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公开(公告)号：US5262579A
公开(公告)日：1993-11-16
申请号：US991918
申请日：1992-12-17
IPC分类号： C01B7/19 , C07C2/62 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) removing HF from said mixture to provide an intermediate stream containing less than about 30 weight percent HF;(b) contacting said intermediate stream with water;(c) contacting said intermediate stream with an aliphatic hydrocarbon co-solvent having from about 3 to about 20 carbon atoms concurrently with said water-contacting step (b);(d) recovering an extract stream enriched in sulfolane and hydrofluoric acid; and(e) recovering a raffinate stream enriched in conjunct polymers.
摘要翻译： 本发明提供了从含有结合聚合物，环丁砜和氢氟酸的混合物中分离环丁砜的方法，其包括以下顺序步骤：（a）从所述混合物中除去HF以提供含有少于约30重量％HF的中间物流; （b）使所述中间物流与水接触; （c）使所述中间物流与具有约3至约20个碳原子的脂族烃共溶剂与所述水接触步骤（b）同时接触; （d）回收富含环丁砜和氢氟酸的萃取物流; 和（e）回收富含结合聚合物的萃余液流。
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公开(公告)号：US5258568A
公开(公告)日：1993-11-02
申请号：US965306
申请日：1992-10-23
CPC分类号： C07C2/62 , C07C2527/054 , C07C2527/1206
摘要： A single path process for alkylating a hydrocarbon feedstock containing an olefin and an isoparaffin is disclosed. The process includes dispersing an acid-based liquid alkylation catalyst into a reaction zone for contact with a continuous hydrocarbon phase. The process further includes separating the hydrocarbon phase from the acid catalyst upon completion of the alkylation reaction and providing a continuous on-line regeneration of the entire volume of catalyst once it has been separated from the hydrocarbon phase.
摘要翻译： 公开了用于烷基化含有烯烃和异链烷烃的烃原料的单程方法。 该方法包括将酸基液体烷基化催化剂分散在与连续烃相接触的反应区中。 该方法还包括在烷基化反应完成时从酸催化剂中分离出烃相，并且一旦将其从烃相中分离出来，就提供了整个体积催化剂的连续在线再生。
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3.发明授权Method for separating conjunct polymeric byproducts from mixture containing hydrofluoric acid and a sulfone 失效从包含氢氟酸和砜的混合物中分离结合的聚合副产物的方法
公开(公告)号：US5264652A
公开(公告)日：1993-11-23
申请号：US991921
申请日：1992-12-17
申请人： Jonathan E. Child , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
发明人： Jonathan E. Child , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
CPC分类号： C01B7/195 , C07C2/62 , C07C9/16 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from said mixture to provide an intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) gravitationally separating said intermediate stream into a more dense sulfolane-enriched stream and a less dense conjunct polymer-enriched stream;(c) distilling said more dense sulfolane-enriched stream of step (b) to provide an overhead stream containing a higher sulfolane concentration than said more dense sulfolane-enriched stream of step (b) and a bottom stream enriched in conjunct polymers.
摘要翻译： 本发明提供一种从含有结合聚合物，环丁砜和氢氟酸的混合物中分离出作为酸催化的异链烷烃 - 烯烃烷基化和环丁砜的副产物形成的结合聚合物的方法，包括以下顺序步骤：（a）将氢氟酸与所述 混合物以提供含有按重量计小于约30％氢氟酸的中间料流; （b）将所述中间物流重力分离成更稠密的富含环丁砜的物流和不太致密的结合聚合物富集料流; （c）蒸馏步骤（b）的所述更稠密的富含环丁砜的物流，以提供比步骤（b）的所述更致密的富含环丁砜的物流高的环丁砜浓度的塔顶物流和富含结合聚合物的塔底物流。
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公开(公告)号：US5276243A
公开(公告)日：1994-01-04
申请号：US991922
申请日：1992-12-17
申请人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Anagha A. Gupte , Tomas R. Melli , Sergei Yurchak
发明人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Anagha A. Gupte , Tomas R. Melli , Sergei Yurchak
IPC分类号： C01B7/19 , C07C2/62 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from said mixture to provide an intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) gravitationally separating said intermediate stream into a sulfolane-enriched stream and a conjunct polymer-enriched stream;(c) contacting said sulfolane-enriched stream with a polar extraction solvent to provide an extract stream enriched in sulfolane and a raffinate stream enriched in conjunct polymers;(d) stripping the polar extraction solvent from said sulfolane-enriched extract stream; and(e) recovering sulfolane from said enriched stream of step (d).
摘要翻译： 本发明提供了从含有结合聚合物，环丁砜和氢氟酸的混合物中分离结合聚合物和环丁砜的方法，包括以下顺序步骤：（a）从所述混合物中分离出氢氟酸，以提供含有少于约30％ 氢氟酸; （b）将所述中间物流重力分离成富含环丁砜的物流和富含聚合物的混合物流; （c）使富含环丁砜的料流与极性萃取溶剂接触，以提供富含环丁砜的萃取物流和富含结合聚合物的萃余液流; （d）从所述富含环丁砜的萃取物流中汽提极性萃取溶剂; 和（e）从步骤（d）的富集流中回收环丁砜。
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公开(公告)号：US5264651A
公开(公告)日：1993-11-23
申请号：US991920
申请日：1992-12-17
IPC分类号： C01B7/19 , C07C2/62 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C2527/1206 , Y02P20/584
摘要： This invention provides a method for separating ASO from a mixture containing ASO, HF and sulfolane comprising the steps of:(a) contacting said mixture with a sorbent to selectively sorb HF and water from said mixture to evolve an intermediate product containing less than 5 weight percent HF;(b) charging said intermediate product to a gravitational separation zone;(c) holding said intermediate product in said gravitational separation zone for time sufficient to evolve two at least partially immiscible liquid phases in said gravitational separation zone; and(d) withdrawing a less-dense phase enriched in ASO and a more-dense phase enriched in sulfolane from said gravitational separation zone.
摘要翻译： 本发明提供了一种从含有ASO，HF和环丁砜的混合物中分离ASO的方法，包括以下步骤：（a）使所述混合物与吸附剂接触以选择性地从所述混合物吸收HF和水，以释放含有小于5重量的中间产物 百分比HF; （b）将所述中间产物装入重力分离区; （c）在所述重力分离区中保持所述中间产物足以在所述重力分离区中放出两个至少部分不混溶的液相的时间; 和（d）从所述重力分离区取出富含ASO的较不密集的相和富含环丁砜的更致密相。
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公开(公告)号：US5264650A
公开(公告)日：1993-11-23
申请号：US991919
申请日：1992-12-17
申请人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
发明人： Michael A. Better , Jonathan E. Child , Kenneth J. Del Rossi , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
CPC分类号： C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid to provide a first intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) mixing said intermediate stream with a nonpolar extraction solvent to provide a second intermediate stream; and(c) gravitationally separating said intermediate stream into a less dense extract stream enriched in conjunct polymers and a more dense liquid stream enriched in sulfolane.
摘要翻译： 本发明提供了一种从含有结合聚合物，环丁砜和氢氟酸的混合物中分离形成酸催化的异链烷烃 - 烯烃烷基化和环丁砜副产物的结合聚合物的方法，其包括以下步骤：（a）将氢氟酸与 含有结合聚合物，环丁砜和氢氟酸的混合物，以提供含有按重量计小于约30％氢氟酸的第一中间物流; （b）将所述中间物流与非极性萃取溶剂混合以提供第二中间物流; 和（c）将所述中间物流重力分离成富含结合聚合物的较不致密的提取物流和富含环丁砜的更致密的液体物流。
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公开(公告)号：US5382746A
公开(公告)日：1995-01-17
申请号：US117274
申请日：1993-09-07
IPC分类号： C01B7/19 , C07C2/62 , C07C9/16 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C9/16 , C07C2527/1206 , Y02P20/584
摘要： The present invention provides a method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid, and for minimizing accumulation of conjunct polymeric byproducts in the recycled acid catalyst.
摘要翻译： 本发明提供了一种分离结合聚合物的方法，其由含有结合聚合物，环丁砜和氢氟酸的混合物形成为酸催化的异链烷烃 - 烯烃烷基化和环丁砜的副产物，并且用于最小化在再循环的酸催化剂中结合的聚合副产物的积聚 。
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8.发明授权Method for separating conjunct polymeric byproducts from mixture containing hydrofluoric acid and a sulfone 失效从包含氢氟酸和砜的混合物中分离结合的聚合副产物的方法
公开(公告)号：US5191150A
公开(公告)日：1993-03-02
申请号：US833684
申请日：1992-02-11
CPC分类号： C01B7/195 , C07C2/62 , C07C2527/1206
摘要： A method for separating conjunct polymers and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid is disclosed, which method comprises the sequential steps of separating hydrofluoric acid from said mixture to provide an intermediate stream containing less than about 30 percent hydrofluoric acid by weight and gravitationally separating said intermediate stream into a sulfolane-enriched stream and a conjunct polymer-enriched stream.
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公开(公告)号：US5120895A
公开(公告)日：1992-06-09
申请号：US664241
申请日：1991-03-04
申请人： Jonathan E. Child , Tomas R. Melli
发明人： Jonathan E. Child , Tomas R. Melli
CPC分类号： C07C2/62 , B01J10/002 , B01J19/006 , B01J2219/00081 , B01J2219/00094 , B01J2219/00768 , C07C2527/1206 , Y10S585/921
摘要： A process and apparatus are disclosed for acid continuous alkylation of a hydrocarbon-containing feedstream in which the inventory of acid is reduced. The apparatus used combines a reactor, settler and heat exchanger in a single vessel. The acid phase flows out of the reactor only for acid makeup, to account for acid consumption, and regeneration.
摘要翻译： 公开了一种酸性连续烷基化含烃进料流的方法和装置，其中酸的存量减少。 使用的装置将反应器，沉降器和热交换器组合在一个容器中。 酸相仅从酸性组合物流出反应器，以解释酸消耗和再生。
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10.发明授权
公开(公告)号：US5414186A
公开(公告)日：1995-05-09
申请号：US136481
申请日：1993-10-13
申请人： Jonathan E. Child , Tomas R. Melli
发明人： Jonathan E. Child , Tomas R. Melli
CPC分类号： C07C2/62 , C07C2527/1206 , C07C2531/025
摘要： The present invention provides an acid catalyzed isoparaffin-olefin alkylation process which improves process stability and safety by storing the acid in an excess of an additive which reduces the fuming tendency of the mixture, for example, a sulfone. Acid is stripped from the additive and concentrated prior to charging the acid to the alkylation reaction zone. Specifically, because the stored solution of acid in the additive is more dilute than can be effectively used for isoparaffin-olefin alkylation, the acid is concentrated prior to charging the catalyst mixture to the reaction zone. The invention solves the problem of conjunct polymer accumulation by diluting the conjunct polymer with a relatively large volume of the additive and continuously regenerating a slipstream of the dilute acid/additive mixture.
摘要翻译： 本发明提供了一种酸催化的异链烷烃烯烃烷基化方法，其通过将酸储存在过量的添加剂中来提高工艺稳定性和安全性，这降低了混合物例如砜的发烟趋势。 在将酸加入到烷基化反应区之前，从添加剂中除去酸并浓缩。 具体地说，由于储存在添加剂中的酸溶液比可以有效地用于异链烷烃 - 烷基化烷基化更为稀释，所以在将催化剂混合物装入反应区之前将酸浓缩。 本发明通过用相对大量的添加剂稀释结合聚合物并连续再生稀酸/添加剂混合物的滑流来解决聚合物聚合物积聚的问题。
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