公开(公告)号：US20230002432A1

公开(公告)日：2023-01-05

申请号：US17755484

申请日：2020-10-30

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIGING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Jingjing LAI ,  Zifang GUO ,  Qingqiang GOU ,  Junling ZHOU ,  Xiaofan ZHANG ,  Dongbing LIU ,  Jie LIN ,  Xinyang LI ,  Junhui ZHANG ,  Yuanning GU ,  Yan LI ,  Jingyan AN ,  Hui ZHAO

IPC分类号： C07F15/04 ,  C08F4/70 ,  C08F10/02

摘要： An amino-imine metal complex represented by Formula I, its preparation method and an application thereof are provided. The complex is used as a main catalyst in catalysts for olefin polymerization, and can catalyze the polymerization of ethylene at a relatively high temperature to prepare branched polyethylene having high molecular weight.

公开(公告)号：US20220282005A1

公开(公告)日：2022-09-08

申请号：US17755554

申请日：2020-10-30

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Jingjing LAI ,  Zifang GUO ,  Qingqiang GOU ,  Junling ZHOU ,  Dongbing LIU ,  Xiaofan ZHANG ,  Jie LIN ,  Xinyang LI ,  Junhui ZHANG ,  Yuanning GU ,  Yan LI ,  Jingyan AN ,  Jie FU ,  Yanhong WAN

IPC分类号： C08F4/70 ,  C07F15/04 ,  C08F4/659 ,  C08F2/38 ,  C08F110/02

摘要： A diimine metal complex represented by Formula I, a preparation method therefor, and application thereof are provided. The complex is used as a main catalyst in catalysts for olefin polymerization, and can achieve catalytic ethylene polymerization at a high temperature to prepare high molecular weight branched polyethylene.

公开(公告)号：US20230391902A1

公开(公告)日：2023-12-07

申请号：US18249096

申请日：2021-10-15

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Wei CEN ,  Junling ZHOU ,  Meiyan FU ,  Lian YAN ,  Zhan SHI ,  Xiaofan ZHANG ,  Xianzhi XIA ,  Zhengyang GUO ,  Jigui ZHANG ,  Jie LIN ,  Lin QI ,  Tianyi ZHANG ,  Junhui ZHANG ,  Hui ZHAO ,  Yu WANG ,  Ying WANG

IPC分类号： C08F110/06 ,  C08F4/02 ,  C08F4/16

CPC分类号： C08F110/06 ,  C08F4/022 ,  C08F4/16

摘要： A magnesium-based solid, by means of determination based on a nitrogen adsorption method, has a multimodal pore distribution and a specific surface area of not less than 50 m2/g, and the pore size distribution of the solid is in a range of 1 nm to 300 nm. There is at least one peak within a pore size range of less than 10 nm, and there is at least another peak within a pore size range of not less than 10 nm. A catalyst is formed using the solid catalyst component is used for propylene polymerization.

公开(公告)号：US20240228680A1

公开(公告)日：2024-07-11

申请号：US18554053

申请日：2022-03-21

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Qingqiang GOU ,  Juan LI ,  Xiaofan ZHANG ,  Jingjing LAI ,  Longgui ZHANG ,  Junling ZHOU ,  Jie LIN ,  Xinyang LI ,  Jianhui SONG ,  Junhui ZHANG ,  Jingyan AN ,  Hui ZHAO ,  Yan LI ,  Dong MA ,  Yuanning GU

IPC分类号： C08F210/02

CPC分类号： C08F210/02 ,  C08F2410/03

摘要： A method for preparing polymer includes the steps of enabling olefin and unsaturated carboxylate be subjected to a polymerization reaction in the presence of a catalyst to generate an olefin-unsaturated carboxylate polymer. The catalyst has a primary catalyst and optionally a cocatalyst. The primary catalyst has at least one complex represented by formula I, formula I′, or formula I″. By selecting a reacted unsaturated carboxylate monomer, catalysts, and a suitable polymerization process, a spherical and/or sphere-like polymer having good shape is directly prepared without subsequent processing steps such as granulation, and the obtained polymer product is not prone to fouling in a reactor and is convenient for transportation.

公开(公告)号：US20220396646A1

公开(公告)日：2022-12-15

申请号：US17755542

申请日：2020-10-30

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Jingjing LAI ,  Zifang GUO ,  Qingqiang GOU ,  Junling ZHOU ,  Wenbo SONG ,  Xinyang LI ,  Xiaofan ZHANG ,  Jie LIN ,  Dongbing LIU ,  Junhui ZHANG ,  Hongtao WANG ,  Shijun ZHANG ,  Yuanning GU ,  Jingyan AN ,  Hui ZHAO ,  Tingjie HUANG ,  Dong MA ,  Ruen WANG ,  Shiyuan XU ,  Jie FU

IPC分类号： C08F4/70 ,  C08F220/64

摘要： A method for preparing an olefin-olefinic alcohol copolymer and an olefin-olefinic alcohol copolymer prepared by the method are provided. The catalyst used in the method for preparing the olefin-olefinic alcohol copolymer has a diimine metal complex as shown in Formula I.

公开(公告)号：US20220251016A1

公开(公告)日：2022-08-11

申请号：US17629300

申请日：2020-07-24

申请人： CHINA PETROLUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Jie LIN ,  Xiaofan ZHANG ,  Ting HUANG ,  Junhui ZHANG ,  Junling ZHOU ,  Zhufang SUN ,  Xianzhi XIA ,  Hui ZHAO ,  Zifang GUO ,  Jin ZHAO ,  Haitao LIU ,  Meiyan FU ,  Jigui ZHANG ,  Lin QI ,  Lian YAN ,  Wei CEN ,  Yu WANG

IPC分类号： C07C47/575 ,  C08F110/06 ,  C07C43/21

摘要： A catalyst system for olefin polymerization contains a main catalyst and a cocatalyst. The cocatalyst contains a twelve-membered ring compound represented by formula (M). The catalyst system is suitable for preparing polypropylene products having high stereoregularity and low ash, and can regulate the melt index of the products within a wide range by adjusting the amount of hydrogenation. It is also suitable for copolymerization systems to improve the copolymerization yield.