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公开(公告)号:US5422187A
公开(公告)日:1995-06-06
申请号:US136965
申请日:1993-10-14
申请人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
发明人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
CPC分类号: B32B27/18 , B65D81/267 , C23F11/02 , Y10T428/12007 , Y10T428/24917 , Y10T428/298 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998 , Y10T428/31692
摘要: A vapor phase corrosion inhibitor-desiccant composite comprising silica gel granules coated with a vapor phase corrosion inhibitor component. The corrosion inhibitor component is selected from a formulation comprising anhydrous molybdates such as ammonium dimolybdate, sodium molybdate and amine molybdates mixed with benzotriazole and sodium nitrate, or from a formulation comprising amine benzoates, amine nitrates and benzotriazole. The composites can be impregnated into foam, extruded with polyolefin films which can additionally be laminated with metallized second film, or encapsulated in an air-permeable container. The corrosion inhibitor formulations have vapor pressures which provide ongoing corrosion protection for susceptible articles situated favorably with respect to the composite.
摘要翻译: 包含涂有气相腐蚀抑制剂组分的硅胶颗粒的气相腐蚀抑制剂 - 干燥剂复合材料。 腐蚀抑制剂组分选自包含无水钼酸盐如二钼酸铵,钼酸钠和与苯并三唑和硝酸钠混合的胺钼酸盐或由苯甲酸胺,硝酸铈和苯并三唑混合的制剂的制剂。 复合材料可以浸渍到泡沫中,用聚烯烃膜挤出,其可以另外与金属化的第二膜层压,或者封装在透气容器中。 腐蚀抑制剂配方具有蒸气压力,其为相对于复合材料有利地定位的易感制品提供持续的防腐蚀保护。
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公开(公告)号:US5393457A
公开(公告)日:1995-02-28
申请号:US136959
申请日:1993-10-14
申请人: Boris A. Miksic , Tsi-Zong Tzou , Joseph M. Foley
发明人: Boris A. Miksic , Tsi-Zong Tzou , Joseph M. Foley
CPC分类号: B32B27/18 , B65D81/267 , C23F11/02 , Y10T428/12007 , Y10T428/24917 , Y10T428/298 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998 , Y10T428/31692
摘要: A vapor phase corrosion inhibitor-desiccant composite comprising silica gel granules coated with a vapor phase corrosion inhibitor component. The corrosion inhibitor component is selected from a formulation comprising anhydrous molybdates such as ammonium dimolybdate, sodium molybdate and amine molybdates mixed with benzotriazole and sodium nitrate, or from a formulation comprising amine benzoates, amine nitrates and benzotriazole. The composites can be impregnated into foam, extruded with polyolefin films which can additionally be laminated with metallized second film, or encapsulated in an air-permeable container. The corrosion inhibitor formulations have vapor pressures which provide ongoing corrosion protection for susceptible articles situated favorably with respect to the composite.
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公开(公告)号:US5320778A
公开(公告)日:1994-06-14
申请号:US136980
申请日:1993-10-14
申请人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
发明人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
CPC分类号: B32B27/18 , B65D81/267 , C23F11/02 , Y10T428/298 , Y10T428/2982 , Y10T428/31692
摘要: A vapor phase corrosion inhibitor-desiccant composite comprising silica gel granules coated with a vapor phase corrosion inhibitor component. The corrosion inhibitor component is selected from a formulation comprising anhydrous molybdates such as ammonium dimolybdate, sodium molybdate and amine molybdates mixed with benzotriazole and sodium nitrate, or from a formulation comprising amine benzoates, amine nitrates and benzotriazole. The composites can be impregnated into foam, extruded with polyolefin films which can additionally be laminated with metallized second film, or encapsulated in an air-permeable container. The corrosion inhibitor formulations have vapor pressures which provide ongoing corrosion protection for susceptible articles situated favorably with respect to the composite.
摘要翻译: 包含涂有气相腐蚀抑制剂组分的硅胶颗粒的气相腐蚀抑制剂 - 干燥剂复合材料。 腐蚀抑制剂组分选自包含无水钼酸盐如二钼酸铵,钼酸钠和与苯并三唑和硝酸钠混合的胺钼酸盐或由苯甲酸胺,硝酸铈和苯并三唑混合的制剂的制剂。 复合材料可以浸渍到泡沫中,用聚烯烃膜挤出,其可以另外与金属化的第二膜层压,或者封装在透气容器中。 腐蚀抑制剂配方具有蒸气压力,其为相对于复合材料有利地定位的易感制品提供持续的防腐蚀保护。
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公开(公告)号:US5344589A
公开(公告)日:1994-09-06
申请号:US136968
申请日:1993-10-14
申请人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
发明人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
CPC分类号: B32B27/18 , B65D81/267 , C23F11/02 , Y10T428/298 , Y10T428/2982 , Y10T428/31692
摘要: A vapor phase corrosion inhibitor-desiccant composite comprising silica gel granules coated with a vapor phase corrosion inhibitor component. The corrosion inhibitor component is selected from a formulation comprising anhydrous molybdates such as ammonium dimolybdate, sodium molybdate and amine molybdates mixed with benzotriazole and sodium nitrate, or from a formulation comprising amine benzoates, amine nitrates and benzotriazole. The composites can be impregnated into foam, extruded with polyolefin films which can additionally be laminated with metallized second film, or encapsulated in an air-permeable container. The corrosion inhibitor formulations have vapor pressures which provide ongoing corrosion protection for susceptible articles situated favorably with respect to the composite.
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公开(公告)号:US5332525A
公开(公告)日:1994-07-26
申请号:US929621
申请日:1992-08-13
申请人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
发明人: Boris A. Miksic , Joseph M. Foley , Tsi-Zong Tzou
CPC分类号: B32B27/18 , B65D81/267 , C23F11/02 , Y10T428/12007 , Y10T428/24917 , Y10T428/298 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998 , Y10T428/31692
摘要: A vapor phase corrosion inhibitor-desiccant composite comprising silica gel granules coated with a vapor phase corrosion inhibitor component. The corrosion inhibitor component is selected from a formulation comprising anhydrous molybdates such as ammonium dimolybdate, sodium molybdate and amine molybdates mixed with benzotriazole and sodium nitrate, or from a formulation comprising amine benzoates, amine nitrates and benzotriazole. The composites can be impregnated into foam, extruded with polyolefin films which can additionally be laminated with metallized second film, or encapsulated in an air-permeable container. The corrosion inhibitor formulations have vapor pressures which provide ongoing corrosion protection for susceptible articles situated favorably with respect to the composite.
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公开(公告)号:US5209869A
公开(公告)日:1993-05-11
申请号:US905953
申请日:1992-06-29
申请人: Boris A. Miksic , Tsi-Zong Tzou , Joseph M. Foley
发明人: Boris A. Miksic , Tsi-Zong Tzou , Joseph M. Foley
摘要: A vapor phase corrosion inhibitor-desiccant formulation comprising silica gel granules coated with a finely divided anhydrous molybdate selected from the group consisting of anhydrous sodium molybdate, anhydrous ammonium dimolybdate, and anhydrous amine molybdates having the structural formula: ##STR1## wherein R.sub.1 is an aliphatic hydrocarbon having up to 7 carbon atoms, and wherein R.sub.2 is either hydrogen or an aliphatic hydrocarbon having up to 7 carbon atoms with these anhydrous molybdates being provided in admixture with sodium nitrite and benzotriazole. The composite formulations of the present invention have been found to be particularly desirable as a vapor phase corrosion inhibitor when in contact with the environs of metals susceptible to corrosion including, for example, iron, aluminum, copper, and alloys such as alloys of iron, copper, and the like. The vapor phase corrosion inhibitors appear to exhibit improved properties when utilized as a powdered coating upon granular silica gel. In a preferred embodiment, the amine-molybdate compounds are those amine-molybdates derived from dicyclohexylamine, 2-ethylhexylamine, and cyclohexylamine. When incorporated as a powdered coating upon silica gel granules, the amine-molybdates have vapor pressures which contribute to enhanced protection against corrosion, as well as a continued or ongoing availability of that protection. When provided in admixture with sodium nitrite and benzotriazole, these composite materials find particular applicability for extrusion with polyolefin films such as polyethylene and polypropylene, and with such films being capable of forming laminates with metallized second film layers.
摘要翻译: 一种气相腐蚀抑制剂 - 干燥剂制剂,其包含用选自无水钼酸钠,无水二钼酸铵和无水胺钼酸盐的细碎无水钼酸盐涂覆的硅胶颗粒,其具有以下结构式:其中R1是脂族 具有至多7个碳原子的烃,其中R2是氢或具有至多7个碳原子的脂族烃,这些无水钼酸盐与亚硝酸钠和苯并三唑的混合物提供。 已经发现本发明的复合制剂作为气相腐蚀抑制剂在与易受腐蚀的金属的环境接触时是特别理想的,包括例如铁,铝,铜以及诸如铁, 铜等。 当用作颗粒状硅胶上的粉末涂料时,气相腐蚀抑制剂似乎表现出改善的性能。 在优选的实施方案中,胺 - 钼酸盐化合物是衍生自二环己基胺,2-乙基己基胺和环己胺的那些胺 - 钼酸盐。 当作为粉末涂料掺入硅胶颗粒时,胺 - 钼酸盐具有有助于增强防腐蚀保护的蒸气压,以及该保护的持续或持续的可用性。 当与亚硝酸钠和苯并三唑的混合物提供时,这些复合材料特别适用于聚烯烃膜如聚乙烯和聚丙烯的挤出,并且这些膜能够形成具有金属化的第二膜层的层压体。
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公开(公告)号:US5855975A
公开(公告)日:1999-01-05
申请号:US491533
申请日:1995-06-16
申请人: Boris A. Miksic , Joseph M. Foley
发明人: Boris A. Miksic , Joseph M. Foley
IPC分类号: B32B5/16 , B29D7/01 , B29K23/00 , B29K105/26 , B29K503/04 , B32B9/00 , B32B27/00 , B32B27/06 , B32B27/18 , B32B27/32 , C08J5/18 , C08J11/06 , C08K3/22 , C08K5/17 , C08K5/20 , C08K5/3472 , C08K5/3475 , C23F11/02
CPC分类号: C08J5/18 , B32B27/06 , B32B27/18 , C08J11/06 , C23F11/02 , B32B2272/00 , C08J2323/00 , Y02W30/701 , Y10S428/91 , Y10T428/1355 , Y10T428/1359 , Y10T428/259 , Y10T428/2993 , Y10T428/31692
摘要: A resinous film at least partially formulated from a recycled resin and containing a vapor phase corrosion inhibitor. One embodiment of the invention is a single layer film which is formulated from three components. The first component is a recycled resin such as polyethylene, the second component is a fresh resin identical to the first, and the third component is a vapor phase anti-corrosion agent. Multi-layer films are also included. The films emit the anti-corrosion agent over a period of time to thereby protect items encased by the film.
摘要翻译: 至少部分地由再循环树脂配制并含有气相腐蚀抑制剂的树脂膜。 本发明的一个实施方案是由三个组分配制的单层膜。 第一组分是再生树脂如聚乙烯,第二组分是与第一组分相同的新鲜树脂,第三组分是气相防腐剂。 还包括多层薄膜。 该膜在一段时间内发射防腐蚀剂,从而保护被膜包裹的物品。
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公开(公告)号:US5894040A
公开(公告)日:1999-04-13
申请号:US654481
申请日:1996-05-30
申请人: Joseph M. Foley , Barry Rudman
发明人: Joseph M. Foley , Barry Rudman
CPC分类号: B32B27/10 , B65D81/267 , C23F11/02 , Y10T428/1303 , Y10T428/1317 , Y10T428/1321 , Y10T428/1345 , Y10T428/1379 , Y10T428/31993
摘要: Pulp prepared from post-consumer used or recycled paper may be employed in the preparation of substrates which are blended with a vapor phase corrosion inhibitor for preparation and fabrication of packaging enclosures or containers. The present invention permits substrates prepared in this fashion to be employed in such applications for which they are rendered highly suitable. Because of the unknown history of the post-consumer recycled materials forming the pulp, the utility of enclosures and/or packages prepared from such pulp is expanded. Vapor phase corrosion inhibitors useful in the present invention preferably include quantities of amine salts, alkali metal molybdates, including ammonium molybdates, or mixtures of molybdates with a second component such as benzotriazole.
摘要翻译: 从消费后使用或再生纸制备的纸浆可用于制备与气相腐蚀抑制剂混合以制备和制造包装外壳或容器的基材。 本发明允许以这种方式制备的基材用于其被赋予非常合适的这种应用中。 由于形成纸浆的消费后回收材料的未知历史,扩大了由这种纸浆制备的外壳和/或包装的实用性。 可用于本发明的气相腐蚀抑制剂优选包括量的胺盐,包括钼酸铵的钼酸金属钼酸盐,或钼酸盐与第二组分如苯并三唑的混合物。
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