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    Catalyst systems of the Ziegler-Natta type
    2.
    发明授权
    Catalyst systems of the Ziegler-Natta type 失效
    齐格勒 - 纳塔型催化剂系统

    公开(公告)号：US06524995B2

    公开(公告)日：2003-02-25

    申请号：US09750715

    申请日：2001-01-02

    申请人： Wolf Spaether ,  Stephan Hüffer ,  John Lynch ,  Wolfgang Bidell ,  Joachim Rösch ,  Günther Schweier ,  Roland Hingmann ,  Alexandre Segul ,  Rainer Hemmerich ,  Ingo Treffkorn

    发明人： Wolf Spaether ,  Stephan Hüffer ,  John Lynch ,  Wolfgang Bidell ,  Joachim Rösch ,  Günther Schweier ,  Roland Hingmann ,  Alexandre Segul ,  Rainer Hemmerich ,  Ingo Treffkorn

    IPC分类号： B01J2302

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/025 ,  C08F4/6546 ,  C08F2500/12 ,  C08F2500/24

    摘要： Catalyst systems of the Ziegler-Natta type comprise as active constituents a) a solid component comprising a compound of titanium or vanadium, a compound of magnesium, a particulate inorganic oxide as support and an internal electron donor compound, and as cocatalyst b) an aluminum compound and c) if desired, a further, external electron donor compound, wherein the particulate, inorganic oxide used has a specific surface area of from 350 to 1000 m2/g and a mean particle diameter {overscore (D)} in the range from 5 to 60 &mgr;m and comprises particles which are composed of primary particles having a mean particle diameter {overscore (d)} in the range from 1 to 10 &mgr;m and contain voids or channels between the primary particles, where the macroscopic proportion of voids or channels having a diameter of greater than 1 &mgr;m in the particles of the inorganic oxides is in the range from 5 to 30% by volume and the molar ratio of the compound of magnesium to the particulate, inorganic oxide is from 0.5:1 to 2.0:1.

    摘要翻译： 齐格勒 - 纳塔型的催化剂体系包括作为活性成分的a）包含钛或钒的化合物的固体组分，镁的化合物，作为载体的颗粒状无机氧化物和内部电子给体化合物，以及作为助催化剂）铝化合物和 ），其中所用的颗粒状无机氧化物的比表面积为350〜1000m2 / g，平均粒径（超芯（D在5〜60μm的范围内）和 包含由平均粒径（超芯（d在1-10μm范围内）并且在初级颗粒之间含有空隙或通道的初级颗粒组成的颗粒，其中空隙或通道的宏观比例具有大于1的直径 无机氧化物颗粒中的母体在5至30体积％的范围内，镁与颗粒的无机氧化物的摩尔比为0.5:1至 2.0：1。

    Ziegler-Natta catalyst and methods of making and using same
    5.
    发明授权
    Ziegler-Natta catalyst and methods of making and using same 失效
    齐格勒 - 纳塔催化剂及其制备和使用方法

    公开(公告)号：US06831032B2

    公开(公告)日：2004-12-14

    申请号：US10223561

    申请日：2002-08-19

    申请人： Wolf Spaether

    发明人： Wolf Spaether

    IPC分类号： B01J3100

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6546 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/24

    摘要： A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining a porous particulate support with a magnesium source in a hydrocarbon solvent to form a mixture, the magnesium source including a hydrocarbon soluble organomagnesium compound and a hydrocarbon insoluble anhydrous inorganic magnesium-halogen compound. The organomagnesium compound is halogenated and the mixture is reacted with a titanium compound or vanadium compound to form the solid catalyst component. The solid catalyst component is then recovered and combined with an organoaluminum cocatalyst to form a Ziegler-Natta catalyst which is advantageously used for the polymerization of olefins, particularly alk-1-enes such as ethylene, propylene, 1-butene, and the like. The catalyst can optionally include internal and external electron donors.

    摘要翻译： 制备用于齐格勒 - 纳塔催化剂的固体催化剂组分的方法包括在烃溶剂中将多孔颗粒载体与镁源组合以形成混合物，所述镁源包括可溶于烃的有机镁化合物和不溶于烃的无水无机无机物 镁 - 卤素化合物。 将有机镁化合物卤化，并将混合物与钛化合物或钒化合物反应形成固体催化剂组分。 然后回收固体催化剂组分并与有机铝助催化剂组合以形成齐格勒 - 纳塔催化剂，该催化剂有利地用于烯烃聚合，特别是烯-1-烯如乙烯，丙烯，1-丁烯等。 催化剂可以任选地包括内部和外部电子给体。