公开(公告)号：US20150217249A1

公开(公告)日：2015-08-06

申请号：US14551141

申请日：2014-11-24

申请人： Dohyun Kim ,  David Alexoff ,  Sung Won Kim ,  Jacob M. Hooker ,  Richard A. Ferrieri

发明人： Dohyun Kim ,  David Alexoff ,  Sung Won Kim ,  Jacob M. Hooker ,  Richard A. Ferrieri

IPC分类号： B01J8/02 ,  C01C3/02

CPC分类号： B01J8/0285 ,  B01J8/0278 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00415 ,  B01J2208/00823 ,  B01J2208/00893 ,  B01J2208/024 ,  C01C3/0212 ,  C01C3/0216 ,  C01C3/0229 ,  C07B59/00

摘要： A method for providing 11C-labeled cyanides from 11C labeled oxides in a target gas stream retrieved from an irradiated high pressure gaseous target containing O2, wherein 11C labeled oxides are reduced with H2 in the presence of a nickel catalyst under a pressure and a temperature sufficient to form a product stream comprising at least about 95% 11CH4, the 11CH4 is then combined with an excess of NH3 in a carrier/reaction stream flowing at an accelerated velocity and the combined 11CH4 carrier/reaction stream is then contacted with a platinum (Pt) catalyst particulate supported on a substantially-chemically-nonreactive heat-stable support at a temperature of at least about 900° C., whereby a product stream comprising at least about 60% H 11CN is provided in less than 10 minutes from retrieval of the 11C labeled oxide.

摘要翻译： 在从含有O 2的被照射的高压气态靶中回收的目标气体流中，从11℃标记的氧化物中提供11C标记的氰化物的方法，其中在镍催化剂存在下，在压力和温度足够的情况下，用H 2还原11℃标记的氧化物 以形成包含至少约95％11CH4的产物流，然后将11CH4与以加速速度流动的载体/反应物流中的过量NH 3合并，然后将组合的11CH 4载体/反应物流与铂（Pt ）催化剂颗粒在至少约900℃的温度下负载在基本上化学反应性的热稳定性载体上，由此在不到10分钟内提供包含至少约60％H 11 CN的产物流， 11C标记氧化物。

公开(公告)号：US20170246617A1

公开(公告)日：2017-08-31

申请号：US15508615

申请日：2015-10-09

申请人： HALDOR TOPØE A/S

发明人： Burcin Temel McKenna ,  Poul Erik Høijlund Nielsen

IPC分类号： B01J23/74 ,  B01J23/825 ,  B01J23/835 ,  B01J23/94 ,  B01J23/745 ,  B01J37/02 ,  B01J37/03 ,  B01J37/18 ,  C01C3/02 ,  B01J38/14 ,  B01J23/80 ,  B01J37/00

CPC分类号： B01J23/74 ,  B01J23/745 ,  B01J23/80 ,  B01J23/825 ,  B01J23/835 ,  B01J23/94 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/18 ,  B01J38/14 ,  B01J2523/00 ,  C01C3/0229 ,  Y02P20/584 ,  B01J2523/31 ,  B01J2523/43 ,  B01J2523/845

摘要： The invention relates to a catalyst material comprising a support, a first metal and a second metal on said support. The first and second metals are in the form of a chemical compound. The first metal is Fe, Co or Ni, and the second metal is selected from the group consisting of Sn, Zn and In. The invention also relates to a process for the preparation of hydrogen cyanide (HCN) from methane (CH4) and ammonia (NH3), wherein the methane and ammonia are contacted with a catalyst according to the invention.

公开(公告)号：US20160145114A1

公开(公告)日：2016-05-26

申请号：US14896719

申请日：2014-05-21

申请人： Bernd GLÖCKLER ,  Martin STEFFAN ,  Martin STEURENTHALER ,  Thomas MÜLLER ,  Steffen KRILL ,  Martin KÖRFER ,  EVONIK DEGUSSA GMBH

发明人： Bernd Glockler ,  Martin Steffan ,  Martin Steurenthaler ,  Thomas Müller ,  Nicolas Rigot ,  Steffen Krill ,  Martin Körfer

IPC分类号： C01C3/02 ,  B01J19/00 ,  B01J19/24

CPC分类号： C01C3/0229 ,  B01J12/007 ,  B01J19/0026 ,  B01J19/006 ,  B01J19/2415 ,  B01J2219/00777 ,  B01J2219/24

摘要： The reaction tube comprises a cylindrical ceramic tube and a catalyst comprising platinum applied to the inner surface of the tube, wherein the reaction tube has fins on the inner surface which run in the longitudinal direction of the tube, extend into the interior space of the reaction tube and are coated with catalyst. The reaction tube is suitable for preparing hydrogen cyanide by reacting ammonia and at least one aliphatic hydrocarbon having 1 to 4 carbon atoms at a temperature of 1000 to 1400° C.

摘要翻译： 反应管包括圆柱形陶瓷管和包含铂的催化剂，其施加到管的内表面，其中反应管在内表面上具有在管的纵向方向上延伸的翅片，延伸到反应的内部空间 并用催化剂涂覆。 该反应管适用于在1000-1400℃的温度下使氨和至少一种具有1至4个碳原子的脂族烃反应制备氰化氢。

公开(公告)号：US20140147365A1

公开(公告)日：2014-05-29

申请号：US14169248

申请日：2014-01-31

申请人： ARKEMA FRANCE

发明人： JEAN-LUC DUBOIS

IPC分类号： C01C3/02 ,  C01C3/10

CPC分类号： C01C3/0229 ,  A01N37/34 ,  C01C3/0208 ,  C01C3/0216 ,  C01C3/0241 ,  C01C3/10

摘要： The invention relates to a hydrocyanic acid containing bioresourced carbon, and to a method for producing a raw material mainly containing the same by reacting ammonia with methane or methanol optionally in the presence of air and/or oxygen, characterized in that at least one of the reagents selected from ammonia, methane and methanol is obtained from a biomass. The invention also relates to the uses of the raw material for producing acetone cyanohydrin, adiponitrile, methionine or methionine hydroxyl-analog, and sodium cyanide.

摘要翻译： 本发明涉及含有生物活性炭的氢氰酸，以及任选地在空气和/或氧气存在下使氨与甲烷或甲醇反应生成原料的方法，其特征在于，至少一种 从生物质获得选自氨，甲烷和甲醇的试剂。 本发明还涉及原料用于生产丙酮氰醇，己二腈，甲硫氨酸或甲硫氨酸羟基 - 类似物和氰化钠的用途。

公开(公告)号：US09821285B2

公开(公告)日：2017-11-21

申请号：US14551141

申请日：2014-11-24

申请人： Brookhaven Science Associates, LLC

发明人： Dohyun Kim ,  David Alexoff ,  Sung Won Kim ,  Jacob M. Hooker ,  Richard A. Ferrieri

IPC分类号： B01J8/02 ,  B01J8/04 ,  C01C3/02 ,  C07B59/00

CPC分类号： B01J8/0285 ,  B01J8/0278 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00415 ,  B01J2208/00823 ,  B01J2208/00893 ,  B01J2208/024 ,  C01C3/0212 ,  C01C3/0216 ,  C01C3/0229 ,  C07B59/00

摘要： A method for providing 11C-labeled cyanides from 11C labeled oxides in a target gas stream retrieved from an irradiated high pressure gaseous target containing O2, wherein 11C labeled oxides are reduced with H2 in the presence of a nickel catalyst under a pressure and a temperature sufficient to form a product stream comprising at least about 95% 11CH4, the 11CH4 is then combined with an excess of NH3 in a carrier/reaction stream flowing at an accelerated velocity and the combined 11CH4 carrier/reaction stream is then contacted with a platinum (Pt) catalyst particulate supported on a substantially-chemically-nonreactive heat-stable support at a temperature of at least about 900° C., whereby a product stream comprising at least about 60% H11CN is provided in less than 10 minutes from retrieval of the 11C labeled oxide.

公开(公告)号：US20160263558A1

公开(公告)日：2016-09-15

申请号：US15028415

申请日：2014-10-02

申请人： Martin STEURENTHALER ,  Thomas MÜLLER ,  Martin KÖRFER ,  Steffen KRILL ,  EVONIK DEGUSSA GMBH ,  Martin STEFAN

发明人： Martin Steffan ,  Martin Steurenthaler ,  Thomas Müller ,  Martin Körfer ,  Steffen Krill

IPC分类号： B01J23/42 ,  B01J21/04 ,  C01C3/02 ,  B01J35/04

CPC分类号： B01J23/42 ,  B01J12/007 ,  B01J19/0026 ,  B01J19/006 ,  B01J19/2415 ,  B01J21/04 ,  B01J35/04 ,  B01J2219/0263 ,  B01J2219/30242 ,  C01C3/0229

摘要： The reaction tube for preparing hydrogen cyanide comprises a cylindrical tube composed of ceramic, a catalyst comprising platinum applied to the inner wall of the tube and also at least one insert composed of ceramic, having three or four fins pointing from the tube axis to the inner wall of the tube, which is inserted into the cylindrical tube, wherein the fins divide the tube interior space into substantially straight channels with substantially identical circle segment cross sections and wherein the mean gap between the ends of the fins and the inner wall of the tube is in the range of 0.1 to 3 mm. In the method for preparing hydrogen cyanide, ammonia and at least one aliphatic hydrocarbon having 1 to 4 carbon atoms are reacted in the reaction tube at 1000 to 1400° C.

摘要翻译： 用于制备氰化氢的反应管包括由陶瓷构成的圆柱形管，包含铂的催化剂，其施加到管的内壁上，还包括至少一个由陶瓷组成的插入件，具有从管轴指向内部的三个或四个翅片 插入圆柱形管中的管的壁，其中翅片将管内部空间划分成具有基本相同的圆形截面的基本上直的通道，并且其中翅片的端部与管的内壁之间的平均间隙 在0.1〜3mm的范围内。 在制备氰化氢的方法中，氨和至少一种具有1至4个碳原子的脂族烃在反应管中在1000-1400℃下反应。

公开(公告)号：US20160108809A1

公开(公告)日：2016-04-21

申请号：US14893524

申请日：2014-04-30

申请人： Georg MARKOWZ ,  Jürgen Erwin LANG ,  Rüdiger SCHÜTTE ,  Evonik Degussa GmbH

发明人： Georg Markowz ,  Jürgen Erwin Lang ,  Rüdiger Schütte

IPC分类号： F02C3/22 ,  B01J19/08 ,  F01K23/10 ,  B01J8/24 ,  H01M8/06 ,  C01C3/02 ,  B01J19/24

CPC分类号： F02C3/22 ,  B01J8/24 ,  B01J19/088 ,  B01J19/24 ,  B01J2208/00389 ,  B01J2219/00006 ,  B01J2219/00132 ,  B01J2219/0871 ,  C01B3/00 ,  C01B3/0005 ,  C01B3/50 ,  C01B2203/066 ,  C01B2203/84 ,  C01C3/0229 ,  C01C3/0233 ,  C01C3/025 ,  F01K23/10 ,  H01M8/0606 ,  Y02E20/16 ,  Y02E60/324 ,  Y02P20/129

摘要： The present invention relates to an integrated plant which comprises a plant for the electrothermic production of hydrogen cyanide and a plant for electricity generation, the plant for the electrothermic production of hydrogen cyanide being connected to the plant for electricity generation via a conduit and electricity being generated in the plant for electricity generation from a product gas obtained in the plant for the electrothermic production of hydrogen cyanide. This integrated plant affords flexible use of electricity by a method in which, at times of a high electricity supply, the plant for the electrothermic production of hydrogen cyanide is operated and at least some of the hydrogen and/or gaseous hydrocarbons obtained in addition to hydrogen cyanide is stored and, at times of a low electricity supply, stored hydrogen and/or gaseous hydrocarbons are fed to the plant for electricity generation.

摘要翻译： 本发明涉及一种综合设备，其包括用于电热生产氰化氢的设备和用于发电的设备，用于电热生产氰化氢的设备通过导管和电力被连接到用于发电的设备上 在用于电生产氰化氢的工厂中获得的产品气体的发电厂中。 该综合工厂通过一种方法灵活地使用电力，其中在高电力供应的时候，用于电化学生产氰化氢的设备运行，以及除了氢气之外获得的至少一些氢气和/或气态烃 存储氰化物，并且在低电力供应的时候，储存的氢气和/或气态碳氢化合物被供给到工厂用于发电。

公开(公告)号：US20110150743A1

公开(公告)日：2011-06-23

申请号：US12993374

申请日：2009-05-19

申请人： Jean-Luc Dubois

发明人： Jean-Luc Dubois

IPC分类号： C01C3/02 ,  C01C3/00 ,  C07C253/24 ,  C07C51/305 ,  C01C3/10

CPC分类号： C01C3/0229 ,  A01N37/34 ,  C01C3/0208 ,  C01C3/0216 ,  C01C3/0241 ,  C01C3/10

摘要： The invention relates to a hydrocyanic acid containing bioresource carbon, and to a method for producing a raw material mainly containing the same by reacting ammonia with methane or methanol optionally in the presence of air and/or oxygen, characterized in that at least one of the reagents selected from ammonia, methane and methanol is obtained from a biomass. The invention also relates to the uses of the raw material for producing acetone cyanohydrin, adiponitrile, methionine or methionine hydroxyl-analog, and sodium cyanide.

摘要翻译： 本发明涉及含有氢氰酸的生物资源碳，以及主要含有氢氰酸的原料的制造方法，其特征在于，在空气和/或氧气存在下，使氨与甲烷或甲醇反应，其特征在于， 从生物质获得选自氨，甲烷和甲醇的试剂。 本发明还涉及原料用于生产丙酮氰醇，己二腈，甲硫氨酸或甲硫氨酸羟基 - 类似物和氰化钠的用途。

公开(公告)号：US20060257308A1

公开(公告)日：2006-11-16

申请号：US10542215

申请日：2004-02-18

申请人： Lukas Von Hippel ,  Robert Weber ,  Martin Bewersdorf ,  Ernst Gail ,  Helmut Schwarz

发明人： Lukas Von Hippel ,  Robert Weber ,  Martin Bewersdorf ,  Ernst Gail ,  Helmut Schwarz

IPC分类号： B01J23/00

CPC分类号： B01J23/48 ,  B01J23/44 ,  B01J23/6527 ,  B01J23/8926 ,  B01J37/0219 ,  C01C3/0229

摘要： The invention relates to an improvement to the BMA process for the production of hydrogen cyanide from methane and ammonia in the presence of a platinum-containing catalyst. The problem of sooting, and thus the decrease in activity, of the catalysts can be reduced, or the activity increased, in that the catalyst is doped with an element from the series Cu, Ag, Au, Pd and W. The doping is preferably in the range of 0.01 to 20 mole % doping element, based on Pt.

摘要翻译： 本发明涉及在含铂催化剂存在下从甲烷和氨生产氰化氢的BMA方法的改进。 由于催化剂掺杂有来自Cu，Ag，Au，Pd和W系列的元素，催化剂的烟化和活性降低的问题可以降低或活性增加。优选掺杂 在0.01至20摩尔％掺杂元素的范围内，基于Pt。

公开(公告)号：US08574530B2

公开(公告)日：2013-11-05

申请号：US12865873

申请日：2009-03-20

申请人： Enzo Formentin ,  Catherine Schafer

发明人： Enzo Formentin ,  Catherine Schafer

IPC分类号： C01C3/0245

CPC分类号： C01C3/0212 ,  C01C3/0229 ,  C07C253/10 ,  C07C319/20 ,  C07C323/58 ,  C07C255/04

摘要： The present invention relates to an improved process for producing hydrocyanic acid by reaction of ammonia with methane in which a small amount of at least one sulphur-containing compound corresponding to the general formula R S (S)x—R′ is added, in which R and R′, which are identical or different, represent a linear or branched alkyl or alkenyl radical containing from 1 to 5 carbon atoms, and x is a number ranging from 1 to 5, to the reactive gas mixture before it passes over the catalyst. The process according to the invention makes it possible to obtain improved yields of HCN. Another subject of the invention relates to the use of the resulting product for producing methionine, acetone cyanohydrin, adiponitrile or sodium cyanide.

摘要翻译： 本发明涉及通过氨与甲烷反应制备氢氰酸的改进方法，其中加入少量至少一种对应于通式RS（S）xR'的含硫化合物，其中R和R '相同或不同，表示在其通过催化剂之前，含有1至5个碳原子的直链或支链烷基或烯基，并且x为1至5的数。 根据本发明的方法使得可以获得提高的HCN产率。 本发明的另一主题涉及所得产物用于生产甲硫氨酸，丙酮氰醇，己二腈或氰化钠的用途。