摘要:
A compound of formula (I): wherein M is a transition metal; Ar1 is a 5 or 6 membered heteroaryl ring or a polycyclic heteroaromatic group; Ar2 is a polycyclic group comprising two or more rings selected from aromatic and heteroaromatic rings; Ar1 and Ar2 may be linked by a direct bond or divalent linking group; L is a ligand; x is at least 1; a, b and y are each 0 or a positive integer; R1, R2 and R3 are each independently a substituent; and (i) Ar1 is a polycyclic heteroaromatic group; or (ii) Ar1 is a 5 or 6 membered heteroaryl ring and Ar2 is a polycyclic group comprising at least 3 rings selected from aromatic and heteroaromatic rings. The compound may be used as an infra-red emitting material of an organic light-emitting device.
摘要:
A light-emitting polymer comprising a light-emitting repeat unit in a backbone of the polymer, wherein the polymer has an anisotropy of no more than 0.8 and wherein a transition dipole moment of the light-emitting repeat unit is aligned with the polymer backbone.
摘要:
A polymer comprising a repeat unit of formula (I): wherein R1 in each occurrence is independently H or a substituent; R2 in each occurrence is independently a substituent; and x is 0, 1, 2 or 3. The polymer may be used as a light-emitting polymer in an organic light-emitting device.
摘要:
A white light emitting device having an anode and a cathode and therebetween an organic electroluminescent layer which emits white light on the provision of a current between the anode and the cathode, said organic electroluminescent layer including a plurality of electroluminescent zones in laterally separated arrangement, the first of said electroluminescent zones including a first polymer and the second of said electroluminescent zones including a second polymer, wherein the first polymer includes a fluorescent blue light emitting species and the second polymer includes a fluorescent green light emitting species, said first and/or second zones further including a phosphorescent red light emitting species, such that together with the blue emitting species results in the emission of white light, said first and second polymers being physically incompatible so that separation of the zones pertains.
摘要:
A light-emitting polymer comprising a light-emitting repeat unit in a backbone of the polymer, wherein the polymer has an anisotropy of no more than 0.8 and wherein a transition dipole moment of the light-emitting repeat unit is aligned with the polymer backbone.
摘要:
Polymer and Organic Light Emitting Device A polymer comprising a repeat unit of formula (I a), (I b) or (Ic): (Formulae (Ia), (Ib), (Ic)) wherein M is a metal; R is a backbone repeat group; n is 1 or 2; Sp is a spacer group; w is 0 or 1; L1 and L2 are mono- or bidentate co-coordinating groups; ---- represents a second metal to ligand bond in the case where L1 or L2 is a bidentate ligand and at least one of L1 and L2 is substituted with group of formula (II) (Formula (II)) wherein m is 0 or 1; each Ar1, Ar2 and Ar3 is aryl or heteroaryl. The polymer may be used as an emissive material in an organic light-emitting device.
摘要:
A composition suitable for use in an organic light-emitting layer (103) of an organic light-emitting device having an anode (101) and a cathode (105), the composition comprising a fluorescent light-emitting material, a first triplet-accepting material and a second triplet-accepting material that is different from the first triplet-accepting material. The fluorescent light-emitting material may be a repeat unit of a light-emitting polymer, and the first and second triplet-accepting materials may independently be repeat units of the light-emitting polymer or may be mixed with the fluorescent light-emitting material.
摘要:
Light-Emitting Compound A composition comprising a light-emitting compound having a peak wavelength of at least 650 nm and a material comprising a group of formula (I): wherein Ar1, Ar2 and Ar3 in each occurrence are independently selected from a C6-20 aromatic group and a 6-20 membered heteroaromatic group of C and N ring atoms and at least one of Ar1, Ar2 and Ar3 is a 6-20 membered heteroaromatic group of C and N ring atoms; x, y and z are each independently at least 1; n, m and p are each independently 0 or a positive integer; and R1, R2 and R3 in each occurrence is independently a substituent or a single bond to a polymer chain, wherein the group of formula (I) has no more than 3 single bonds to a polymer chain. The composition may be used in the light-emitting layer of an infrared organic light-emitting device.
摘要:
A copolymer comprising a repeat unit of Formula (I) and at least one further repeat unit: Formula (I) wherein: wherein: Ar1 and Ar2 are each independently selected from aryl and heteroaryl, each of which is independently unsubstituted or substituted with one or more substituents; each R is independently a substituent; each n is independently 0, 1 or 2; each m is independently 0, 1, 2 or 3, and at least one of the repeat units of the polymer is a partially conjugating repeat unit.
摘要:
A method of forming a crosslinked polymer comprising the step of reacting a crosslinkable group in the presence of a polymer, wherein: the crosslinkable group comprises a core unit substituted with at least one crosslinkable unit of formula (I): the crosslinkable group is bound to the polymer or is a crosslinkable compound mixed with the polymer; Ar is aryl or heteroaryl which may be unsubstituted or substituted with one or more substituents independently selected from monovalent substituents and a divalent linking group linking the unit of formula (I) to the core unit; and R is independently in each occurrence H, a monovalent substituent or a divalent linking group linking the unit of formula (I) to the core unit, with the proviso that at least one R is not H.