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公开(公告)号：US5534657A
公开(公告)日：1996-07-09
申请号：US376176
申请日：1995-01-20
CPC分类号： B01J31/0222 , B01D5/00 , C01B7/191 , C07C2/62 , B01J2231/323 , B01J27/12 , C07C2527/1206
摘要： A novel alkylation catalyst is described which is used in processes for alkylating olefin hydrocarbons with isoparaffin hydrocarbons to produce high octane alkylate products suitable for use as blending components of gasoline motor fuel. The novel catalyst comprises a mixture of a hydrogen halide, a sulfone and water and has suitable corrosion properties which permit its utilization in alkylation process systems. The novel alkylation catalyst is utilized in a novel process for alkylating olefin hydrocarbons with isoparaffin hydrocarbons.
摘要翻译： 描述了一种新的烷基化催化剂，其用于使用异链烷烃烷基化烯烃的方法，以产生适合用作汽油发动机燃料混合组分的高辛烷基烷基化物产物。 新型催化剂包括卤化氢，砜和水的混合物，并且具有合适的腐蚀性质，其允许其在烷基化方法体系中的应用。 新型烷基化催化剂用于使用异链烷烃对烯烃进行烷基化的新方法。
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公开(公告)号：US5347064A
公开(公告)日：1994-09-13
申请号：US45435
申请日：1993-04-12
CPC分类号： C10G50/00 , C07C2/62 , C07C9/16 , C07C2527/1213 , C07C2527/173
摘要： An isoparaffin-olefin alkylation process is disclosed which improves alkylate quality by segregating the olefin feed into intermediate feedstreams which are enriched in propene, 1-butene, and/or 2-butenes with respect to the olefin feed, and alkylating these intermediate feedstreams in separate reaction zones at reaction temperatures specific to the olefin feed to increase the ratio of trimethylpentanes to dimethylhexanes in the resulting alkylate product.
摘要翻译： 公开了一种异链烷烃烯烃烷基化方法，其通过将烯烃进料分离成相对于烯烃进料富含丙烯，1-丁烯和/或2-丁烯的中间进料流，并将这些中间进料流分离 反应区域在烯烃进料特有的反应温度下，以增加所得烷基化产物中三甲基戊烷与二甲基己烷的比例。
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3.发明授权Alkylation process using co-current downflow reactor with a continuous hydrocarbon phase 失效使用具有连续烃相的并流下流反应器的烷基化方法
公开(公告)号：US5345027A
公开(公告)日：1994-09-06
申请号：US933163
申请日：1992-08-21
申请人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Frederick J. Krambeck , Thomas R. Melli , Sergei Yurchak
发明人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Frederick J. Krambeck , Thomas R. Melli , Sergei Yurchak
CPC分类号： C07C2/62 , B01J27/12 , B01J27/16 , C07C2527/1213 , C07C2527/173
摘要： A continuous alkylation process for the production of high octane gasoline comprising contacting a mixture of an isoparaffin and an olefin with a catalyst complex comprising BF3:H.sub.3 PO.sub.4 in a continuous hydrocarbon downflow reactor.
摘要翻译： 包括用于生产高辛烷值汽油的连续烷基化方法，包括使异链烷烃和烯烃的混合物与包含BF 3 :H 3 PO 4的催化剂络合物在连续的烃下流反应器中接触。
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公开(公告)号：US5276243A
公开(公告)日：1994-01-04
申请号：US991922
申请日：1992-12-17
申请人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Anagha A. Gupte , Tomas R. Melli , Sergei Yurchak
发明人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Anagha A. Gupte , Tomas R. Melli , Sergei Yurchak
IPC分类号： C01B7/19 , C07C2/62 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from said mixture to provide an intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) gravitationally separating said intermediate stream into a sulfolane-enriched stream and a conjunct polymer-enriched stream;(c) contacting said sulfolane-enriched stream with a polar extraction solvent to provide an extract stream enriched in sulfolane and a raffinate stream enriched in conjunct polymers;(d) stripping the polar extraction solvent from said sulfolane-enriched extract stream; and(e) recovering sulfolane from said enriched stream of step (d).
摘要翻译： 本发明提供了从含有结合聚合物，环丁砜和氢氟酸的混合物中分离结合聚合物和环丁砜的方法，包括以下顺序步骤：（a）从所述混合物中分离出氢氟酸，以提供含有少于约30％ 氢氟酸; （b）将所述中间物流重力分离成富含环丁砜的物流和富含聚合物的混合物流; （c）使富含环丁砜的料流与极性萃取溶剂接触，以提供富含环丁砜的萃取物流和富含结合聚合物的萃余液流; （d）从所述富含环丁砜的萃取物流中汽提极性萃取溶剂; 和（e）从步骤（d）的富集流中回收环丁砜。
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公开(公告)号：US5264650A
公开(公告)日：1993-11-23
申请号：US991919
申请日：1992-12-17
申请人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
发明人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
CPC分类号： C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid to provide a first intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) mixing said intermediate stream with a nonpolar extraction solvent to provide a second intermediate stream; and(c) gravitationally separating said intermediate stream into a less dense extract stream enriched in conjunct polymers and a more dense liquid stream enriched in sulfolane.
摘要翻译： 本发明提供了一种从含有结合聚合物，环丁砜和氢氟酸的混合物中分离形成酸催化的异链烷烃 - 烯烃烷基化和环丁砜副产物的结合聚合物的方法，其包括以下步骤：（a）将氢氟酸与 含有结合聚合物，环丁砜和氢氟酸的混合物，以提供含有按重量计小于约30％氢氟酸的第一中间物流; （b）将所述中间物流与非极性萃取溶剂混合以提供第二中间物流; 和（c）将所述中间物流重力分离成富含结合聚合物的较不致密的提取物流和富含环丁砜的更致密的液体物流。
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公开(公告)号：US5262579A
公开(公告)日：1993-11-16
申请号：US991918
申请日：1992-12-17
IPC分类号： C01B7/19 , C07C2/62 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) removing HF from said mixture to provide an intermediate stream containing less than about 30 weight percent HF;(b) contacting said intermediate stream with water;(c) contacting said intermediate stream with an aliphatic hydrocarbon co-solvent having from about 3 to about 20 carbon atoms concurrently with said water-contacting step (b);(d) recovering an extract stream enriched in sulfolane and hydrofluoric acid; and(e) recovering a raffinate stream enriched in conjunct polymers.
摘要翻译： 本发明提供了从含有结合聚合物，环丁砜和氢氟酸的混合物中分离环丁砜的方法，其包括以下顺序步骤：（a）从所述混合物中除去HF以提供含有少于约30重量％HF的中间物流; （b）使所述中间物流与水接触; （c）使所述中间物流与具有约3至约20个碳原子的脂族烃共溶剂与所述水接触步骤（b）同时接触; （d）回收富含环丁砜和氢氟酸的萃取物流; 和（e）回收富含结合聚合物的萃余液流。
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公开(公告)号：US5012014A
公开(公告)日：1991-04-30
申请号：US515029
申请日：1990-04-26
CPC分类号： C07C29/04 , C07C41/06 , C07C41/09 , B01J29/7007
摘要： A process for production of alcohol or ether by hydration of olefinic feedstock containing at least one lower alkene by contacting the olefinic feedstock and water in a hydration zone with porous solid metal oxide acidic olefin hydration catalyst under olefins hydration conditions. The process is characterized by the step of pretreating porous solid catalyst, such as acid zeolite, prior to contacting with the olefinic feedstock with a wetting agent containing at least one polar aliphatic oxygenated hydrocarbon to substantially wet said solid catalyst and sorb said wetting agent into pores of said solid catalyst. After initiating hydration reaction by feeding the olefinic feedstock and water, increased catalytic activity is obtained. The process is particularly useful for making isopropanol and DIPE from propene and water.
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8.发明授权Process and apparatus for the uniform distribution of a two-phase feed in a chemical reaction zone 失效用于在化学反应区中均匀分布两相进料的方法和装置
公开(公告)号：US4927977A
公开(公告)日：1990-05-22
申请号：US296093
申请日：1989-01-12
摘要： A process and apparatus are provided for the substantially uniform distribution of a two-phase feed in a chemical reaction zone. As applied, for example, to the hydration/etherification of light olefin to alcohol(s) and/or ether(s), the invention results in greater process control and in particular cases, to improved reaction product selectivities.
摘要翻译： 提供了一种用于将化学反应区中的两相进料基本上均匀分布的方法和装置。 例如，应用于轻烯烃与醇和/或醚的水合/醚化，本发明导致更大的过程控制，特别是在改进的反应产物选择性方面。
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9.发明授权Isomerization process to produce low pour point distillate fuels and lubricating oil stocks 失效产生低倾点馏分燃料和润滑油库存的异构化过程
公开(公告)号：US4554065A
公开(公告)日：1985-11-19
申请号：US606499
申请日：1984-05-03
CPC分类号： C10G65/043
摘要： A process for dewaxing a hydrocarbon feedstock with a relatively high pour point and containing normal and slightly branched paraffins by subjecting said feed to catalytic dewaxing over a noble metal promoted zeolite beta catalyst followed by dewaxing with a base metal promoted zeolite beta catalyst. The feed may be hydrotreated before dewaxing.
摘要翻译： 通过使所述进料在贵金属上促进沸石β催化剂进行催化脱蜡，然后用碱金属促进的沸石β催化剂脱蜡，使具有较高倾点的烃原料脱蜡并含有正常和轻微支化的链烷烃的方法。 进料可以在脱蜡之前进行加氢处理。
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公开(公告)号：US5258568A
公开(公告)日：1993-11-02
申请号：US965306
申请日：1992-10-23
CPC分类号： C07C2/62 , C07C2527/054 , C07C2527/1206
摘要： A single path process for alkylating a hydrocarbon feedstock containing an olefin and an isoparaffin is disclosed. The process includes dispersing an acid-based liquid alkylation catalyst into a reaction zone for contact with a continuous hydrocarbon phase. The process further includes separating the hydrocarbon phase from the acid catalyst upon completion of the alkylation reaction and providing a continuous on-line regeneration of the entire volume of catalyst once it has been separated from the hydrocarbon phase.
摘要翻译： 公开了用于烷基化含有烯烃和异链烷烃的烃原料的单程方法。 该方法包括将酸基液体烷基化催化剂分散在与连续烃相接触的反应区中。 该方法还包括在烷基化反应完成时从酸催化剂中分离出烃相，并且一旦将其从烃相中分离出来，就提供了整个体积催化剂的连续在线再生。
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