公开(公告)号：US20080083658A1

公开(公告)日：2008-04-10

申请号：US11858575

申请日：2007-09-20

Applicant: Carolus MESTERS

Inventor： Carolus MESTERS

IPC: C10G45/36 ,  B01J23/06

CPC classification number: B01J20/3007 ,  B01D53/8603 ,  B01J20/0225 ,  B01J20/0244 ,  B01J20/06 ,  B01J20/08 ,  B01J20/28016 ,  B01J20/3014 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J23/755 ,  B01J23/80 ,  B01J35/0073 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/16 ,  B01J37/18 ,  B01J2220/42 ,  C10G45/06 ,  C10G2300/202

Abstract: A catalyst is provided comprising nickel in a reduced valence state on a carrier comprising zinc oxide and alumina, wherein the Zn:Ni atomic ratio is at least 12, and the catalyst particles are prepared by: mixing zinc oxide in the form of a powder and alumina or an alumina precursor in the form of a powder; peptising the powder mixture and forming an extrudable dough by adding acid and water to the powder mixture in such amounts that the dough contains 0.8-1.2 moles acid equivalents per kg powder; extruding the extrudable dough to form extrudates; drying and calcining the extrudates; impregnating the extrudates with an aqueous solution of a nickel compound; drying, calcining and reducing the impregnated extrudates. Further provided is a process for desulphurisation of a hydrocarbonaceous feedstock using such catalyst.

Abstract translation: 提供一种催化剂，其包含在包含氧化锌和氧化铝的载体上的还原价态的镍，其中Zn:Ni原子比为至少12，催化剂颗粒通过以下方式制备：将粉末形式的氧化锌和 氧化铝或粉末形式的氧化铝前体; 将粉末混合物胶化并通过向粉末混合物中加入酸和水形成可挤出生面团，其量使得面团每kg粉末含有0.8-1.2摩尔酸当量; 挤出可挤出的面团以形成挤出物; 干燥和煅烧挤出物; 用镍化合物的水溶液浸渍挤出物; 干燥，煅烧和还原浸渍的挤出物。 还提供了使用这种催化剂对含烃原料进行脱硫的方法。