公开(公告)号：US20240246052A1

公开(公告)日：2024-07-25

申请号：US18566128

申请日：2022-06-23

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

发明人： Hongyuan ZONG ,  Guozhen QI ,  Pan GAO ,  Xiaohong LI ,  Jing CAO ,  Zhinan YU ,  Yanxue WANG ,  Fei PENG

IPC分类号： B01J8/18 ,  B01J8/00 ,  B01J8/26 ,  C07C1/24

CPC分类号： B01J8/1827 ,  B01J8/0055 ,  B01J8/1863 ,  B01J8/26 ,  C07C1/24 ,  B01J2208/00752 ,  B01J2208/00849 ,  B01J2208/00902 ,  B01J2208/00938 ,  C07C2529/40

摘要： A fluidized bed reactor, a device for preparing low-carbon olefin, and a method for preparing low-carbon olefin are provided. The reaction zone of the fluidized bed reactor is sequentially, from bottom to top, provided with a raw material first distributor, a raw material second distributor and a catalyst distributor; the catalyst distributor is connected with the catalyst second feeding inlet; a dense-phase zone is formed between the raw material first distributor and the raw material second distributor, and the area where the catalyst distributor is located is formed as a catalyst distribution zone connected with the dense-phase zone; and at least one catalyst first feeding inlet(s) is provided on the side wall of reactor of the dense-phase zone. The distribution of the catalyst and the full contact of the catalyst with the raw materials can be achieved using the fluidized bed reactor and the device.

公开(公告)号：US20130178681A1

公开(公告)日：2013-07-11

申请号：US13736892

申请日：2013-01-08

申请人： China Petroleum & Chemical Corporation ,  Shanghai Research Institute Of Petrochemical Technology, SINOPEC

发明人： Guozhen QI ,  Siqing ZHONG ,  Zhinan YU ,  Yongming JIN

IPC分类号： B01J8/00

CPC分类号： B01J8/008 ,  B01J8/1872 ,  B01J8/26

摘要： The invention provides a start-up method for a reaction-regeneration unit for preparing light olefins from methanol, which comprises: (a) heating a regenerator with an auxiliary combustion chamber and a reactor with a start-up furnace; (b) charging a catalyst into the regenerator and reactor; (c) closing a spent catalyst slide valve and a regenerated catalyst slide valve after the reactor reaches about 350° C. or more; (d) feeding methanol to the reactor after the dense phase stage of the regenerator reaches about 350° C. or more; (e) opening the spent catalyst slide valve and introducing a carbon deposited catalyst from the reactor to the regenerator after the dense phase stage reaches about 400° C. or more and the average amount of carbon deposits on the catalyst in the reactor reaches about 2.5% or more; (f) raising the regenerator to above about 580° C.; and (g) stopping the start-up furnace and auxiliary combustion chamber.

摘要翻译： 本发明提供了一种用于从甲醇制备轻质烯烃的反应 - 再生单元的启动方法，其包括：（a）用辅助燃烧室加热再生器和具有启动炉的反应器; （b）将催化剂装入再生器和反应器; （c）在反应器达到约350℃或更高之后关闭废催化剂滑阀和再生催化剂滑阀; （d）在再生器的致密相达到约350℃以上之后，将甲醇进料到反应器中; （e）在致密相达到约400℃或更高之后，打开废催化剂滑阀并将碳沉积催化剂从反应器引入再生器，并且反应器中催化剂上的平均碳沉积量达到约2.5 ％ 或者更多; （f）将再生器升高至约580℃以上; 和（g）停止起动炉和辅助燃烧室。

公开(公告)号：US20230348340A1

公开(公告)日：2023-11-02

申请号：US18245381

申请日：2021-09-15

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

发明人： Hongyuan ZONG ,  Xiaohong LI ,  Guozhen QI ,  Hongtao WANG ,  Zhinan YU ,  Yijun ZHENG ,  Li WANG

IPC分类号： C07C1/22 ,  B01J29/85 ,  B01J29/90 ,  B01J38/02 ,  B01J8/26 ,  B01J8/18 ,  B01J8/00

CPC分类号： C07C1/22 ,  B01J29/85 ,  B01J29/90 ,  B01J38/02 ,  B01J8/26 ,  B01J8/1827 ,  B01J8/007 ,  B01J8/1863 ,  C07C2529/85

摘要： A device for mixing at least two granular materials has a first lifting tube used for loading first particles and a second lifting tube surrounding and coaxial to the first lifting tube and used for loading second particles. The upper part of said first lifting tube extends beyond the top of said second lifting tube, and at least part of the upper part of the first lifting tube and at least part of the upper part of the second lift tube are located inside a fast bed precipitator, allowing the first and second particles to be transported by means of the first and second lifting tubes to the interior of said fast bed precipitator and mixed.

公开(公告)号：US20160102033A1

公开(公告)日：2016-04-14

申请号：US14881620

申请日：2015-10-13

申请人： China Petroleum & Chemical Corporation ,  Shanghai Research Institute of Petrochemical Technology SINOPEC

发明人： Weimin YANG ,  Xiaohong LI ,  Siqing ZHONG ,  Guozhen QI ,  Jun XU ,  Zhinan YU

IPC分类号： C07C1/20 ,  B01J8/00 ,  B01J8/24

CPC分类号： B01J8/0015 ,  B01J8/0055 ,  B01J8/26 ,  B01J2208/00752 ,  B01J2208/00938 ,  B01J2208/00991 ,  C07C1/20 ,  C07C2529/40 ,  C07C2529/85 ,  C10G11/182 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06

摘要： A fluidized bed reactor is provided, comprising an inlet zone at a lower position, an outlet zone at an upper position, and a reaction zone between the inlet zone and the outlet zone. A guide plate with through holes is disposed in the reaction zone, comprising a dense channel region in an intermediate region thereof and a sparse channel region disposed on a periphery thereof and encompassing the dense channel region. Catalysts in said fluidized bed reactor can be homogeneously distributed in the reaction zone thereof, whereby the reaction efficiency can be improved. A reaction regeneration apparatus comprising said fluidized bed reactor, and a process for preparing olefins from oxygenates and a process for preparing aromatic hydrocarbons from oxygenates using the reaction regeneration apparatus.

摘要翻译： 提供了流化床反应器，其包括位于下部位置的入口区域，在上部位置处的出口区域以及入口区域和出口区域之间的反应区域。 具有通孔的引导板设置在反应区中，包括在其中间区域中的密集沟道区域和设置在其周边上并且包围密集沟道区域的稀疏沟道区域。 所述流化床反应器中的催化剂可以均匀地分布在其反应区中，从而可提高反应效率。 包括所述流化床反应器的反应再生装置，以及由含氧化合物制备烯烃的方法和使用反应再生装置从含氧化合物制备芳烃的方法。

公开(公告)号：US20230139652A1

公开(公告)日：2023-05-04

申请号：US17912271

申请日：2020-09-16

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

发明人： Hongyuan ZONG ,  Guozhen QI ,  Jing CAO ,  Xiaohong LI ,  Zhinan YU ,  Li WANG

IPC分类号： B01J8/18 ,  C07C1/24 ,  B01J35/00 ,  B01J8/34 ,  B01J29/85

摘要： The invention relates to a method for regulating the gas velocity of the empty bed in a fluidized bed, wherein solid catalysts are used as fluidized particles or as a part of fluidized particles, characterized in that the gas velocity of the empty bed μ of the reaction zone of the fluidized bed is measured, compared with the bed average catalyst density ρ of the solid catalysts in the reaction zone of the fluidized bed, the gas velocity of the empty bed μ being adjusted as required such that the gas velocity of the empty bed μ and the bed average catalyst density ρ satisfy the formula (I) below: ρ=0.356μ3−4.319μ2−35.57μ+M; wherein M=250−; where μ is provided in m/s and ρ is provided in kg/m3. The method can be used for the industrial production of lower olefin.

公开(公告)号：US20230137544A1

公开(公告)日：2023-05-04

申请号：US17906487

申请日：2021-03-12

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

发明人： Hongyuan ZONG ,  Guozhen QI ,  Jing CAO ,  Hongtao WANG ,  Zhinan YU ,  Yijun ZHENG

IPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J38/06 ,  B01J8/26 ,  B01J8/18

摘要： The present invention relates to a process of converting methanol to olefins, comprising: feeding a feedstock comprising methanol to a fluidized bed reactor to contact with catalysts to produce an olefin product, wherein the process at least partially deactivates the catalysts to format least partially deactivated catalysts; feeding spent catalysts from the at least partially deactivated catalysts to a regenerator for regeneration, thereby forming regenerated catalysts, and returning the activated catalysts from the regenerated catalysts to the reactor via a regenerated catalyst line; characterized in that on the regenerated catalyst line, the oxygen content by volume in the gas phase component at the outlet of the regenerated catalyst line is controlled to be less than 0.1%, preferably less than 0.05%, and more preferably less than 0.01%.

公开(公告)号：US20160101396A1

公开(公告)日：2016-04-14

申请号：US14881605

申请日：2015-10-13

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  Shanghai Research Institute of Petrochemical Technology, SINOPEC

发明人： Jun XU ,  Songyuan GU ,  Siqing ZHONG ,  Yongming JIN ,  Zhinan YU ,  Guozhen QI ,  Xiaohong LI

IPC分类号： B01J8/24 ,  B04C5/26 ,  B04C9/00 ,  C07C1/20

CPC分类号： B01J8/0015 ,  B01J8/0055 ,  B01J8/26 ,  B01J2208/00752 ,  B01J2208/00938 ,  B01J2208/00991 ,  C07C1/20 ,  C07C2529/40 ,  C07C2529/85 ,  C10G11/182 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06

摘要： Device for use in a fluidized bed reactor includes a gas-solid separator communicated with an outlet of the fluidized bed reactor; a vertically arranged damper, a solid outlet of the gas-solid separator communicated with a lower region of the damper, a gas outlet of the gas-solid separator communicated with an upper region of the damper; a fine gas-solid separator, an inlet of the fine gas-solid separator communicated with the upper region of the damper, and a solid outlet of the fine gas-solid separator communicated with the lower region of the damper. Product from the fluidized bed reactor is fed into the preliminary gas-solid separator, most solid catalysts separated and fed into the lower region; the product entraining the rest catalysts is fed into the upper region, and into the fine gas-solid separator, the rest catalysts fed into the lower region; and final product is obtained from the fine gas-solid separator.

摘要翻译： 用于流化床反应器的装置包括与流化床反应器的出口连通的气固分离器; 垂直排列的阻尼器，与阻尼器的下部区域连通的气体 - 固体分离器的固体出口，与阻尼器的上部区域连通的气体 - 固体分离器的气体出口; 细气固分离器，与阻尼器的上部区域连通的细气固分离器的入口和与阻尼器的下部区域连通的细气固分离器的固体出口。 将来自流化床反应器的产物进料到预备气固分离器中，大部分固体催化剂分离并进料到下部区域; 进料剩余催化剂的产品进料到上部区域，并进入精细的气固分离器，剩余的催化剂进料到下部区域; 并从精细气固分离器获得最终产物。