphur submerged combustor for converting the SO3 to SO2 and producing Sn vapor, a sulphur power plant for combusting Sn vapor to produce SO2, electricity and heat and for supplying the SO2 and the electricity to the SDE and for supplying the heat to the decomposition reactor. The hydrogen is delivered to a carbon capture and utilization facility. An optional Flue Gas Desulphurisation (FGD) regenerable system removes SO2 from flue gas, a CO2 converter generates COS, and a separator separates the COS from the flue gas.
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公开(公告)号：US20170252696A1
公开(公告)日：2017-09-07
申请号：US15174504
申请日：2016-06-06
申请人： Bogdan Wojak
发明人： Bogdan Wojak
CPC分类号： B01D53/62 , B01D53/8681 , B01D2251/508 , B01D2258/0283 , C01C1/04 , C07C1/12 , C07C29/151 , C07C29/1516 , C07C273/04 , C10G2/50 , C25B1/02 , C25B1/04 , C25B1/22 , C25B9/08 , Y02E60/366 , C07C31/04
摘要： Disclosed herein is a system and method for sulphur-assisted carbon capture and utilization. The system includes a sulphur depolarized electrolyser (SDE) for receiving electricity, H2O and SO2 and for electrolysing the H2O and SO2 to produce hydrogen and sulphuric acid (H2SO4), a decomposition reactor for receiving and decomposing the H2SO4 into SO3 and H2O, wherein the H2O is recycled to the SDE, a sulphur submerged combustor for converting the SO3 to SO2 and producing Sn vapor, a sulphur power plant for combusting Sn vapor to produce SO2, electricity and heat and for supplying the SO2 and the electricity to the SDE and for supplying the heat to the decomposition reactor. The hydrogen is delivered to a carbon capture and utilization facility. An optional Flue Gas Desulphurisation (FGD) regenerable system removes SO2 from flue gas, a CO2 converter generates COS, and a separator separates the COS from the flue gas.
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公开(公告)号：US09709268B2
公开(公告)日：2017-07-18
申请号：US14762846
申请日：2013-04-15
申请人： Bogdan Wojak
发明人： Bogdan Wojak
摘要： A system for carbon capture includes an oxy-fuel combustor for combusting a hydrocarbon with pure oxygen to produce heat energy and carbon dioxide, a COS converter for converting the carbon dioxide to COS, a transport means for transporting the COS, a sulphur recovery unit for recovering sulphur from the COS and an adjunct sulphur-burning power plant for combusting the sulphur to generate energy for powering one or more carbon capture and storage processes.
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公开(公告)号：US20090235669A1
公开(公告)日：2009-09-24
申请号：US12442046
申请日：2007-09-19
申请人： Bogdan Wojak
发明人： Bogdan Wojak
CPC分类号： C01B17/54 , C01B17/76 , F02C3/30 , F02C3/32 , Y02P20/129
摘要： A method of generating electrical power using sulfur, the method having the steps of combusting oxygen with a stoichiometric quantity of sulfur comprising predominantly diatomic sulfur to generate hot sulfur dioxide gas; and mixing a cooling gas substantially cooler than the hot sulfur dioxide gas with the hot sulfur dioxide gas to produce a mixed working gas for driving a gas turbine, the mixed working gas having a temperature less than a maximum allowable temperature determined by a metallurgic limit of turbine blades in the gas turbine, whereby the gas turbine generates electrical power.
摘要翻译： 一种使用硫产生电力的方法，所述方法具有以主要为双原子硫的化学计量的硫燃烧氧气以产生热的二氧化硫气体的步骤; 将与所述热二氧化硫气体基本上比所述热二氧化硫气体更冷的冷却气体与所述热二氧化硫气体混合，以产生用于驱动燃气轮机的混合工作气体，所述混合工作气体的温度小于由冶金极限 燃气轮机中的涡轮机叶片，由此燃气轮机产生电力。
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