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    Method for the prodution of monomers useful in the manufacture of semiconductive polymers
    5.
    发明申请
    Method for the prodution of monomers useful in the manufacture of semiconductive polymers 有权
    用于生产半导体聚合物的单体的生产方法

    公开(公告)号：US20050240011A1

    公开(公告)日：2005-10-27

    申请号：US10532835

    申请日：2003-10-29

    申请人： Paul Wallace ,  Carl Towns ,  Thomas Pounds

    发明人： Paul Wallace ,  Carl Towns ,  Thomas Pounds

    IPC分类号： C07C13/00 ,  C07F5/02 ,  C09K11/00 ,  A61K39/395 ,  C07K16/18

    CPC分类号： C07F5/025

    摘要： The instant invention relates to a new method for the synthesis of monomers and their use inter alia in the manufacture of semiconductive polymers. Monomers, in particular, asymmetric monomers, such as asymmetric fluorene compounds, are valuable material in the manufacture of semiconductive polymers. The know methods for producing asymmetric monomers, such as asymmetric fluorene compounds, are expensive due to the formation of by-products. The method according to the present invention avoids the formation of such by-products and is described in more detail in claims 1 to 14.

    摘要翻译： 本发明涉及用于合成单体的新方法及其在半导体聚合物的制造中的用途。 单体，特别是不对称单体，例如不对称芴化合物，在半导体聚合物的制造中是有价值的材料。 用于生产不对称单体（例如不对称芴化合物）的已知方法由于副产物的形成而是昂贵的。 根据本发明的方法避免了这种副产物的形成，并且在权利要求1至14中更详细地描述。

    Method for the production of monomers useful in the manufacture of semiconductive polymers
    6.
    发明授权
    Method for the production of monomers useful in the manufacture of semiconductive polymers 有权
    用于生产用于制备半导体聚合物的单体的方法

    公开(公告)号：US07368616B2

    公开(公告)日：2008-05-06

    申请号：US10532835

    申请日：2003-10-29

    申请人： Paul Wallace ,  Carl Towns ,  Thomas Pounds

    发明人： Paul Wallace ,  Carl Towns ,  Thomas Pounds

    IPC分类号： C07C13/465

    CPC分类号： C07F5/025

    摘要： The instant invention relates to a new method for the synthesis of monomers and their use inter alia in the manufacture of semiconductive polymers. Monomers, in particular, asymmetric monomers, such as asymmetric fluorene compounds, are valuable material in the manufacture of semiconductive polymers. The know methods for producing asymmetric monomers, such as asymmetric fluorene compounds, are expensive due to the formation of by-products.The method according to the present invention avoids the formation of such by-products and is described in more detail in claims 1 to 14.

    摘要翻译： 本发明涉及用于合成单体的新方法及其在半导体聚合物的制造中的用途。 单体，特别是不对称单体，例如不对称芴化合物，在半导体聚合物的制造中是有价值的材料。 用于生产不对称单体（例如不对称芴化合物）的已知方法由于副产物的形成而是昂贵的。 根据本发明的方法避免了这种副产物的形成，并且在权利要求1至14中更详细地描述。

    Monomer, polymerization method, and polymer
    9.
    发明授权
    Monomer, polymerization method, and polymer 有权
    单体，聚合方法和聚合物

    公开(公告)号：US08916677B2

    公开(公告)日：2014-12-23

    申请号：US13258910

    申请日：2010-04-15

    申请人： Mary McKiernan ,  Thomas Pounds

    发明人： Mary McKiernan ,  Thomas Pounds

    IPC分类号： C08G59/24 ,  C08G61/12 ,  C07D265/38 ,  H01L51/00 ,  C09K11/06 ,  C08G59/00 ,  H01L51/50

    CPC分类号： C08G61/122 ,  C07D265/38 ,  C08G61/12 ,  C08G2261/3162 ,  C08G2261/3245 ,  C08G2261/364 ,  C08G2261/5222 ,  C09K11/06 ,  C09K2211/1466 ,  C09K2211/1475 ,  C09K2211/1483 ,  H01L51/0035 ,  H01L51/5012

    摘要： A monomer of formula (III): wherein X is a polymerisable group Ar, Ar1 and Ar2 each independently represent an optionally substituted aryl or heteroaryl group; R1 represents H or a substituent; and Z represents a direct bond or a divalent linking atom or group, wherein Ar1 and Ar2 are linked by a single bond or a divalent linking group selected from CR1R2, SiR1R2, PR1, NR1, O and S wherein R1 and R2 are independently selected from hydrogen; optionally substituted alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, N, C═O and —COO—; alkoxy, aryl, arylalkyl, heteroaryl and heteroarylalkyl. Ar1 and Ar2 are preferably linked by an oxygen atom, and Ar1 and/or Ar2 may be fused to their respective adjacent Ar groups. Ar1 and its adjacent Ar group and/or Ar2 and its adjacent Ar group are optionally fused to form a fluorene unit.

    摘要翻译： 式（III）的单体：其中X是可聚合基团Ar，Ar 1和Ar 2各自独立地表示任选取代的芳基或杂芳基; R1表示H或取代基; Z表示直接键或二价连接原子或基团，其中Ar 1和Ar 2通过单键或选自CR 1 R 2，SiR 1 R 2，PR 1，NR 1，O和S的二价连接基团连接，其中R 1和R 2独立地选自 氢; 任选取代的烷基，其中一个或多个不相邻的C原子可被O，S，N，C = O和-COO-取代; 烷氧基，芳基，芳基烷基，杂芳基和杂芳基烷基。 Ar 1和Ar 2优选通过氧原子连接，并且Ar 1和/或Ar 2可以与它们各自相邻的Ar基团稠合。 Ar1及其相邻的Ar基团和/或Ar 2及其相邻的Ar基团任选地稠合形成芴单元。

    Polymer and polymerization method
    10.
    发明授权
    Polymer and polymerization method 有权
    聚合物和聚合方法

    公开(公告)号：US08916675B2

    公开(公告)日：2014-12-23

    申请号：US13264143

    申请日：2010-04-15

    申请人： Mary McKiernan ,  Thomas Pounds

    发明人： Mary McKiernan ,  Thomas Pounds

    IPC分类号： C08G67/02 ,  C08G61/12 ,  H01L51/00 ,  H01L51/50

    CPC分类号： C08G61/12 ,  C08G2261/164 ,  C08G2261/3142 ,  C08G2261/3162 ,  C08G2261/411 ,  C08G2261/5222 ,  H01L51/0035 ,  H01L51/5012 ,  Y02E10/549 ,  Y10T428/12 ,  Y10T428/12528 ,  Y10T428/12556 ,  Y10T428/12771

    摘要： A method for forming a polymer comprising the polymerization of a plurality of monomers, wherein at least one of the plurality of monomers is one or both of: a charge transporting unit and a hydrocarbon monomer in which at least one carbon atom has been substituted by an atom or group with a greater quantity of unshared valence electrons than the carbon atom it has been substituted for, and wherein at least one of the plurality of monomers comprises an end-capping compound at one end of said monomer, the end-capping compound preventing polymerization at the end, wherein the end-capping compound is not charge transporting and comprises at least two rings. The end capping compound preferably consists of or includes a structural unit having the formula: (Ar)n—X, wherein Ar in each occurrence independently represents an aryl or heteroaryl group; X represents a leaving group comprising a boron derivative group or halogen; and n is 2 or more.

    摘要翻译： 一种形成聚合物的方法，其包括多个单体的聚合，其中所述多个单体中的至少一个单体是以下之一或两者：电荷输送单元和烃单体，其中至少一个碳原子被 原子或基团，其具有比其已被取代的碳原子更大量的非共价价电子，并且其中所述多个单体中的至少一个单体包含在所述单体一端的封端化合物，所述封端化合物预防 末端聚合，其中封端化合物不是电荷输送并且包含至少两个环。 封端化合物优选包含或包括具有下式的结构单元：（Ar）n -X，其中Ar各自独立地表示芳基或杂芳基; X表示包含硼衍生物基团或卤素的离去基团; n为2以上。