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公开(公告)号:US06617477B2
公开(公告)日:2003-09-09
申请号:US09995798
申请日:2001-11-29
申请人: Byeong No Lee , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han , Hyun Kwan Shin , Ho Sun Lee
发明人: Byeong No Lee , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han , Hyun Kwan Shin , Ho Sun Lee
IPC分类号: C07C2700
CPC分类号: C07C29/149 , B01J23/72 , C07C31/205
摘要: A process for preparing an 1,3-alkanediol from a 3-hydroxyester includes hydrogenating a 3-hydroxyester in an alcohol-containing solvent in the presence of a hydrogenation catalyst prepared by adding an alkaline precipitator to an aqueous solution containing a copper salt to form particles, and then aging the particles following addition of colloidal silica thereto. Novel hydrogenation catalysts so prepared are also disclosed.
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公开(公告)号:US06617478B2
公开(公告)日:2003-09-09
申请号:US10212671
申请日:2002-08-06
申请人: Byeong No Lee , In Sun Jung , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han
发明人: Byeong No Lee , In Sun Jung , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han
IPC分类号: C07C2700
CPC分类号: B01J23/72 , B01J21/08 , B01J23/8892 , B01J37/0009 , B01J37/03 , B01J37/18 , C07C29/149 , C07C31/205
摘要: A process for preparing a 1,3-alkandiol from a 3-hydroxyester, comprises preparing a catalyst by adding an alkaline precipitator to an aqueous copper salt solution to form copper hydroxide particles, and aging the particles following the addition of a colloidal silica thereto; activating the catalyst by reduction with a H2 gas or a H2-containing gas and applying a pressure of about 5 psig to about 2000 psig at a temperature of about 100° C. to about 250° C. in the presence of an activation solvent; and hydrogenating a 3-hydroxyester in a liquid phase slurry with a H2 gas or a H2-containing gas and applying a pressure of about 50 psig to about 3000 psig at a temperature of about 100° C. to about 250° C. in the presence of the activated catalyst and a reaction solvent, whereby a 1,3-alkanediol can be selectively prepared from a 3-hydroxyester with a high yield.
摘要翻译: 从3-羟基酯制备1,3-二醇的方法包括通过向铜盐水溶液中加入碱性沉淀器来制备催化剂以形成氢氧化铜颗粒,并且在加入胶体二氧化硅后使颗粒老化; 通过用H 2气体或含H 2气体还原并在约100psi至约250℃的温度下在活化溶剂的存在下施加约5psig至约2000psig的压力来活化催化剂; 并用氢气或含H 2气体在液相浆料中氢化3-羟基酯,并在约100℃至约250℃的温度下施加约50psig至约3000psig的压力 存在活化的催化剂和反应溶剂,从而可以高产率从3-羟基酯选择性地制备1,3-链烷二醇。
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公开(公告)号:US20110245358A1
公开(公告)日:2011-10-06
申请号:US13139155
申请日:2009-04-27
申请人: Tae Sun Chang , Hyung Rok Kim , Kyoung Hee Yun
发明人: Tae Sun Chang , Hyung Rok Kim , Kyoung Hee Yun
IPC分类号: G02C7/04 , C08F251/00 , C08F230/08 , C08F226/10 , C08G73/06
摘要: The present invention relates to a hydrogel contact lens having improved wettability, and particularly to a hydrogel contact lens of a complex membrane having an IPN (interpenetrating polymer network) intra structure, which is prepared by crosslinking composition for a contact lens comprising, as a main ingredient, an acryl monomer and an oligosaccharide and optionally a silicone compound. Due to the presence of an oligosaccharide in a contact lens herein, tensile strength and wettability can be maximized to provide a superior wearing feeling and maintain wettability even after a long-term storage in a care solution such as a washing solution, a storage solution and a protein-removing solution.
摘要翻译: 本发明涉及具有改善的润湿性的水凝胶隐形眼镜,特别涉及具有IPN(互穿聚合物网络)结构的复合膜的水凝胶隐形眼镜,其通过用于隐形眼镜的交联组合物制备,所述组合物包含作为主要的 成分,丙烯酸单体和寡糖以及任选的硅氧烷化合物。 由于在本文的隐形眼镜中存在寡糖,因此即使在洗涤溶液,储存溶液等保养溶液中长期保存后,拉伸强度和润湿性也可以最大化,以提供优异的穿着感,并保持润湿性, 蛋白质去除溶液。
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公开(公告)号:US08530532B2
公开(公告)日:2013-09-10
申请号:US13139155
申请日:2009-04-27
申请人: Tae Sun Chang , Hyung Rok Kim , Kyoung Hee Yun
发明人: Tae Sun Chang , Hyung Rok Kim , Kyoung Hee Yun
IPC分类号: G02C7/04
摘要: The present invention relates to a hydrogel contact lens having improved wettability, and particularly to a hydrogel contact lens of a complex membrane having an IPN (interpenetrating polymer network) intra structure, which is prepared by crosslinking composition for a contact lens comprising, as a main ingredient, an acryl monomer and an oligosaccharide and optionally a silicone compound. Due to the presence of an oligosaccharide in a contact lens herein, tensile strength and wettability can be maximized to provide a superior wearing feeling and maintain wettability even after a long-term storage in a care solution such as a washing solution, a storage solution and a protein-removing solution.
摘要翻译: 本发明涉及具有改善的润湿性的水凝胶隐形眼镜,特别涉及具有IPN(互穿聚合物网络)结构的复合膜的水凝胶隐形眼镜,其通过用于隐形眼镜的交联组合物制备,所述组合物包含作为主要的 成分,丙烯酸单体和寡糖以及任选的硅氧烷化合物。 由于在本文的隐形眼镜中存在寡糖,因此即使在洗涤溶液,储存溶液等保养溶液中长期保存后,拉伸强度和润湿性也可以最大化,以提供优异的穿着感并保持润湿性, 蛋白质去除溶液。
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