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公开(公告)号：US4275049A
公开(公告)日：1981-06-23
申请号：US174828
申请日：1980-08-04
申请人： Carl Voigt , Peter Kleinschmit
发明人： Carl Voigt , Peter Kleinschmit
摘要： Hydrogen cyanide in hydrogen cyanide containing gas is transformed into ammonia by a special iridium catalyst in the presence of at least the equivalent amount of hydrogen for the change.
摘要翻译： 在含有氰化氢的气体中的氰化氢在至少相当量的氢气存在下通过特殊的铱催化剂转化成氨。
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公开(公告)号：US4415485A
公开(公告)日：1983-11-15
申请号：US300298
申请日：1981-09-08
申请人： Carl Voigt , Peter Kleinschmit , Reinhard Manner
发明人： Carl Voigt , Peter Kleinschmit , Reinhard Manner
摘要： The previously carried out internal coating of contact tubes not only required very much manual labor and was very time consuming, but it was also unsatisfactory in regard to adhesion of the contact liquid to the surface and homogenity of the catalyst. By the simultaneous action of heat on the liquid interface in the tubes during the lowering of the liquid level as well as by a specially suited apparatus for this purpose which operates according to the principle of communicating tubes there is provided the possibility of a good adhesion to the surface as well as the formation of a homogeneous layer at very little operating expense.
摘要翻译： 先前进行的接触管的内部涂层不仅需要非常多的手工劳动，并且非常耗时，而且对于接触液体对表面的粘附和催化剂的均匀性也是不令人满意的。 通过在液面降低期间在管中的液体界面上的热同时作用以及根据连通管的原理的特别适合的用于该目的的设备，提供了对 表面以及以非常小的操作费用形成均匀的层。
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公开(公告)号：US4320104A
公开(公告)日：1982-03-16
申请号：US183955
申请日：1980-09-03
申请人： Friedrich Bittner , Carl Voigt , Peter Kleinschmit
发明人： Friedrich Bittner , Carl Voigt , Peter Kleinschmit
IPC分类号： C01C3/02
CPC分类号： C01C3/0233
摘要： By introducing the reaction gas mixture of hydrocarbons and ammonia at increased velocity through an inlet tube with one or more openings in a customary reaction tube in the hydrocyanic acid-methane-ammonia (BMA) process the yield of HCN is increased considerably.
摘要翻译： 通过在氢氰酸 - 甲烷 - 氨（BMA）方法的常规反应管中通过具有一个或多个开口的入口管以增加的速度引入烃和氨的反应气体混合物，HCN的产率显着增加。
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公开(公告)号：US4317808A
公开(公告)日：1982-03-02
申请号：US208026
申请日：1980-11-18
申请人： Carl Voigt , Hans Strack , Peter Kleinschmit
发明人： Carl Voigt , Hans Strack , Peter Kleinschmit
IPC分类号： C01C1/12 , B01D53/02 , B01D53/04 , C01B39/14 , C01B39/22 , C01B39/24 , C01B39/26 , C01B39/30 , C01C3/02
CPC分类号： B01D53/04 , C01C3/0233 , B01D2253/108 , B01D2257/406 , B01D2257/408 , B01D2257/7022 , B01D2259/40086 , B01D2259/402
摘要： For the reduction of the ammonia content in the product gas of the hydrocyanic acid-methane-ammonia (BMA) process and accordingly to increase the yield the reaction gas mixture of this process is brought into contact with zeolite and the ammonia thereafter desorbed from the zeolite preferably again employed in the reaction step. If the desorption is carried out with a flushing gas such as the hydrocarbon used in the reaction then this mixture can be directly supplied again to the BMA reactor. Through this procedure the amount of ammonia previously lost to the process can again be made useful in the process itself.
摘要翻译： 为了降低氢氰酸 - 甲烷 - 氨（BMA）工艺的产物气中的氨含量，并且为了提高产率，该方法的反应气体混合物与沸石接触，然后氨从沸石中脱附 优选在反应步骤中再次使用。 如果用反应中使用的烃类的冲洗气体进行解吸，则可以将该混合物再次直接供给到BMA反应器。 通过这个过程，过程中丢失的氨的量可以再次在该过程本身中有用。
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公开(公告)号：US4471712A
公开(公告)日：1984-09-18
申请号：US508133
申请日：1983-06-27
申请人： Carl Voigt , Peter Kleinschmit , Reinhard Manner
发明人： Carl Voigt , Peter Kleinschmit , Reinhard Manner
摘要： The previously carried out internal coating of contact tubes not only required very much manual labor and was very time consuming, but it was also unsatisfactory in regard to adhesion of the contact liquid to the surface and homogenity of the catalyst. By the simultaneous action of heat on the liquid interface in the tubes during the lowering of the liquid level as well as by a specially suited apparatus for this purpose which operates according to the principle of communicating tubes there is provided the possibility of a good adhesion to the surface as well as the formation of a homogeneous layer at very little operating expense.
摘要翻译： 先前进行的接触管的内部涂层不仅需要非常多的手工劳动，并且非常耗时，而且对于接触液体对表面的粘附和催化剂的均匀性也是不令人满意的。 通过在液面降低期间在管中的液体界面上的热同时作用以及根据连通管的原理的特别适合的用于该目的的设备，提供了对 表面以及以非常小的操作费用形成均匀的层。
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公开(公告)号：US4289741A
公开(公告)日：1981-09-15
申请号：US133358
申请日：1980-03-24
申请人： Carl Voigt , Peter Kleinschmit , Eberhard Walter
发明人： Carl Voigt , Peter Kleinschmit , Eberhard Walter
IPC分类号： C01C3/02
CPC分类号： C01C3/0233
摘要： The known hydrocyanic acid-methane-ammonia (BMA) process for the production of hydrogen cyanide can now be carried out with liquified gases namely through the presence of additional hydrogen at the beginning of the reaction. The atomic ratio of carbon to nitrogen and hydrogen is from 1:1:7.1 to 1:1.33:13. As additional hydrogen there is the portion of hydrogen present coming out of the reaction "hydrocarbon+NH.sub.3 ". Otherwise the reaction conditions are the same as in the known BMA process.
摘要翻译： 用于生产氰化氢的已知氢氰酸 - 甲烷 - 氨（BMA）方法现在可以用液化气体进行，即在反应开始时通过存在另外的氢气来进行。 碳与氮和氢的原子比为1:1至7.1:1.33:1。 作为另外的氢，存在从反应“烃+ NH 3”出来的部分氢。 否则反应条件与已知的BMA方法相同。
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公开(公告)号：US4387081A
公开(公告)日：1983-06-07
申请号：US304049
申请日：1981-09-21
申请人： Carl Voigt , Peter Kleinschmit , Gerd Schreyer , Gerhard Sperka
发明人： Carl Voigt , Peter Kleinschmit , Gerd Schreyer , Gerhard Sperka
CPC分类号： C01C3/0233
摘要： In order to be independent of the situation in regard to methane and natural gas and at the same time to obtain a heating gas there is employed in the hydrocyanic acid-methane-ammonia process (the BMA process) in place of methane an alkanol or alkanediol having 2-4 carbon atoms, preferably ethyl alcohol, and this is reacted with ammonia in a C:N ratio of 0.8:1 to 2:1. Optionally additional hydrogen can be present.
摘要翻译： 为了独立于甲烷和天然气的情况，同时获得加热气体，采用氢氰酸 - 甲烷 - 氨法（BMA法）代替烷烃或链烷二醇 具有2-4个碳原子，优选乙醇，并且其与C：N比为0.8:1至2:1的氨反应。 可选地，可以存在另外的氢。
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公开(公告)号：US4321059A
公开(公告)日：1982-03-23
申请号：US174829
申请日：1980-08-04
申请人： Carl Voigt , Lothar Schmidt , Peter Kleinschmit
发明人： Carl Voigt , Lothar Schmidt , Peter Kleinschmit
CPC分类号： G01N31/005 , Y10T436/172307
摘要： Hydrogen cyanide in hydrogen cyanide containing gas is transformed into ammonia by a special iridium catalyst in the presence of at least the equivalent amount of hydrogen for the change. The ammonia is analyzed to provide a measure of the hydrogen cyanide in the hydrogen cyanide containing gas.
摘要翻译： 在含有氰化氢的气体中的氰化氢在至少相当量的氢气存在下通过特殊的铱催化剂转化为氨。 分析氨以提供含氰化氢气体中氰化氢的量度。
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公开(公告)号：US4961914A
公开(公告)日：1990-10-09
申请号：US218858
申请日：1988-07-14
CPC分类号： B01J23/40 , C01C3/0229
摘要： As a result of a special form of the surface coating of Al.sub.2 O.sub.3 catalysts using additional amounts of aluminum ions and very slight amounts of platinum ions, Al.sub.2 O.sub.3 was able to be used as catalyst for continuous operation (150 days and longer) in the preparation of hydrogen cyanide from hydrocarbons and ammonia, preferably in the BMA method.
摘要翻译： 作为使用额外量的铝离子和非常少量的铂离子的Al 2 O 3催化剂的表面涂覆的特殊形式的结果，Al 2 O 3能够用作连续操作（150天以上）的催化剂，用于制备氢 来自烃和氨的氰化物，优选以BMA方法。
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公开(公告)号：US06242373B1
公开(公告)日：2001-06-05
申请号：US09541915
申请日：2000-04-03
IPC分类号： C03C304
CPC分类号： C03C1/00 , C01B35/10 , C01P2006/12
摘要： A boron oxide-silicon dioxide mixed oxide which has a BET surface of less than 100 m2g, and optionally containing oxides of aluminium, titanium or zirconium, is prepared pyrogenically by flame hydrolysis. The mixed oxide is used in glass making.
摘要翻译： 通过火焰水解热原制备具有小于100m 2 g的BET表面和任选地含有铝，钛或锆的氧化物的氧化硼 - 二氧化硅混合氧化物。 混合氧化物用于制造玻璃。
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