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1.发明授权Thermotropic polyester-carbonates containing 2,2-dimethyl-1,3-propanediol 失效含2,2-二甲基-1,3-丙二醇的热致聚酯 - 碳酸酯
公开(公告)号：US4612362A
公开(公告)日：1986-09-16
申请号：US716312
申请日：1985-03-27
申请人： Yu-Chin Lai , Bruce T. DeBona , Dusan C. Prevorsek
发明人： Yu-Chin Lai , Bruce T. DeBona , Dusan C. Prevorsek
IPC分类号： C08G63/64
CPC分类号： C08G63/64
摘要： A thermotropic polyester carbonate containing aromatic diacyl moieties, aromatic dihydroxy moieties and carbonate moieties, wherein up to 50 mole percent of the aromatic dioxy moieties are replaced with aliphatic dihydroxy moiety, such as 2,2-dimethyl-1,3-propanediol.
摘要翻译： 含有芳族二酰基部分，芳族二羟基部分和碳酸酯部分的热致聚酯碳酸酯，其中至多50摩尔％的芳族二氧基部分被脂族二羟基部分如2,2-二甲基-1,3-丙二醇代替。
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2.发明授权Temperature stable thermotropic poly(ester carbonate) derived from t-butylhydroquinone 失效衍生自叔丁基氢醌的温度稳定的热致聚（碳酸酯）
公开(公告)号：US4398018A
公开(公告)日：1983-08-09
申请号：US333228
申请日：1981-12-21
IPC分类号： C08G63/64
CPC分类号： C08G63/64
摘要： A thermotropic poly(ester carbonate) containing diacyl moieties such as terephthalate and carbonate moieties as well as dihydroxy-derived moieties is useful for forming fibers or films. The dihydroxy-derived moieties are at least 40% derived from t-butylhydroquinone, with hydroquinone and methylhydroquinone being exemplary second components. The polymers can be prepared by melt, solution or interfacial polymerization, are liquid crystalline in the melt and have glass transition temperatures above 100.degree. C.
摘要翻译： 含有二酰基部分如对苯二甲酸酯和碳酸酯部分的热致聚（酯碳酸酯）以及二羟基衍生的部分可用于形成纤维或膜。 二羟基衍生的部分至少40％来自叔丁基氢醌，其中氢醌和甲基氢醌是示例性的第二组分。 聚合物可以通过熔融，溶液或界面聚合制备，在熔体中为液晶，玻璃化转变温度高于100℃。
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3.发明授权Process for the production of thermoplastic compositions containing thermotropic oligomers and compositions produced by such process 失效用于生产含有热致低聚物和通过这种方法制备的组合物的热塑性组合物的方法
公开(公告)号：US4611025A
公开(公告)日：1986-09-09
申请号：US720103
申请日：1985-04-04
摘要： A process of blending two or more polymers having varying viscosities by blending the polymers in the melt in the presence of a solid particulate material to form polymer blends having improved dispersion of the polymer.
摘要翻译： 通过在固体颗粒材料的存在下共混熔体中的聚合物以形成具有改进的聚合物分散体的聚合物共混物来混合具有不同粘度的两种或更多种聚合物的方法。
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4.发明授权Melt processable poly(ester carbonate) with high glass transition temperature 失效具有高玻璃化转变温度的可熔融加工的聚（碳酸酯）
公开(公告)号：US4310652A
公开(公告)日：1982-01-12
申请号：US133228
申请日：1980-03-24
CPC分类号： C08G63/64
摘要： Poly(ester aromatic dihydric alcohol) polymers having carbonate moieties, aromatic or cycloaliphatic dicarboxylic acid moieties and carbonate moieties and having high glass transition temperatures (over 100.degree. C.) and being melt processable. At least part of the aromatic dihydric alcohol moieties have the 4-carbon of each of two phenoxies covalently bonded to the same ring carbon of a carbocyclic or heterocyclic moiety. Representative poly(ester carbonates) are formed from bisphenol-A, phenolphthalein, terephthaloyl chloride and phosgene.
摘要翻译： 具有碳酸酯部分，芳族或脂环族二羧酸部分和碳酸酯部分并具有高玻璃化转变温度（超过100℃）并且可熔融加工的聚（酯芳族二元醇）聚合物。 至少部分芳族二元醇部分具有共价键合到碳环或杂环部分的相同环碳上的两个苯氧基中的每一个的4-碳。 代表性的聚（碳酸酯）由双酚A，酚酞，对苯二甲酰氯和光气形成。
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5.发明授权Temperature stable thermotropic poly(ester carbonate) containing high amounts of readily available diols 失效含有大量容易获得的二醇的温度稳定的热致聚（碳酸酯）
公开(公告)号：US4435561A
公开(公告)日：1984-03-06
申请号：US509471
申请日：1983-06-30
IPC分类号： C08G63/64
CPC分类号： C08G63/64
摘要： Thermotropic poly(ester carbonates) such as the terephthalate/carbonate of a mixture of hydroquinose, resorcinol, tert-butylhydroquinone and methylhydroquinone. With a major proportion of the more readily available hydroquinone and resorcinol, thermotropic properties (liquid crystallinity in the melt) are observed.
摘要翻译： 热致聚（碳酸酯）如氢醌，间苯二酚，叔丁基氢醌和甲基氢醌的混合物的对苯二甲酸酯/碳酸酯。 在较大比例的较容易获得的氢醌和间苯二酚中，观察到热致变性（熔体中的液晶）。
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公开(公告)号：US4374973A
公开(公告)日：1983-02-22
申请号：US283330
申请日：1981-07-15
申请人： Dusan C. Prevorsek , Bruce T. DeBona , Yali Kesten
发明人： Dusan C. Prevorsek , Bruce T. DeBona , Yali Kesten
CPC分类号： C08G63/64
摘要： Polycarbonate copolymers from bisphenol-A containing terephthalate moieties constituting 5 or 10 mol percent of the polymer, whereby after long exposure to working temperature the polymer retains Izod impact resistance of at least 9 ft. -lbs. per inch of notch.
摘要翻译： 来自双酚A的对苯二酸酯部分的聚碳酸酯共聚物构成聚合物的5或10摩尔％，由此在长时间暴露于工作温度之后，聚合物保持至少9英尺-1磅的艾佐德冲击抗力。 每英寸的切口。
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7.发明授权Circuit board made from cross-linked polycyanurate polymer, thermoplastic polymer and polyaramid fiber 失效电路板由交联聚氰化聚合物，热塑性聚合物和聚芳酰胺纤维制成
公开(公告)号：US4623577A
公开(公告)日：1986-11-18
申请号：US697359
申请日：1985-02-01
申请人： Eric S. Hsiue , Daniel Ziatyk , George R. Stone , Bruce T. DeBona
发明人： Eric S. Hsiue , Daniel Ziatyk , George R. Stone , Bruce T. DeBona
CPC分类号： H05K1/0346 , H05K1/0366 , H05K2201/0129 , H05K2201/0278 , H05K2201/068 , Y10S428/901 , Y10S428/902 , Y10T428/24917 , Y10T428/31547 , Y10T442/2893 , Y10T442/3854
摘要： The present invention is a circuit board having a substrate comprising a semi-IPN and at least one balanced polyaramid layer.
摘要翻译： 本发明是具有包含半IPN和至少一个平衡聚芳酰胺层的基板的电路板。
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公开(公告)号：US4255556A
公开(公告)日：1981-03-10
申请号：US29422
申请日：1979-04-12
申请人： Leon Segal , Bruce T. DeBona
发明人： Leon Segal , Bruce T. DeBona
CPC分类号： C08G63/64
摘要： Poly(ester carbonate) polymers are prepared by reaction of bifunctional phenolates in an aqueous phase with phosgene and with the acyl halide of a bifunctional carboxylic acid halide such as terephthaloyl chloride in an organic solvent such as dichloromethane. At least a portion of the phosgene is reacted with the phenolate before or during reaction of the acid chloride with the phenolate to avoid the formation of polyester blocks which have limited solubility in the organic solvent. After reaction is complete, or at any stage wherein oligomers are formed, the aqueous phase can be cleanly removed and easily separated from the organic phase, and the organic phase readily washed free of by-products. The final polymer product is recovered from the washed organic phase and is colorless, substantially amorphous and melt processable, and has a high glass transition temperature.
摘要翻译： 聚（碳酸酯）聚合物通过在水相中的双功能酚盐与光气和双官能羧酸卤化物如对苯二甲酰氯的酰卤在有机溶剂如二氯甲烷中反应来制备。 在酸酰胺与酚盐反应之前或期间，光气的至少一部分与酚盐反应，以避免在有机溶剂中溶解度有限的聚酯嵌段的形成。 反应完成后，或在其中形成低聚物的任何阶段，水相可以被干净地除去并容易地与有机相分离，并且有机相容易地被洗涤而不含副产物。 从洗涤的有机相中回收最终的聚合物产物，是无色的，基本上无定形的和可熔融加工的，并且具有高的玻璃化转变温度。
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9.发明授权Polymers of p-(1,1-dimethyl-2-hydroxyethyl)benzoic acid and preparation thereof 失效对 - （1,1-二甲基-2-羟乙基）苯甲酸的聚合物及其制备方法
公开(公告)号：US4310655A
公开(公告)日：1982-01-12
申请号：US153361
申请日：1980-05-27
IPC分类号： C08G63/06 , C08G63/664
CPC分类号： C08G63/664 , C08G63/06 , C08G63/065
摘要： The subject polymers are novel homopolymers and copolymers. The homopolymers are characterized by relatively high T.sub.g of about 120.degree. C. relative to their T.sub.m of about 250.degree. C., whereby they can readily be fabricated into fibers, films and like structures from the melt, and retain strength above 100.degree. C. The copolymers have T.sub.g 's intermediate between those of the homopolymers of the constituent monomers, and can be fabricated as for the subject homopolymers.Novel processes of obtaining the monomer, p-(1,1-dimethyl-2-hydroxyethyl)benzoic acid, are disclosed.
摘要翻译： 主题聚合物是新的均聚物和共聚物。 均聚物的特征在于相对于它们的Tm约为250℃的约120℃的相对高的Tg，由此它们可以容易地从熔体制成纤维，薄膜和类似结构，并保持高于100℃的强度。 共聚物的Tg在构成单体的均聚物之间的中间体，并且可以与目标均聚物一样制备。 公开了获得单体对 - （1,1-二甲基-2-羟乙基）苯甲酸的新方法。
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10.发明授权Interfacial production of poly(ester carbonate) or polyester including acid chloride synthesis 失效聚（碳酸酯）或聚酯的界面生产，包括酰氯合成
公开(公告)号：US4311822A
公开(公告)日：1982-01-19
申请号：US145901
申请日：1980-05-02
申请人： Gerald J. Dege , Leon Segal , Bruce T. DeBona , Robert S. Cooke
发明人： Gerald J. Dege , Leon Segal , Bruce T. DeBona , Robert S. Cooke
IPC分类号： C08G63/00 , B01J31/00 , C07C51/00 , C07C51/58 , C07C51/60 , C07C67/00 , C08G63/19 , C08G63/64 , C08G64/22 , C08G64/26 , C08G63/62
摘要： A process for producing poly(ester carbonates) and polyesters by reacting an aromatic or cycloaliphatic dicarboxylate salt such as sodium terephthalate with phosgene in an organic solvent in the presence of a catalytic amount of a tertiary nitrogen compound such as pyridine, optionally separating the suspended by-product inorganic salt and then interfacially reacting with a bisphenol such as bisphenol A. Excess phosgene in the diacid chloride synthesis can be carried over to the polymerization if a poly(ester carbonate) is to be produced or removed if a polyester is to be produced. Certain low levels of a tertiary nitrogen compound with a pyridine nucleus in the organic solution do not interfere with the interfacial polymerization.
摘要翻译： 通过使芳族或脂环族二羧酸盐如对苯二甲酸钠与光气在有机溶剂中在催化量的叔氮化合物如吡啶的存在下反应来制备聚（碳酸酯）和聚酯的方法，任选将由 - 产物无机盐，然后与双酚如双酚A进行界面反应。如果要生产或除去聚酯（如果要生产聚酯），则二酰氯合成中的过量光气可以转移到聚合反应 。 某些低水平的有机溶液中含有吡啶核的叔氮化合物不会干扰界面聚合。
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