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公开(公告)号:US20210079128A1
公开(公告)日:2021-03-18
申请号:US16771306
申请日:2018-12-20
Applicant: BOREALIS AG
Inventor: Alexander REZNICHENKO , Jari-Jussi RUSKEENIEMI , Joseph THORMAN , Xiao Dong CHEN , Victor SUMERIN
IPC: C08F4/651 , C08F210/16 , B01J4/00 , C08F4/654
Abstract: The present invention relates to a process for producing of solid particulate olefin polymerisation catalyst or catalyst carrier comprising forming a solution of the catalyst or a catalyst carrier in a solvent, subjecting the solution into an atomization by spraying the solution via a capillary vibrating spray nozzle with a capillary orifice having a diameter of 5 to 100 μm generating a laminar jet of liquid, which disintegrates into liquid droplets entering into the spray-dryer, transforming the droplets with aid of a gas to solid particulate catalyst or carrier in the spray-dryer and recovering the solid particulate olefin polymerisation catalyst or carrier having particle size distribution defined by a volumetric SPAN of 0.7 or less. The invention further relates to the catalyst produced by the methods, and use thereof in olefin polymerisation process.
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公开(公告)号:US20210179744A1
公开(公告)日:2021-06-17
申请号:US16771307
申请日:2018-12-19
Applicant: BOREALIS AG
Inventor: Alexander REZNICHENKO , Noureddine AJELLAL , Joseph THORMAN , Bernard BINKS
IPC: C08F4/6592 , C08F4/659 , C08F10/02 , C08F10/06 , C07F7/00
Abstract: A process for the preparation of a solid olefin polymerisation catalyst or a solid olefin polymerisation catalyst component comprising the steps of: (a) forming a liquid/liquid emulsion of (i) a first organic liquid comprising at least one olefin polymerization catalyst component and (ii) an optionally halogenated hydrocarbon liquid immiscible therewith; where the first organic liquid forms the dispersed phase and the optionally halogenated hydrocarbon liquid forms the continuous phase of the liquid/liquid emulsion and wherein the dispersed phase forms droplets in the continuous phase; and (b)transforming the droplets of the dispersed phase to solid particulate particles comprising said at least one olefin polymerization catalyst component, wherein the liquid/liquid emulsion is stabilized with a solid particulate stabilizer
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公开(公告)号:US20210147660A1
公开(公告)日:2021-05-20
申请号:US17056855
申请日:2019-05-30
Applicant: BOREALIS AG
Inventor: Anh Tuan TRAN , Alexandra Romina ALBUNIA , Joy Jie CHENG , Joseph THORMAN , John JAMIESON , Ravindra TUPE
IPC: C08L23/06 , C08F210/02 , C08F210/08 , C08F2/00 , C08F2/34 , B29C45/00 , B29C43/00
Abstract: The invention provides a process for the preparation of a multimodal high density polyethylene (HDPE) having a melt flow rate (MFR2) of 0.1 to 4.0 g/10 min, said process comprising: (i) polymerising ethylene in a first polymerisation stage in the presence of a Ziegler-Natta catalyst to prepare a first ethylene homopolymer having a MFR2 from 10 to 500 g/10 min; (ii) polymerising ethylene in a second polymerisation stage in the presence of said catalyst and said first ethylene homopolymer to prepare an ethylene homopolymer mixture comprising said first ethylene homopolymer and a second ethylene homopolymer, said mixture having a MFR2 from 50 to 1000 g/10 min; and (iii) polymerising ethylene and at least one alpha-olefin comonomer in a third polymerisation stage in the presence of said catalyst and said ethylene homopolymer mixture to prepare said multimodal HDPE.
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公开(公告)号:US20190292284A1
公开(公告)日:2019-09-26
申请号:US16438690
申请日:2019-06-12
Applicant: BOREALIS AG
Inventor: Victor SUMERIN , Joseph THORMAN , Jani AHO , Markku VAHTERI , Ravindra TUPE , Jarmo KELA
IPC: C08F210/16 , C08L23/16
Abstract: The present invention relates to a process for producing ethylene copolymers in a multistage process comprising at least one slurry phase polymerization stage and at least one gas phase polymerization stage in the presence of Ziegler Natta catalyst comprising a solid catalyst component, a cocatalyst of a compound of group 13 metal and an external additive selected from alkoxysilanes of formula (1) R1nSi(OR2)4-n, (I) where n is an integer 0 to 3, each R1 are equal or different and are selected among H, halogen, alkyl groups of 1 to 6 10 carbon atoms optionally substituted with one or more halogen atoms, alkenyl groups of 2 to 6 carbon atoms optionally substituted with one or more halogen atoms, and aryl groups of 6 to 12 carbon atoms optionally substituted with one or more halogen atoms, or the R1 groups can form with the Si atom they are linked to a ring of 3 to 8 ring atoms, provided that all R1 are not hydrogen, R2 are equal or different and are selected among alkyl groups of 1 to 6 carbon atoms optionally substituted with one or more halogen atoms, alkenyl groups of 2 to 6 carbon atoms optionally substituted with one or more halogen atoms, and aryl groups of 6 to 12 carbon atoms optionally substituted with one or more halogen atoms, or the OR2 groups can form with the Si atom they are linked to a ring of 3 to 8 ring atoms, halogen is Br, Cl or F. The invention further relates to the catalysts and use thereof in said multistage process r for producing ethylene copolymers having melt flow rate ratio FRR21/5 at least 40 and/or polydispersity index PDI of at least 27.
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公开(公告)号:US20230279159A1
公开(公告)日:2023-09-07
申请号:US18196110
申请日:2023-05-11
Applicant: BOREALIS AG
Inventor: Alexander REZNICHENKO , Jari-Jussi RUSKEENIEMI , Joseph THORMAN , Xiao Dong CHEN , Victor SUMERIN
CPC classification number: C08F4/651 , B01J4/002 , C08F4/6543 , C08F210/16 , C08F4/022 , B01J2/04 , C08F2500/12 , C08F2500/18 , C08F2500/24 , B01D1/18
Abstract: The present invention relates to a process for producing of solid particulate olefin polymerisation catalyst or catalyst carrier comprising forming a solution of the catalyst or a catalyst carrier in a solvent, subjecting the solution into an atomization by spraying the solution via a capillary vibrating spray nozzle with a capillary orifice having a diameter of 5 to 100 μm generating a laminar jet of liquid, which disintegrates into liquid droplets entering into the spray-dryer, transforming the droplets with aid of a gas to solid particulate catalyst or carrier in the spray-dryer and recovering the solid particulate olefin polymerisation catalyst or carrier having particle size distribution defined by a volumetric SPAN of 0.7 or less. The invention further relates to the catalyst produced by the methods, and use thereof in olefin polymerisation process.
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6.
公开(公告)号:US20160369091A1
公开(公告)日:2016-12-22
申请号:US14901948
申请日:2014-09-24
Applicant: BOREALIS AG
Inventor: Thomas HJERTBERG , Ravindra TUPE , Undo WAHNER , Tanja Piel , Yi LIU , Romina Alexandra ALBUNIA , Floran PRADES , Joseph THORMAN , Dusan JEREMIC
IPC: C08L23/08
CPC classification number: C08L23/0815 , C08F2/001 , C08L2205/02 , C08L2205/03 , C08F210/16 , C08F210/14 , C08F2500/07 , C08F2500/12
Abstract: A process for polymerizing ethylene in the presence of a polymerization catalyst by copolymerizing ethylene with a comonomer selected from the group of C4-C10 alpha-olefins in three polymerization stages. The polymers produced in the three stages have different melt flow rates. The polymer composition produced by the process has good mechanical properties and can be used for making pipes. The process has a good productivity and provides a stable and economic operation.
Abstract translation: 在聚合催化剂存在下,通过在三个聚合阶段使乙烯与选自C 4 -C 10α-烯烃的共聚单体共聚来制备乙烯的方法。 在三个阶段中生产的聚合物具有不同的熔体流动速率。 该方法生产的聚合物组合物具有良好的机械性能,可用于制造管材。 该过程具有良好的生产力,并提供稳定和经济的运作。
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公开(公告)号:US20180030179A1
公开(公告)日:2018-02-01
申请号:US15548882
申请日:2016-02-04
Applicant: BOREALIS AG
Inventor: Victor SUMERIN , Joseph THORMAN , Jani AHO , Markku VAHTERI , Ravindra TUPE , Jarmo KELA
IPC: C08F210/16
CPC classification number: C08F210/16 , C08L23/16 , C08F4/6465 , C08F2/001 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/07 , C08F4/6492 , C08F4/6555
Abstract: The present invention relates to a process for producing ethylene copolymers in a multistage process comprising at least one slurry phase polymerization stage and at least one gas phase polymerization stage in the presence of Ziegler Natta catalyst comprising a solid catalyst component, a cocatalyst of a compound of group 13 metal and an external additive selected from alkoxysilanes of formula (I) R1nSi(OR2)4-n, (I) where n is an integer 0 to 3, each R1 are equal or different and are selected among H, halogen, alkyl groups of 1 to 6 10 carbon atoms optionally substituted with one or more halogen atoms, alkenyl groups of 2 to 6 carbon atoms optionally substituted with one or more halogen atoms, and aryl groups of 6 to 12 carbon atoms optionally substituted with one or more halogen atoms, or the R1 groups can form with the Si atom they are linked to a ring of 3 to 8 ring atoms, provided that all R1 are not hydrogen, R2 are equal or different and are selected among alkyl groups of 1 to 6 carbon atoms optionally substituted with one or more halogen atoms, alkenyl groups of 2 to 6 carbon atoms optionally substituted with one or more halogen atoms, and aryl groups of 6 to 12 carbon atoms optionally substituted with one or more halogen atoms, or the OR2 groups can form with the Si atom they are linked to a ring of 3 to 8 ring atoms, halogen is Br, Cl or F. The invention further relates to the catalysts and use thereof in said multistage process r for producing ethylene copolymers having melt flow rate ratio FRR21/5 at least 40 and/or polydispersity index PDI of at least 27.
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公开(公告)号:US20170349683A1
公开(公告)日:2017-12-07
申请号:US15536919
申请日:2015-12-17
Applicant: Borealis AG
Inventor: Victor SUMERIN , Joseph THORMAN
IPC: C08F210/16
CPC classification number: C08F210/16 , C08F210/08 , C08F2500/03 , C08F4/651
Abstract: This invention relates to a solid MgCl2 based Natta catalyst component for producing olefin polymers and preparation of said catalyst component. Further the invention relates to a Ziegler Natta catalyst comprising said solid catalyst component, Group 13 metal compound as cocatalyst and optionally external additives. The invention further relates to the use of said catalyst component in producing olefin polymers, especially ethylene polymers with desired properties.
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