Thermoplastic polyolefins with high flowability and excellent surface quality produced by a multistage process

    公开(公告)号:US10253171B2

    公开(公告)日:2019-04-09

    申请号:US14057818

    申请日:2013-10-18

    Applicant: Borealis AG

    Abstract: Reactor grade thermoplastic polyolefins with high flowability and excellent surface quality comprising (A) 40-90 wt % of a propylene homo- or copolymer matrix with an MFR in accordance with ISO 1 133 (230° C., 2.16 kg load) of ≥200 g/10 min and (B) 2-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of ≤2.8 dl/g and an ethylene content of >50 to 80 wt % and (C) 8-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of 3.0-6.5 dl/g and an propylene content of 50 to 80 wt %, the reactor grade thermoplastic polyolefins being obtainable by a multistage polymerization process with at least 3 polymerization steps in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester and (ii) an organometallic cocatalyst and (iii) external donor represented by formula (I) Si(OCH2CH3)3(NR1R2) wherein R1 and R2 can be the same or different a represent a hydrocarbon group having 1 to 12 carbon atoms, as well as the use of these reactor grade thermoplastic polyolefins and molded articles produced from them.

    THERMOPLASTIC POLYOLEFINS WITH HIGH FLOWABILITY AND EXCELLENT SURFACE QUALITY PRODUCED BY A MULTISTAGE PROCESS
    4.
    发明申请
    THERMOPLASTIC POLYOLEFINS WITH HIGH FLOWABILITY AND EXCELLENT SURFACE QUALITY PRODUCED BY A MULTISTAGE PROCESS 审中-公开
    具有高流动性和优异表面质量的热塑性聚烯烃由多种工艺生产

    公开(公告)号:US20140045994A1

    公开(公告)日:2014-02-13

    申请号:US14057818

    申请日:2013-10-18

    Applicant: Borealis AG

    Abstract: Reactor grade thermoplastic polyolefins with high flowability and excellent surface quality comprising (A) 40-90 wt % of a propylene homo- or copolymer matrix with an MFR in accordance with ISO 1 133 (230° C., 2.16 kg load) of ≧200 g/10 min and (B) 2-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of ≦2.8 dl/g and an ethylene content of >50 to 80 wt % and (C) 8-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of 3.0-6.5 dl/g and an propylene content of 50 to 80 wt %, the reactor grade thermoplastic polyolefins being obtainable by a multistage polymerization process with at least 3 polymerization steps in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester and (ii) an organometallic cocatalyst and (iii) external donor represented by formula (I) Si(OCH2CH3)3(NR1R2) wherein R1 and R2 can be the same or different a represent a hydro-carbon group having 1 to 12 carbon atoms, as well as the use of these reactor grade thermoplastic polyolefins and molded articles produced from them.

    Abstract translation: 具有高流动性和优异表面质量的反应器级热塑性聚烯烃,其包含(A)40-90重量%的丙烯均聚物或共聚物基体,其具有符合ISO 1 133(230℃,2.16kg负荷)的MFR = 200g / 10分钟,和(B)2-30重量%的特性粘度IV(根据ISO 1628和十氢化萘作为溶剂)的弹性体乙烯 - 丙烯共聚物为2.8dl / g,乙烯含量> 50〜 80重量%和(C)8-30重量%的具有3.0-6.5dl / g的特性粘度IV(根据ISO 1628和十氢化萘作为溶剂)的弹性体乙烯 - 丙烯共聚物,丙烯含量为50-80重量% %,反应器级热塑性聚烯烃可以通过多级聚合方法获得,在催化剂体系存在下至少具有3个聚合步骤,包括(i)齐格勒 - 纳塔前催化剂,其含有低级醇和邻苯二甲酸的酯交换反应产物 酯和(ii)有机金属助催化剂和(iii) 由式(I)Si(OCH 2 CH 3)3(NR 1 R 2)表示的外部供体,其中R 1和R 2可以相同或不同,a表示具有1至12个碳原子的烃基,以及这些反应器级热塑性塑料 聚烯烃和由它们生产的模塑制品。

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