Storage-stable, quick-curing epoxide resin moulding materials

    公开(公告)号:US3963666A

    公开(公告)日:1976-06-15

    申请号:US571143

    申请日:1975-04-24

    IPC分类号: C08G59/10 C08G59/18 C08L63/00

    CPC分类号: C08G59/184 C08G59/10

    摘要: The invention relates to storage-stable, quick-curing epoxide resin moulding materials containing:A. pre-adducts containing aromatic constituents and free epoxide groups and formed from epoxide resins and polyamines,B. pre-adducts containing free amino groups and formed from polyamines containing cycloaliphatic or heterocyclic groups with polyglycidyl compounds, as curing agents, andC. mineral or organic pulverulent or fibrous fillers, with the epoxide resin pre-adducts and the curing agents softening between 45.degree. and 120.degree.C, and melting 5.degree. to 30.degree.C above the softening point, and the resin pre-adducts and the curing agents being present in the moulding materials predominantly in the form of particles separated from each other.The moulded articles are distinguished by very good stability to solar and UV rays, and retain their original colour to a very considerable extent even after prolonged irradiation.

    Storage-stable, quick-curing epoxide resin moulding materials
    2.
    发明授权
    Storage-stable, quick-curing epoxide resin moulding materials 失效
    储存稳定,快速固化环氧树脂成型材料

    公开(公告)号:US3996175A

    公开(公告)日:1976-12-07

    申请号:US489331

    申请日:1974-07-17

    IPC分类号: C08G59/18 C08L63/00 C08L91/00

    CPC分类号: C08L63/00 C08G59/184

    摘要: The invention relates to storage-stable, quick-curing epoxide resin moulding materials containing:A. epoxide resins,B. pre-adducts containing free amino groups and formed from polyamines containing aromatic groups and low-molecular epoxide resins, as curing agents, andC. mineral or organic pulverulent or fibrous fillers, with the epoxide resins and the curing agents softening between 45.degree. and 120.degree. C, and having a melting point higher by 5.degree. to 30.degree. C than the softening point, and being present in the said moulding materials predominantly in the form of particles separated from each other. The moulded articles have good mechanical and dielectrical properties.

    摘要翻译: 本发明涉及储存稳定,快速固化的环氧树脂成型材料,其包含:

    Method for treating paper with a composition containing hydantoin
compounds and a copolymer
    3.
    发明授权
    Method for treating paper with a composition containing hydantoin compounds and a copolymer 失效
    用含有乙内酰脲化合物和共聚物的组合物处理纸的方法

    公开(公告)号:US4144120A

    公开(公告)日:1979-03-13

    申请号:US806425

    申请日:1977-06-14

    摘要: A composition for the treatment of paper which improves the wet strength of paper is provided. This composition contains(a) a water-soluble mono- or binuclear hydantoin compound containing glycidyl groups, and(b) a water-soluble copolymer of maleic acid or of one of its derivatives such as maleic anhydride and of a further ethylenically unsaturated copolymerizable comonomer with 2 to 20 carbon atoms such as vinyl methyl ether, dec-1-ene, styrene and/or ethylene or a water-soluble salt of such a copolymer.Also a process for the treatment, preferably the surface treatment of paper with the above composition is provided.

    摘要翻译: 提供了一种用于处理纸张的组合物,其提高纸张的湿强度。 该组合物含有(A)含有甘氨酸组合物的水溶性单一或单一含有氨基糖的化合物,和(B)一种酸性或其衍生物的水溶性共聚物,如马来酸酐和另一种乙烯基不饱和可共聚的共聚物 具有2至20个碳原子,如乙烯基甲醚,DEC-1-ENE,苯乙烯和/或乙烯或这种共聚物的水溶性盐。

    Composition, for the treatment of paper, which contains hydantoin
compounds and an amine curing agent
    4.
    发明授权
    Composition, for the treatment of paper, which contains hydantoin compounds and an amine curing agent 失效
    用于处理含有乙内酰脲化合物和胺固化剂的纸的组合物

    公开(公告)号:US4145247A

    公开(公告)日:1979-03-20

    申请号:US806573

    申请日:1977-06-14

    IPC分类号: D21H19/24 D21H17/52 D21F11/00

    CPC分类号: D21H17/52

    摘要: A composition for the treatment of paper which improves the wet strength of paper is provided. This composition contains (a) a water-soluble mono- or binuclear hydantoin compound containing glycidyl groups, and (b) a water-soluble amine with at least two active amine hydrogen atoms, e.g. an aliphatic polyamine, as curing agent. Also a process for the treatment, preferably the surface treatment of paper with the above composition is provided.

    摘要翻译: 提供了一种用于处理纸张的组合物,其提高纸张的湿强度。 该组合物含有(A)含有甘氨酸组合物的水溶性单一或单一含有氨基糖的化合物,和(B)具有至少两个活性胺氢化物的水溶性胺,E.G. 固化聚氨酯,作为固化剂。

    Moldable prepolymers based on alkali metal silicates and alkaline earth
metal silicates
    6.
    发明授权
    Moldable prepolymers based on alkali metal silicates and alkaline earth metal silicates 失效
    基于碱金属硅酸盐和碱土金属硅酸盐的可成型预聚物

    公开(公告)号:US4366136A

    公开(公告)日:1982-12-28

    申请号:US317959

    申请日:1981-11-04

    CPC分类号: C04B28/00 C04B28/26

    摘要: Prepolymers of alkali metal silicates and/or alkaline earth metal silicates and metal oxides, which can be used as molding compositions, preferably compression molding compositions, for the production of compression-molding laminates or of insulating sheets, are obtained by a method wherein a mixture of solid alkali metal silicates and/or alkaline earth metal silicates, and/or aqueous solutions of such silicates, with or without addition of water, and of divalent to tetravalent metal oxides, the ratio of metal oxide to silicate in the mixture being from 1:1 to 1:9, expressed in parts by weight of solids, and the homogenized mixture having a water content of from 10 to 50% by weight, based on the total amount of mixture, is allowed to pre-react in the temperature range of 10.degree. to 50.degree. C. until the water content of the mixture has decreased by from 0.1 to 25% by weight and a product which is sufficiently tough and dry to permit comminution is obtained, and this product is comminuted and then heated at temperatures of up to 120.degree. C. until the prepolymer obtained has a water content of from 20 to 2% by weight.

    摘要翻译: 可以通过一种方法获得可用作生产压缩成型层压体或绝缘片的成型组合物,优选压缩成型组合物的碱金属硅酸盐和/或碱土金属硅酸盐和金属氧化物的预聚物,其中混合物 的固体碱金属硅酸盐和/或碱土金属硅酸盐,和/或这种硅酸盐的水溶液,有或没有加入水,以及二价至四价金属氧化物,混合物中金属氧化物与硅酸盐的比例为1 :1〜1:9,以固形物的重量份表示,将含水量为10〜50重量%的均匀混合物(以混合物的总量为基准)在温度范围内进行预反应 10℃至50℃,直到混合物的含水量降低0.1至25重量%,得到足够坚硬和干燥以允许粉碎的产品,并将该产品粉碎 然后在高达120℃的温度下加热,直到获得的预聚物的水含量为20-2重量%。

    Foams of silicates and poly(meth)acrylic acids
    7.
    发明授权
    Foams of silicates and poly(meth)acrylic acids 失效
    硅酸盐泡沫和聚(甲基)丙烯酸

    公开(公告)号:US4464486A

    公开(公告)日:1984-08-07

    申请号:US515414

    申请日:1983-07-20

    CPC分类号: C04B28/24

    摘要: Inorganic-organic foams are obtained by foaming a mixture of(a) a 5 to 60% by weight aqueous alkali metal silicate or ammonium silicate solution,(b) a sufficient amount of a conventional hardener for aqueous silicate solutions,(c) a polymer of (meth)acrylic acid or a copolymer of acrylic acid and methacrylic acid or of (meth)acrylic acid and a copolymerizable monomer containing ethylinic double bonds, the polymer and copolymer being soluble in the aqueous silicate solution, some or all the carboxyl groups of the polymer or copolymer, where relevant, being neutralized by a base and the amount of polymer or copolymer being 0.1 to 30 parts per 100 parts of SiO.sub.2 contained in the aqueous silicate solution,(d) a blowing agent,(e) a surfactant having a foaming action and, where relevant,(f) gelling agent for solidifying the foam before hardening and/or conventional fillers, and allowing the foam to harden.The foams can be used as insulating materials in the construction industry.

    摘要翻译: 通过将(a)5至60重量%的碱金属硅酸盐或硅酸铵水溶液,(b)足量的用于硅酸水溶液的常规固化剂的混合物发泡,获得无机有机泡沫,(c)聚合物 的(甲基)丙烯酸或丙烯酸和甲基丙烯酸或(甲基)丙烯酸的共聚物和含有亚乙基双键的可共聚单体,该聚合物和共聚物可溶于硅酸水溶液中,部分或全部羧基为 聚合物或共聚物在相关的情况下被碱中和,聚合物或共聚物的量为0.1至30份/ 100份硅酸盐水溶液中所含的SiO 2,(d)发泡剂,(e)具有 发泡作用,并且在相关的情况下,(f)在硬化前固化泡沫的胶凝剂和/或常规填料,并使泡沫体硬化。 泡沫可以用作建筑行业的绝缘材料。