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1.
公开(公告)号:US20190309282A1
公开(公告)日:2019-10-10
申请号:US16424584
申请日:2019-05-29
申请人: Cornell University
IPC分类号: C12N11/14 , C02F3/34 , C12P17/18 , C12N9/08 , B01J35/00 , C08H7/00 , B82Y30/00 , C12N9/02 , B01J31/00
摘要: A composition comprising mesoporous aggregates of magnetic nanoparticles and free-radical producing enzyme (i.e., enzyme-bound mesoporous aggregates), wherein the mesoporous aggregates of magnetic nanoparticles have mesopores in which the free-radical-producing enzyme is embedded. Methods for synthesizing the enzyme-bound mesoporous aggregates are also described. Processes that use said enzyme-bound mesoporous aggregates for depolymerizing lignin, removing aromatic contaminants from water, and polymerizing monomers polymerizable by a free-radical reaction are also described.
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2.
公开(公告)号:US20180087043A1
公开(公告)日:2018-03-29
申请号:US15701920
申请日:2017-09-12
申请人: CORNELL UNIVERSITY
IPC分类号: C12N11/04 , A62D3/02 , C12N11/08 , B01J19/12 , B01J31/00 , B01J31/02 , B01J35/00 , B01J35/04 , C12N9/04 , C12N9/02 , B01J37/02 , C12N9/08 , C08F18/00 , C08F14/00 , C07G1/00 , C07D301/22 , C07C1/12 , C12P17/02 , C12P7/22 , C12P7/04 , C12N13/00 , C02F3/34 , C02F3/00 , C02F1/48 , C12N11/14 , B01J8/00 , B01J35/10 , C02F101/32
CPC分类号: C12N11/04 , A62D3/02 , B01J8/00 , B01J19/12 , B01J31/003 , B01J31/02 , B01J35/0033 , B01J35/04 , B01J35/1061 , B01J35/1066 , B01J37/02 , B01J2208/00805 , B01J2219/0854 , B01J2219/0862 , C02F1/484 , C02F3/00 , C02F3/342 , C02F2101/327 , C02F2209/006 , C02F2303/04 , C02F2305/08 , C07C1/12 , C07D301/22 , C07G1/00 , C08F14/00 , C08F18/00 , C12N9/0004 , C12N9/0006 , C12N9/0061 , C12N9/0065 , C12N11/08 , C12N11/14 , C12N13/00 , C12P7/04 , C12P7/22 , C12P17/02 , C12Y101/03004 , C12Y111/01 , Y02P20/588 , Y02W10/45
摘要: A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin, remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion.
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3.
公开(公告)号:US20220213464A1
公开(公告)日:2022-07-07
申请号:US17587006
申请日:2022-01-28
申请人: CORNELL UNIVERSITY
IPC分类号: C12N11/04 , A62D3/02 , B01J19/12 , B01J35/04 , B01J37/02 , C02F1/48 , C02F3/00 , C02F3/34 , C07C1/12 , C07G1/00 , C08F14/00 , C08F18/00 , C07D301/22 , C12N11/14 , C12P7/22 , C12N9/02 , C12N9/04 , C12N9/08 , C12N13/00 , C12P7/04 , C12P17/02 , B01J31/00 , B01J35/00 , C12N11/098 , C12N11/091 , C12N11/08 , B01J31/02 , B01J8/00
摘要: A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin, remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion.
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公开(公告)号:US20210047630A1
公开(公告)日:2021-02-18
申请号:US17005962
申请日:2020-08-28
申请人: CORNELL UNIVERSITY
IPC分类号: C12N11/04 , A62D3/02 , B01J19/12 , B01J35/04 , B01J37/02 , C02F1/48 , C02F3/00 , C02F3/34 , C07C1/12 , C07G1/00 , C08F14/00 , C08F18/00 , C07D301/22 , C12N11/14 , C12P7/22 , C12N9/02 , C12N9/04 , C12N9/08 , C12N13/00 , C12P7/04 , C12P17/02 , B01J31/00 , B01J35/00 , B01J31/02 , B01J8/00 , C12N11/08
摘要: A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin, remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion.
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5.
公开(公告)号:US20200002698A1
公开(公告)日:2020-01-02
申请号:US16454714
申请日:2019-06-27
申请人: CORNELL UNIVERSITY
IPC分类号: C12N11/04 , A62D3/02 , B01J19/12 , B01J35/04 , B01J37/02 , C02F1/48 , C02F3/00 , C02F3/34 , C07C1/12 , C07G1/00 , C08F14/00 , C08F18/00 , C07D301/22 , C12N11/14 , C12P7/22 , C12N9/02 , C12N9/04 , C12N9/08 , C12N13/00 , C12P7/04 , C12P17/02 , B01J31/00 , B01J35/00 , B01J31/02 , B01J8/00 , C12N11/08
摘要: A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion.
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6.
公开(公告)号:US20170175101A1
公开(公告)日:2017-06-22
申请号:US15450660
申请日:2017-03-06
申请人: Cornell University
CPC分类号: C12N11/14 , B01J31/003 , B01J35/0033 , B82Y30/00 , C02F3/342 , C02F2305/08 , C08H6/00 , C12N9/0004 , C12N9/0065 , C12P17/181 , C12P2201/00 , C12Y111/01007 , C12Y111/01013 , C12Y111/01014 , C12Y111/01016 , Y02P20/52
摘要: A composition comprising mesoporous aggregates of magnetic nanoparticles and free-radical producing enzyme (i.e., enzyme-bound mesoporous aggregates), wherein the mesoporous aggregates of magnetic nanoparticles have mesopores in which the free-radical-producing enzyme is embedded. Methods for synthesizing the enzyme-bound mesoporous aggregates are also described. Processes that use said enzyme-bound mesoporous aggregates for depolymerizing lignin, removing aromatic contaminants from water, and polymerizing monomers polymerizable by a free-radical reaction are also described.
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7.
公开(公告)号:US20170096658A1
公开(公告)日:2017-04-06
申请号:US15380104
申请日:2016-12-15
申请人: Cornell University
CPC分类号: C12N11/14 , B01J31/003 , B01J35/0033 , B82Y30/00 , C02F3/342 , C02F2305/08 , C08H6/00 , C12N9/0004 , C12N9/0065 , C12P17/181 , C12P2201/00 , C12Y111/01007 , C12Y111/01013 , C12Y111/01014 , C12Y111/01016 , Y02P20/52
摘要: A composition comprising mesoporous aggregates of magnetic nanoparticles and free-radical producing enzyme (i.e., enzyme-bound mesoporous aggregates), wherein the mesoporous aggregates of magnetic nanoparticles have mesopores in which the free-radical-producing enzyme is embedded. Methods for synthesizing the enzyme-bound mesoporous aggregates are also described. Processes that use said enzyme-bound mesoporous aggregates for depolymerizing lignin, removing aromatic contaminants from water, and polymerizing monomers polymerizable by a free-radical reaction are also described.
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