WHEREIN W is chlorine, bromine, cyano, lower alkyl, lower alkoxy carbonyl, phenoxycarbonyl, lower alkythio, phenylthio, lower alkyl sulfonyl or a grouping of the formula WHEREIN Z is -CO-or -SO2- and R1 and R2 are each independently hydrogen or lower alkyl, Y'' is lower alkylene, -CH2CH2OCH2CH2- or -CH2CH2CH2-O-CH2CH2CH2, X is a direct bond, -O-, -S-, -NH-, -COHN- or -SO2NH-, R'''' is lower alkyl, cyclohexyl, phenyl or phenyl substituted by chlorine, lower alkyl or lower alkoxy, or bromine, THE NUCLEUS B is either unsubstituted or is further monosubstituted by chlorine, lower alkyl or lower alkoxy, E is NH2, OH or NHT, and T is lower alkyl, cyclohexyl, phenyl, lower alkyl phenyl or phenoxyphenyl.
DIFFICULTLY WATER-SOLUBLE ANTHRAQUINONE DYESTUFFS FREE FROM WATER-SOLUBILIZATING GROUPS WHICH DISSOCIATE ACID IN WATER OF THE FORMULA WHEREIN V1 REPRESENTS HYDROXYL OR --NH2, V2'' REPRESENTS HYDROGEN, HYDROXYL, PHENYLAMINO OR PHENYLAMINO RING-SUBSTITUTED BY ONE SUBSTITUTED SELECTED FROM CHLORINE AND C1-C4 ALKOXY OR BY ONE TO THREE C1-C4ALKYL, X2 REPRESENTS OXYGEN,SULPHUR, --CO--O--, --CONH--, --SO2--O--, --SO2NH-- OR --O--ALKYLENE--O--, WHEREIN THE ALKYLENE MOIETY HAS AT MOST 4 CARBON ATOMS, Y'' IS AN ALIPHATIC, AROMATICOR HETEROCYCLIC BRIDGE, AND R" IS ALKYL, CYCLOHEXYL OR ARYL; THESE DYESTUFFS BEING SUITED PARTICULARLY FOR THE DYEING OF SYNTHERIC ORGANIC FIBERS, ESPECIALLYPOLYETHYLENE GLYCOL TEREPTHALATE FIBERS, AFFORDING DYEINGS ON THESE FIBERS WHICH HAVE GOOD FASTENESS PROPERTIES AND ESPECIALLY FOOD FASTENESS TO LIGHT AND SUBLIMATION.
摘要:
DIFFICULTLY WATER-SOLUBLE ANTHRAQUINONE DYESTUFFS, FREE FROM WATER-SOLUBILIZING GROUPS WHICH DISSOCIATE ACID IN WATER OF THE FORMULA WHERIN V1 REPRESENTS HYDROXYL OR -NH2, V2 REPRESENTS HYDROGEN, HYDROXYL, -NH2, LOWER AKYLAMINO, CYCLOHEXYLAMINO, PHENYLAMINO, PHENOXYPHENYLAMINO, PHENYLAZOPHENYLAMINO OR PHENYLAMINO RING-SUBSTITUTED BY CHLORINE LOWER ALKYL OR LOWER ALKOXY, X IS OXYGEN OR SULFUR, Y IS C1-C4-ALKYLENE OR
AND R REPRESENTS AN OPTIONALLY SUBSTITUTED ALIPHATIC CYCLOALIPHATIC OR AROMATIC RADICAL; THESE DYESTUFFS BEING SUITED PARTICULARLY FOR THE DYEING OF SYNTHETIC ORGANIC FIBERS, ESPECIALLY POLYETHYLENE GLYCOL TEREPHTHALATE FIBERS, AFFORDING DYEINGS ON THESE FIBERS WHICH HAVE GOOD FASTNESS PROPERTIES AND ESPECIALLY GOOD FASTNESS TO LIGHT AND SUBLIMATION.
摘要:
WHEREIN X1 and X2 each represents a hydrogen atom or a hydroxy group, Y1 and Y2 each represents a hydrogen or halogen atom or a sulphonic acid group, A1 and A2 each represents an n-alkyl radical with 1 to 3 carbon atoms or represents a hydrogen atom, B1 B2 each represents a sulphonic acid or carboxy radical, Z1 and Z2 each represents a fiber-reactive acyl radical, V1 V2 each represents a hydrogen atom or an alkyl or alkoxy radical, and n and m is each indenpendently 1 or 2 are excellent dyes and are suitable for dyeing and printing materials of the most diverse kind.
摘要:
1. A PROCESS FOR THE PRODUCTION OF ACID ANTHRAQUINONE DYESTUFF, COMPRISING THE STEPS OF REACTING AN ANTHRAQUINONE COMPOUND OF FORMULA II 1-(H2N-),2-(M(+).(-)O3S-),4-Y-ANTHRAQUINONE WHEREIN M+ REPRESENTS THE SODIUM OR POTASSIUM CATION, AND Y REPRESENTS HALOGEN, WITH AN ANMINE OF FORMULA III 3,4-DI(CH3-),5-(R1-N(-R2)-SO2-)ANILINE WHEREIN R1 REPRESENTS A SUBSTITUENT SELECTED FROM METHYL, ETHYL, PROPYL, B-HYDROXYETHYL, Y:HYDROXYPROPYL, Y-METHOXYPROPYL, B-HYDROXYETHOXYETHYL AND B-METHOXYETHOXYETHYL, AND R2 REPRESENTS HYDROGEN OR A SUBSTITUENT SELECTED FROM METHYL, ETHYL, PROPYL AND B-HYDROXYETHYL, AT A TEMPERATURE IN THE RANGE OF FROM 70 TO 85*C IN AN AQUEOUS REACTION MEDIUM HAVING A PH OF AT LEAST 5 AND IN THE PRESENCE THEREIN OF AN ACID BINDING AGENT AND COPPER POWDER OR COPPER SULFATE OR A MIXTURE THEREOF, AND RECOVERING FROM THE REACTION MIXTURE THE CORRESPONDING DYESTUFF OF FORMULA I 1-(H2N-),2-(M(+).(-)O3S-),4-((3,4-DI(CH3-), 5-(R1-N(-R2)-SO2-)PHENYL)-NH-)ANTHRAQUINONE WHEREIN M+, R1 AND R2 HAVE THE AFORESAID MEANINGS.
摘要:
DIFFICULTY WATER-SOLUBLE ANTHRAQUINONE DYESTUFFS FREE FROM WATER-SOLUBILIZING GROUPS WHICH DISSOCIATE ACID IN WATER BEARING IN AT LEAST ONE B-POSITION, EITHER DIRECTLY OR BY WAY OF A BRIDGING MEMBER, THE GROUPING -Y-O-COOR, WHEREIN Y REPRESENTS AN ALKYLENE GROUP, OPTIONALLY SUBSTITUTED BY A HYDROXYL GROUP AND R REPRESENTS AN OPTIONALLY SUBSTITUTED ALIPHATIC, CYCLOALIPHATIC OR AROMATIC RADICAL; THESE DYESTUFFS BEING SUITED PARTICULARLY FOR THE DYEING OF OF SYNTHETIC ORGANIC FIBERS, ESPECIALLY POLYETHYLENE GLYCOL TEREPHTHALATE FIBERS, AFFORDING DYEEINGS ON THESE FIBERS WHICH HAVE GOOD FASTNESS PROPERTIES AND ESPECIALLY GOOD FASTNESS TO LIGHT AND SUBLIMATION.
摘要:
A PROCESS FOR PRODUCING 1-AMINO-4-(4'',5''-DI-LOWER ALKYL-3-SULPHAMOYL-PHENYL)-AMINO ANTHRAQUINONES IS DESCRIBED WHICH AFFORDS VERY HIGH YIELDS OF THESE NOVEL DYESTUFFS FREE FROM BY-PRODUCTS AND INVOLVES THE REACTION OF A 1-AMINO-4 - HALOGENO-ANTHRAQUINONE WITH A 1 - AMINO-4,5DIALKYL-3-SULPHAMOYL-BENZENE. THE NOVEL ANTHRAQUINONES WHICH PREFERABLY BEAR A SULPHONIC ACID GROUP IN 2-POSITION AT THE ANTHRAQUINONE NUCLEUS ARE PRACTICALLY FREE FROM ISOMERS HAVING A SULPHAMOYL GROUP IN 2- OR 6-POSITION AT THE 4,5-DIALKYLPHENYLAMINO MOIETY, AND DYE NATURAL AND SYNTHETIC POLYAMIDE FIBERS IN LEVEL VIVID, PURE BLUE SHADES OF GOOD FASTNESS PROPERTIES, ESPECIALLY FASTNESS TO LIGHT; THE BRILLIANCE OF THE SHADE DOES NOT SUFFER EVEN WHEN OBSERVED UNDER ARTIFICIAL LIGHT.
摘要:
DIFFICULTY WATER-SOLUBLE ANTHRAQUINONE DYESTUFFS FREE FROM WATER-SOLUBILIZING GROUPS WHICH DISSOCIATE ACID OF THE FORMULA
1-V1,2-(R-O-CO-O-CH2-),4-V2-ANTHRAQUINONE
WHEREIN V1 IS HYDROXY OR - NH2,V2 IS HYDROXYL, PHENYLAMINO OR SUBSTITUTED PHENYLAMINO, R IS LOWER ALKYL, PHENYL OR SUBSTITUTED PHENYL: THESE DYESTUFFS BEING SUITED PARTICULARLY FOR THE DYEING OF SYNTHETIC ORGANIC FIBERS, ESPECAILLY POLYETHYLENE GLYCOL TEREPHTHALATE FIBERS, AFFORDING DYEINGS ON THESE FIBERS WHICH HAVE GOOD FASTNESS PROPERTIES AND ESPECIALLY GOOD FASTNESS TO LIGHT AND SUBLIMATION.
WHEREIN X IS -SO2-NH-, -SO2-O-, -SO2- AND -S-, R IS C1-C5-ALKYL, CYCLOHEXYL, PHEENYL OR PHENYL SUBSTITUTED BY CHLORINE, BROMINE, C1-C4-ALKYL OR C1-C4ALKOXY, Y IS C1-C4-ALKYLENE, -CH2CH2-O-CH2CH2-, OR -CH2CH2CH2-O-CH2CH2CH2- AND B MAY BE SUBSTITUTED BY CHLORINE BROMINE, C1-C2-ALKYL OR C1-C2ALKOXY. THE DYESTUFFS ARE SUITED FOR DYING SYNTHETIC ORGANIC FIBERS, ESPECIALLY POLYESTER FIBERS, IN FAST BLUE SHADES OF GOOD FASTNESS.