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公开(公告)号:US20210292355A1
公开(公告)日:2021-09-23
申请号:US17253770
申请日:2019-06-28
Applicant: BOREALIS AG
Inventor: Noureddine AJELLAL , Ville VIRKKUNEN , Luigi Maria Cristoforo RESCONI , Vyatcheslav V. IZMER , Dmitry S. KONONOVICH , Alexander Z. VOSKOBOYNIKOV , Jingbo WANG , Simon SCHWARZENBERGER , Wilfried Peter TÖLTSCH
IPC: C07F17/00 , C08F110/06 , C08F4/659
Abstract: A complex of formula (I): (I′) M is Hf; each X is a sigma ligand; L is a bridge of formula -(ER82)y—; y is 1 or 2; E is C or Si; each R8 is independently a C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20- aryl, C7-C20-arylalkyl or C7-C20-alkylaryl or L is an alkylene group such as methylene or ethylene; Ar and Ar′ are each independently an aryl or heteroaryl group optionally substituted by 1 to 3 groups R1 or R1′ respectively; R1 and R1′ are each independently the same or can be different and are a linear or branched C1-C6-alkyl group, C7-20 arylalkyl, C7-20 alkylaryl group or C6-20 aryl group with the proviso that if there are four or more R1 and R1′ groups present in total, one or more of R1 and R1′ is other than tert butyl; R2 and R2′ are the same or are different and are a CH2—R9 group, with R9 being H or linear or branched C1-C6-alkyl group, C3-8 cycloalkyl group, C6-10 aryl group; each R is a —CH2—, —CHRx- or C(Rx)2-group wherein Rx is C1-4 alkyl and where m is 2-6; R5 is a linear or branched C1-C6-alkyl group, C7-20 arylalkyl, C7-20 alkylaryl group or C6-C20-aryl group; R6 is a C(R10)3 group, with R10 being a linear or branched C1-C6 alkyl group; and R6 and R7′ are the same or are different and are H or a linear or branched C1-C6-alkyl group. Invention relates also to a catalyst in solid form comprising (i) a complex of formula (I) and (ii) a cocatalyst of an aluminium compound and (iii) a cocatalyst of a boron compound.
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公开(公告)号:US20220363703A1
公开(公告)日:2022-11-17
申请号:US16475269
申请日:2017-12-21
Applicant: BOREALIS AG
Inventor: Wilfried TOELTSCH , Simon SCHWARZENBERGER , Ismo LEHTINIEMI , Luigi RESCONI , Ville VIRKKUNEN , Noureddine AJELLAL , Vyatcheslav V. IZMER , Dmitry S. KONONOVICH , Alexander Z. VOSKOBOYNIKOV
IPC: C07F17/00 , C08F10/06 , C08F210/16 , C08F4/659 , C08F4/6592
Abstract: Claimed are metallocene-complexes of formula (I) [formula (I′)] wherein M is Hf or Zr, L is a bridge comprising 1-2 C- or Si-atoms, The other variables are as defined in the claims.
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3.
公开(公告)号:US20160200838A1
公开(公告)日:2016-07-14
申请号:US14914501
申请日:2014-10-22
Applicant: BOREALIS AG
Inventor: Alexander REZNICHENKO , Noureddine AJELLAL , Pascal CASTRO , Irfan SAEED
IPC: C08F4/6592
CPC classification number: C08F10/00 , C08F4/649 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F2410/01 , C08F10/06 , C08F110/06 , C08F2500/12 , C08F210/16 , C08F210/14 , C08F110/02 , C08F2500/01
Abstract: Process for the preparation of a solid catalyst system comprising the steps of preparing a liquid clathrate comprising a mixing of an aluminoxane, an aromatic compound and an organo-silicon compound, wherein the mol-ratio between the organo-silicon compound and aluminum of the aluminoxane is below 0.1, mixing said liquid clathrate with an organometallic compound obtaining a liquid mixture, and precipitating the solid catalyst system out of said liquid mixture by adding a saturated aliphatic compound to said mixture liquid.
Abstract translation: 制备固体催化剂体系的方法,包括以下步骤:制备包含铝氧烷,芳族化合物和有机硅化合物的混合物的液体包合物,其中有机硅化合物与铝氧烷铝的摩尔比 将所述液体包合物与有机金属化合物混合,得到液体混合物,并通过向所述混合液中加入饱和脂肪族化合物将所述固体催化剂体系从所述液体混合物中沉淀出来。
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4.
公开(公告)号:US20200079887A1
公开(公告)日:2020-03-12
申请号:US16469617
申请日:2017-12-12
Applicant: BOREALIS AG
Inventor: Noureddine AJELLAL , Anna FAIT , Luigi RESCONI
IPC: C08F210/16
Abstract: Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising (i) a metallocene complex of formula (I) wherein: M is Hf or a mixture with Zr, provided that more than 50% by moles of the complex of Formula (I) has M=Hf; X is a sigma ligand; R are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C6-C10 aryl, C4-C10 heteroaryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms or silicon atoms; R1 is a C6-C10 aryl or C6-C20 alkylaryl group optionally containing up to 2 heteroatoms or silicon atoms or a C4-C10 heteroaryl group; R2 is a C4-C20 cycloalkyl group, optionally carrying alkyl substituents in beta-positions, of formula (II) in which R′ can be the same or can be different from each other and can be hydrogen or is defined as R and n is 1 to 17 (ii) a boron containing cocatalyst
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5.
公开(公告)号:US20200079884A1
公开(公告)日:2020-03-12
申请号:US16469616
申请日:2017-12-12
Applicant: BOREALIS AG
Inventor: Noureddine AJELLAL , Anna FAIT , Luigi RESCONI , Vyatcheslav V. IZMER , Dmitry S. KONONOVICH , Alexander Z. VOSKOBOYNIKOV , Rafael SABLONG , Timo SCIARONE
IPC: C08F4/6592 , C08F210/16 , C08F2/06
Abstract: Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising (i) a metallocene complex of formula (I), M is Hf or a mixture with Zr, provided that more than 50% by moles of the complex of Formula I has M=Hf, X is a sigma ligand, R are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C5-C10 aryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms or silicon atoms, R1 is a C6-C20-aryl, which can be unsubstituted or substituted by one or up to 5 linear or branched C1-C10 alkyl group(s), R2 is a saturated linear or cyclic C3-C20 alkyl group or a branched CR3R4R5 group, wherein R3 is hydrogen or an C1-C20 alkyl group and R4 and R5 are the same or are different and can be an C1-C20 alkyl group and (ii) a boron containing cocatalyst
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公开(公告)号:US20190308995A1
公开(公告)日:2019-10-10
申请号:US16461517
申请日:2017-11-17
Applicant: BOREALIS AG
Inventor: Noureddine AJELLAL , Luigi RESCONI , Vyatcheslav V. IZMER , Dmitry S. KONONOVICH , Alexander Z. VOSKOBOYNIKOV , Ville VIRKKUNEN
IPC: C07F7/08 , C08F10/06 , C08F4/649 , C08F4/6592 , C07C1/20 , C07C41/00 , C07C45/68 , C07C13/32 , C07C49/443
Abstract: A complex of formula (I) wherein M is zirconium or hafnium; each X independently is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom or a C1-C20-hydrocarbyl group optionally containing one or more silicon atoms or heteroatoms of Group 14-16 of the periodic table or fluorine atoms, and optionally two R′ groups taken together can form a ring; R2 and R2′ are each independently a C1-C20 hydrocarbyl group, —OC1-hydrocarbyl group or —SC1-20 hydrocarbyl group; R5 is a —OC1-20 hydrocarbyl group or —SC1-20 hydrocarbyl group, said R5 group being optionally substituted by one or more halo groups; R5′ is hydrogen or a C1-20 hydrocarbyl group; —OC1-20 hydrocarbyl group or —SC1-20 hydrocarbyl group; said C1-20 hydrocarbyl group being optionally substituted by one or more halo groups; R6 and R6′ are each independently a C1-20 hydrocarbyl group; —C1-20 hydrocarbyl group or —SC1-20 hydrocarbyl group; each R1 and R1′ are independently —CH2Rx wherein Rx are each independently H, or a C1-20 hydrocarbyl group, optionally containing heteroatoms.
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公开(公告)号:US20240191052A1
公开(公告)日:2024-06-13
申请号:US18555295
申请日:2022-04-13
Applicant: BOREALIS AG
Inventor: Mohammad AL-HAJ ALI , Noureddine AJELLAL , Mubashar SATTAR , Erno ELOVAINIO , Henry SLEIJSTER
CPC classification number: C08J11/08 , B01D5/0057 , B01D11/028 , C08J2300/30 , C08J2323/02
Abstract: A solvent based recycling process for recycling waste polymer material, the waste polymer material comprising at least one polyolefin, the process comprising the steps of obtaining the waste polymer material comprising the at least one polyolefin; contacting the waste polymer material with at least one dissolving solvent yielding a slurry stream of polymer solution and undissolved solids; screening the slurry stream yielding the undissolved solids and a stream of the polymer solution; vapor-liquid separating the stream of the polymer solution into a polymer-lean vapor stream and a polymer-rich condensed stream; recovering the at least one polyolefin from the polymer-rich condensed stream; wherein the at least one dissolving solvent has a boiling point temperature at 1 bar of equal to or more than 70° C.
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公开(公告)号:US20210179744A1
公开(公告)日:2021-06-17
申请号:US16771307
申请日:2018-12-19
Applicant: BOREALIS AG
Inventor: Alexander REZNICHENKO , Noureddine AJELLAL , Joseph THORMAN , Bernard BINKS
IPC: C08F4/6592 , C08F4/659 , C08F10/02 , C08F10/06 , C07F7/00
Abstract: A process for the preparation of a solid olefin polymerisation catalyst or a solid olefin polymerisation catalyst component comprising the steps of: (a) forming a liquid/liquid emulsion of (i) a first organic liquid comprising at least one olefin polymerization catalyst component and (ii) an optionally halogenated hydrocarbon liquid immiscible therewith; where the first organic liquid forms the dispersed phase and the optionally halogenated hydrocarbon liquid forms the continuous phase of the liquid/liquid emulsion and wherein the dispersed phase forms droplets in the continuous phase; and (b)transforming the droplets of the dispersed phase to solid particulate particles comprising said at least one olefin polymerization catalyst component, wherein the liquid/liquid emulsion is stabilized with a solid particulate stabilizer
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公开(公告)号:US20210108006A1
公开(公告)日:2021-04-15
申请号:US16499509
申请日:2018-03-28
Applicant: BOREALIS AG
Inventor: Anna FAIT , Noureddine AJELLAL , Luigi Maria Cristoforo RESCONI , Vyatcheslav V. IZMER , Dmitry S. KONONOVICH , Oleg SAMSONOV , Alexander Z. VOSKOBOYNIKOV , Rafael SABLONG , Timo SCIARONE
IPC: C08F4/6592 , C08F210/16 , C08F4/659
Abstract: Catalyst system, the catalyst system comprising (i) at least one metallocene complex of formula (I), (I) wherein Mt1 is Hf, X is a sigma-donor ligand, R1, R2, R3 are the same or different from each other and can be hydrogen or a saturated linear or branched C1-C10 alkyl, whereby the alkyl group can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, or R1 and R2 or R2 and R3 can form a ring having 4 to 6 C-atoms and 1 to 3 double bonds, R4 and R5 are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C5-C10 aryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, n can be 1 to 5, Ar is a C6-C20-aryl or -heteroarylgroup, which can be unsubstituted or substituted by 1 to 5 linear or branched C1-C10 alkyl group(s), and (ii) a boron containing cocatalyst.
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公开(公告)号:US20210095057A1
公开(公告)日:2021-04-01
申请号:US16499514
申请日:2018-03-28
Applicant: BOREALIS AG
Inventor: Luigi Maria Cristoforo RESCONI , Noureddine AJELLAL , Anna FAIT , Irfan SAEED , Maria RANIERI , David QUIN , Vyatcheslav V. IZMER , Dmitry S. KONONOVICH , Oleg SAMSONOV , Alexander Z. VOSKOBOYNIKOV
IPC: C08F4/6592 , C08F4/642 , C08F210/16
Abstract: Catalyst system, the catalyst system comprising (i) at least one metallocene complex of formula (I) wherein Mt1 is Hf, X is a sigma-donor ligand, R1, R2, R3 are the same or different from each other and can be hydrogen or a saturated linear or branched C1-C10 alkyl, whereby the alkyl group can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, or R1 and R2 or R2 and R3 can form a ring having 4 to 6 C-atoms and 1 to 3 double bonds, R4 and R5 are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C5-C10 aryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, n can be 1 to 5, Ar is a C6-C20-aryl or -heteroaryl group, which can be unsubstituted or substituted by 1 to 5 linear or branched C1-C10 alkyl group(s), and (ii) an aluminoxane cocatalyst and (iii) optionally an aluminium alkyl compound AI(R7)3, with R7 being a linear or branched C2-C8-alkyl group.
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