摘要:
Disclosed is an anionic diinitiator prepared using a diisopropenyl benzene compound and an organo lithium compound having primary polymerization sites. The anionic diinitiators are prepared by admixing a diisopropenyl benzene compound with diethyl ether, ethylene, an organo lithium compound, and a solvent under reaction conditions sufficient to prepare a diinitiator having primary lithium alkyl reactive sites. The diinitiators are particularly useful in preparing block copolymers.
摘要:
Disclosed is an anionic diinitiator prepared using a diisopropenyl benzene compound and an organo lithium compound having primary polymerization sites. The anionic diinitiators are prepared by admixing a diisopropenyl benzene compound with diethyl ether, ethylene, an organo lithium compound, and a solvent under reaction conditions sufficient to prepare a diinitiator having primary lithium alkyl reactive sites. The diinitiators are particularly useful in preparing block copolymers.
摘要:
Disclosed is an anionic diinitiator prepared using a diisopropenyl benzene compound and an organo lithium compound having primary polymerization sites. The anionic diinitiators are prepared by admixing a diisopropenyl benzene compound with diethyl ether, ethylene, an organo lithium compound, and a solvent under reaction conditions sufficient to prepare a diinitiator having primary lithium alkyl reactive sites. The diinitiators are particularly useful in preparing block copolymers.
摘要:
Lithium-terminated polymers of one or more conjugated dienes and of one or more mono alkenyl arenes are coupled by reaction with an alkoxy silane coupling agent having the formula Rx—Si—(OR′)y, where x is 0 or 1, x+y=4, R and R′ are the same or different, R is selected from aryl hydrocarbon radicals, linear alkyl hydrocarbon radicals and branched alkyl hydrocarbon radicals, and R′ is selected from linear and branched alkyl hydrocarbon radicals, such that the resulting polymer composition contains less than about ten weight percent of uncoupled polymer diblock. The polymer compositions are subsequently selectively hydrogenated, and are useful in a variety of compounds and end use applications.
摘要翻译:通过与具有式Rx-Si-(OR')y的烷氧基硅烷偶联剂反应将一个或多个共轭二烯和一个或多个单链烯基芳烃的锂封端的聚合物偶联,其中x为0或1,x + y = 4,R和R'相同或不同,R选自芳基烃基,直链烷基烃基和支链烷基烃基,R'选自直链和支链烷基烃基,使得所得聚合物 组合物含有小于约10重量%的未偶联的聚合物二嵌段。 聚合物组合物随后被选择性氢化,并且可用于各种化合物和最终用途。
摘要:
Lithium-terminated polymers of one or more conjugated dienes and of one or more mono alkenyl arenes are coupled by reaction with an alkoxy silane coupling agent having the formula Rx—Si—(OR′)y, where x is 0 or 1, x+y=4, R and R′ are the same or different, R is selected from aryl hydrocarbon radicals, linear alkyl hydrocarbon radicals and branched alkyl hydrocarbon radicals, and R′ is selected from linear and branched alkyl hydrocarbon radicals, such that the resulting polymer composition contains less than about ten weight percent of uncoupled polymer diblock. The polymer compositions are subsequently selectively hydrogenated, and are useful in a variety of compounds and end use applications.
摘要翻译:一个或多个共轭二烯和一个或多个单链烯基芳烃的锂封端的聚合物通过与具有式R x -Si-(OR') 其中x为0或1,x + y = 4,R和R'相同或不同,R选自芳基烃基,直链烷基烃基和支链烷基烃基,R' 选自直链和支链烷基烃基,使得所得聚合物组合物含有小于约10重量%的未偶联聚合物二嵌段。 聚合物组合物随后被选择性氢化,并且可用于各种化合物和最终用途。
摘要:
A method for removing a tertiary halide from an olefin hydrocarbon stream which comprises contacting the hydrocarbon stream with activated alumina at a temperature of about -40.degree. to about 120.degree. C.
摘要:
A solid, cyclone-finishable polymer which does not exhibit cold flow and provides an unexpected balance of viscosity improving properties for oil compositions is produced by hydrogenating a copolymer comprising a homopolymer block of isoprene connected to a copolymer block of isoprene and a monoalkenyl aromatic hydrocarbon. The amount of the monoalkenyl aromatic hydrocarbon is sufficient to allow cyclone finishing although sufficiently distributed to provide oil compositions having good low temperature viscosity. Prior to hydrogenation, the copolymers have a number average molecular weight between 125,000 and 275,000, preferably 150,000 to 240,000, and a total monoalkenyl aromatic content between 10 and 2 percent by weight, preferably between 7 and 3 percent. The copolymer is hydrogenated to substantially saturate the isoprene and to reduce the size of monoalkenyl aromatic segments in the copolymer block.
摘要:
A solid, cyclone-finishable polymer which does not exhibit cold flow and provides an unexpected balance of viscosity improving properties for oil compositions is produced by hydrogenating a copolymer comprising a homopolymer block of isoprene connected to a copolymer block of isoprene and a monoalkenyl aromatic hydrocarbon. The amount of the monoalkenyl aromatic hydrocarbon is sufficient to allow cyclone finishing although sufficiently distributed to provide oil compositions having good low temperature viscosity. Prior to hydrogenation, the copolymers have a number average molecular weight between 125,000 and 275,000, preferably 150,000 to 240,000, and a total monoalkenyl aromatic content between 10 and 2 percent by weight, preferably between 7 and 3 percent. The copolymer is hydrogenated to substantially saturate the isoprene and to reduce the size of monoalkenyl aromatic segments in the copolymer block.
摘要:
A method for preparing asymmetric radial polymers wherein the different polymeric arms are contacted sequentially with a nonpolymerizable coupling agent. Contacting of the final step in the process, which frequently but not necessarily always will be the second step in the process, will be carried out in the presence of a polar compound suitable for increasing the amount of vinyl content in a conjugated diolefin polymer during polymerization thereof. The method used narrows the relative arm distribution of the several asymmetric radial polymers produced and significantly increases the amount of total product having the desired ratio of polymeric arms and accomplishes this objective in relatively short reaction time. Any nonpolymerizable coupling agent known in the prior art to be useful in the production of asymmetric radial polymers may be used in the method of this invention but nonpolymerizable coupling agents having from 3 to about 12 functional groups are most effective and nonpolymerizable coupling agents having 2 or 3 functional groups are most preferred. Useful polar compounds are, generally, selected from the group consisting of ethers, tertiary amines, pyridine and pyrolidene compounds.
摘要:
The present invention includes star polymers which can be used as viscosity index improvers in oil compositions formulated for high performance engines. The star polymers have copolymer arms of hydrogenated polyisoprene and polystyrene with sufficient amounts of polystyrene to be finishable as a polymer crumb.